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Sodium bis(trimethylsilyl)amide

Sodium bis(trimethylsilyl)amide
Sodium bis(trimethylsilyl)amide
CAS No.
1070-89-9
Chemical Name:
Sodium bis(trimethylsilyl)amide
Synonyms
NAHMDS;HMDS Na;HMN NA SALT;Sodium bis(trimethyl;N-SODIUMHEXAMETHYLDISILA;SODIUM HEXAMETHYLDISILAZIDE;SODIUM HEXAMETHYLDISILAZANE;N-SODIOHEXAMETHYLDISILAZANE;N-SODIUMHEXAMETHYLDISILAZANE;Sodiobis(trimethylsilyl)amine
CBNumber:
CB8382263
Molecular Formula:
C6H18NNaSi2
Formula Weight:
183.37
MOL File:
1070-89-9.mol

Sodium bis(trimethylsilyl)amide Properties

Melting point:
171-175 °C(lit.)
Boiling point:
67°C
Density 
0.904 g/mL at 25 °C
Flash point:
43 °F
storage temp. 
2-8°C
solubility 
Soluble in hexane, toluene, ether,terahydrofuran, benzene and toluene.
form 
Liquid
color 
Clear orange to brown
Water Solubility 
reacts
Sensitive 
Moisture Sensitive
BRN 
3629917
CAS DataBase Reference
1070-89-9(CAS DataBase Reference)
EPA Substance Registry System
Silanamine, 1,1,1-trimethyl-N-(trimethylsilyl)-, sodium salt(1070-89-9)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  C,F
Risk Statements  14-34-19-11-67-65-63-48/20-14/15-40-37
Safety Statements  26-45-62-36/37/39-33-16-43-8
RIDADR  UN 3263 8/PG 2
WGK Germany  3
10-21
TSCA  Yes
HazardClass  4.3
PackingGroup  III
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3
Danger
Warning
P231+P232, P280, P370+P378,P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H303 May be harmfulif swallowed Acute toxicity,oral Category 5 P312
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P309 IF exposed or if you feel unwell:
P310 Immediately call a POISON CENTER or doctor/physician.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P402 Store in a dry place.
P405 Store locked up.
P403+P235 Store in a well-ventilated place. Keep cool.

Sodium bis(trimethylsilyl)amide price More Price(24)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 235083 Sodium bis(trimethylsilyl)amide 95% 1070-89-9 5g $35.7 2018-11-13 Buy
Sigma-Aldrich 235083 Sodium bis(trimethylsilyl)amide 95% 1070-89-9 25g $123 2018-11-13 Buy
TCI Chemical H0894 Sodium Bis(trimethylsilyl)amide (contains 2-Methyl-2-butene) (38% in Tetrahydrofuran, ca. 1.9mol/L) 1070-89-9 100mL $52 2017-12-01 Buy
TCI Chemical H0894 Sodium Bis(trimethylsilyl)amide (contains 2-Methyl-2-butene) (38% in Tetrahydrofuran, ca. 1.9mol/L) 1070-89-9 500mL $184 2017-12-01 Buy
Alfa Aesar 033505 Sodium bis(trimethylsilyl)amide, 98% 1070-89-9 2g $15.6 2018-11-16 Buy

Sodium bis(trimethylsilyl)amide Chemical Properties,Uses,Production

Chemical Properties

Slightly yellow to light beige crystalline powder

Uses

It is a strong base; deprotonates ketones and esters to generate enolate derivative.

Uses

Significantly accelerated the polymerization of pheneylacetylene in conjunction with rhodium (I) catalysis

Purification Methods

It can be sublimed at 170o/2mm (bath temperature 220-250o) onto a cold finger, and can be recrystallised from *C6H6 (its solubility is: 10g in 100mL at 60o). It is slightly soluble in Et2O and is decomposed by H2O. [Wannagat & Niederprüm Chem Ber 94 1540 1961.]It is available commercially under N2 in Sure/Seal bottles in tetrahydrofuran (various concentrations) and at ~0.6M in toluene. [Beilstein 4 IV 4014.]

Sodium bis(trimethylsilyl)amide Preparation Products And Raw materials

Raw materials

Preparation Products


Sodium bis(trimethylsilyl)amide Suppliers

Global( 197)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
inquiry@dakenchem.com CHINA 22119 58
Beijing Cooperate Pharmaceutical Co.,Ltd.
+86-10-60279497 +86(0)15646567669
+86-10-60279497 sales01@cooperate-pharm.com CHINA 1529 55
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20795 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32764 55
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070;product@chemlin.com.cn
product@chemlin.com.cn CHINA 3015 60
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 10011 58
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30308 84
Chengdu Hongsheng Sci-Tech Development Co..,Ltd 86-028-37690186,18089504818,13568974161
86-028-37690186 cdchemical@163.com China 40 58
Sichuan Weibo Science and Technology Co., Ltd. +86 (28) 8757-8473 / +86 13880582998
+86 (28) 8757-8473 ellnn@163.com China 50 60
Adamas Reagent, Ltd. 400-600-9262
bxy@titansci.com China 14017 59

View Lastest Price from Sodium bis(trimethylsilyl)amide manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-08-06 Sodium bis(trimethylsilyl)amide solution
1070-89-9
US $10.00 / KG 10KG 99% 20KG

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