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(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole

Reaction
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
CAS No.
112022-81-8
Chemical Name:
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
Synonyms
(S)-ME CBS;(s)-methyl;(S)-Me-CBS Catalyst;(S)-Tetrahydro-1-Methyl-3;(S)-METHYL OXAZABOROLIDINE;(S)-2-METHYL-CBS-OXAZABOROL;(S)-2-METHYL-CBS-OXAZABOROLIDINE;1-(S)-methyl CBS oxazaborolidine;(S)-(+)-Methyl-CBS-oxazaborolidine;(S)-(-)-2-METHYL-CBS-OXAZABOROLIDINE
CBNumber:
CB3106062
Molecular Formula:
C18H20BNO
Formula Weight:
277.17
MOL File:
112022-81-8.mol

(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Properties

Melting point:
115-117°C
Boiling point:
111 °C
Density 
0.93 g/mL at 20 °C(lit.)
refractive index 
-68 ° (C=1, MeOH)
Flash point:
40 °F
storage temp. 
Refrigerator
form 
Liquid
color 
Colorless to amber
Water Solubility 
Hydrolyzes in water.
Sensitive 
Air & Moisture Sensitive
BRN 
8492123
InChIKey
VMKAFJQFKBASMU-KRWDZBQOSA-N
CAS DataBase Reference
112022-81-8(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xi,Xn,F
Risk Statements  36/37/38-67-65-63-48/20-11-19-40
Safety Statements  26-62-36/37-33-29-16
RIDADR  UN 1294 3/PG 2
WGK Germany  3
10-21
HazardClass  3
PackingGroup  II
HS Code  29349990
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H361 Suspected of damaging fertility or the unborn child Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P281 Use personal protective equipment as required.
P331 Do NOT induce vomiting.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P403+P235 Store in a well-ventilated place. Keep cool.

(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 457701 (S)-(?)-2-Methyl-CBS-oxazaborolidine solution 1 M in toluene 112022-81-8 5ml $77.1 2018-11-13 Buy
Sigma-Aldrich 457701 (S)-(?)-2-Methyl-CBS-oxazaborolidine solution 1 M in toluene 112022-81-8 25ml $258 2018-11-13 Buy
TCI Chemical D2131 (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine >98.0%(T) 112022-81-8 1g $71 2018-11-22 Buy
TCI Chemical D2131 (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine >98.0%(T) 112022-81-8 5g $285 2018-11-22 Buy
Alfa Aesar L09219 (S)-2-Methyl-CBS-oxazaborolidine monohydrate, 94% 112022-81-8 1g $316 2018-11-13 Buy

(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Chemical Properties,Uses,Production

Reaction

  1. Convenient catalyst for the enantioselective borane reduction of ketones at ambient temperatures.
  2. Asymmetric synthesis of α-chiral hydroxyalkylphosphines via a catalytic, enantioselective reduction of acylphosphines.
  3. Nickel-catalyzed cross-couplings of benzylic pivalates with arylboroxines: Stereospecific formation of diarylalkanes and triarylmethanes.
  4. Enantioselective reduction of prochiral ketones with NaBH4/Me2SO4/(S)-Me-CBS.

Chemical Properties

Colorless to yellow liquid

Uses

suzuki reaction

(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Preparation Products And Raw materials

Raw materials

Preparation Products


(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Suppliers

Global( 176)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
+86 (0)571-855 867 18
+86 (0)571-858 647 95 sales@capotchem.com China 19953 60
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 22049 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20786 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32651 55
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070;product@chemlin.com.cn
product@chemlin.com.cn CHINA 3015 60
Shanghai Yingrui Biopharma Co., Ltd.
+86-21-33585366 E-mail:sales03@shyrchem.com
+86-21-34979012 sales03@shyrchem.com CHINA 663 60
Nanjing Finetech Chemical Co., Ltd.
025-85710122 17714198479
025-85710122 sales@fine-chemtech.com CHINA 894 55
Zjartschem
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+86-571-87063838 jocelynpan@zjarts.com CHINA 664 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 10967 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 19990 58

View Lastest Price from (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-23 (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
112022-81-8
US $1.00 / kg 1kg 95%-99% as request career henan chemical co
2018-03-06 (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
112022-81-8
US $1.00 / KG 1KG 99% 100t Shanghai Yingrui Biopharma Co., Ltd.

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