ChemicalBook >> CAS DataBase List >>1,1'-Bis(di-tert-butylphosphino)ferrocene
1,1'-Bis(di-tert-butylphosphino)ferrocene
- CAS No.
- 84680-95-5
- Chemical Name:
- 1,1'-Bis(di-tert-butylphosphino)ferrocene
- Synonyms
- DTBPF;1,1'-BIS(DI-T-BUTYLPHOSPHINO)FERROCENE;DBtPF;98% DtBPF;1,1'-Bis(di-t-butyL;1,1'-Bis(di-tert-butylphosphi;1,1'-Bis(di-tert-butylphosphin;1,1'-Bis(di-t-butylphosphino)ferrocene;1,1'-Bis(di-tert-butylphosphiNA)ferrocene;1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
- CBNumber:
- CB3689138
- Molecular Formula:
- C26H44FeP210*
- Molecular Weight:
- 474.42
- MDL Number:
- MFCD01630818
- MOL File:
- 84680-95-5.mol
- MSDS File:
- SDS
Last updated:2024-04-28 15:15:04
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
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---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 22-24/25-36/37/39-26 | |||||||||
WGK Germany | 3 | |||||||||
TSCA | No | |||||||||
HS Code | 29319090 | |||||||||
NFPA 704 |
|
1,1'-Bis(di-tert-butylphosphino)ferrocene price More Price(43)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 695149 | 1,1′-Bis(di-tert-butylphosphino)ferrocene | 84680-95-5 | 1g | $171 | 2024-03-01 | Buy |
Sigma-Aldrich | 695149 | 1,1′-Bis(di-tert-butylphosphino)ferrocene | 84680-95-5 | 250mg | $93.8 | 2023-06-20 | Buy |
TCI Chemical | B2711 | 1,1'-Bis(di-tert-butylphosphino)ferrocene >95.0%(T) | 84680-95-5 | 1g | $124 | 2024-03-01 | Buy |
TCI Chemical | B2711 | 1,1'-Bis(di-tert-butylphosphino)ferrocene >95.0%(T) | 84680-95-5 | 100mg | $23 | 2024-03-01 | Buy |
Alfa Aesar | L19759 | 1,1'-Bis(di-tert-butylphosphino)ferrocene, 98% | 84680-95-5 | 500mg | $65.2 | 2021-12-16 | Buy |
1,1'-Bis(di-tert-butylphosphino)ferrocene Chemical Properties,Uses,Production
Reaction
- Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
- Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
- Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
- Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
- Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
- Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
- Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
- Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
- Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.
![Reactions of 84680-95-5_1](/NewsImg/2018-03-23/201832314112739516.jpg)
![Reactions of 84680-95-5_2](/NewsImg/2018-03-23/201832314113544299.jpg)
Uses
1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE is an organophosphine compound and can be used as an organometallic ligand.
Uses
The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene.
![65587-59-9](/CAS/20210305/GIF/1000210-73-0.gif)
![13716-10-4](/CAS/GIF/13716-10-4.gif)
![84680-95-5](/CAS/GIF/84680-95-5.gif)
Synthesis of 1,1'-Bis(di-tert-butylphosphino)ferrocene from Ethanamine, N-[(3,5-dichlorophenyl)methylene]-2,2-diethoxy- and Di-tert-butylchlorophosphane
1,1'-Bis(di-tert-butylphosphino)ferrocene Preparation Products And Raw materials
Global( 246)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Puyang Huicheng Electronic Materials Co., Ltd. | +86-0393-+86-0393-8910800 +8615839383373 | info@huichengchem.com | China | 522 | 58 |
XINXIANG RUNYU MATERIAL CO., LTD. | +86-13592593621; +8613592593621 | sales@runvmat.com | China | 425 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12470 | 58 |
Ouhuang Engineering Materials (Hubei) Co., Ltd | +8617702722807 | admin@hbouhuang.com | China | 3001 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15954 | 58 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32715 | 60 |
career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
View Lastest Price from 1,1'-Bis(di-tert-butylphosphino)ferrocene manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2024-04-28 | 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
84680-95-5
|
US $100.00-30.00 / kg | 1kg | 99.93% | 1000kg per week | Ouhuang Engineering Materials (Hubei) Co., Ltd | |
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2023-07-28 | 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
84680-95-5
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
![]() |
2023-07-27 | 1,1'-Bis(di-tert-butylphosphino)ferrocene
84680-95-5
|
US $0.00-0.00 / KG | 1KG | 0.98 | 500kg | XINXIANG RUNYU MATERIAL CO., LTD. |
-
- 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
84680-95-5
- US $100.00-30.00 / kg
- 99.93%
- Ouhuang Engineering Materials (Hubei) Co., Ltd
-
- 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
84680-95-5
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- 1,1'-Bis(di-tert-butylphosphino)ferrocene
84680-95-5
- US $0.00-0.00 / KG
- 0.98
- XINXIANG RUNYU MATERIAL CO., LTD.
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DBtPF
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1,1'-Bis(di-tert-butylphosphino)ferrocene >
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1,1'-Bis(di-t-butylphosphino)ferrocene, min. 98% DTBPF
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DTBPF / 1,1'-Bis(di-tert-butylphosphino)ferrocene
1,1'-Bis(di-tert-butylphosphino)ferrocene 98%
DTBPF
1,1'-BIS(DI-T-BUTYLPHOSPHINO)FERROCENE
Dehch(bis(2-ethylhexyl) cyclohexane -1,2-dicarboxylate)
1,1'-Bis(di-tert-butylphosphino)ferrocene
1,1'-Bis[bis(1,1-dimethylethyl)phosphino]ferrocene
1,1'-Bis(di-t-butylphosphino)ferrocene
84680-95-5
94680-95-5
C26H44FeP2
C4H92PC5H42Fe
2C13H22PFe
C26H44FeP210
2C13H23PFe
C26H42FeP2
Metallocenes
Transition Metal Compounds
Phosphine Ligands
Classes of Metal Compounds
Ferrocenes
Fe (Iron) Compounds
Achiral Phosphine
Aryl Phosphine
Classes of Metal Compounds
Fe (Iron) Compounds
Ferrocenes
Metallocenes
Phosphine Ligands
Synthetic Organic Chemistry
Transition Metal Compounds
Catalysis and Inorganic Chemistry
Phosphorus Compounds
Polydentate Phosphine Ligands