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2-Mercaptobenzimidazole

2-Mercaptobenzimidazole Structure
2-Mercaptobenzimidazole structure
CAS No.
583-39-1
Chemical Name:
2-Mercaptobenzimidazole
Synonyms
1H-BENZO[D]IMIDAZOLE-2-THIOL;Mercaptobenzimidazole;Vulkanox;SuMilizer MB;Benzimidazole-2-thiol;2-BENZIMIDAZOLETHIOL;Benzimidazol-2-thiol;2-Mercapto benzanidazole;AOMB;asmmb
CBNumber:
CB8490256
Molecular Formula:
C7H6N2S
Molecular Weight:
150.2
MDL Number:
MFCD00466107
MOL File:
583-39-1.mol
MSDS File:
SDS
Last updated:2024-04-17 18:50:11
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2-Mercaptobenzimidazole Properties

Melting point 300-304 °C (lit.)
Boiling point 270.6±23.0 °C(Predicted)
Density 1.42
vapor pressure 0-0.001Pa at 25℃
refractive index 1.5500 (estimate)
Flash point >250°C
storage temp. 2-8°C
solubility 0.3g/l
form Powder
pka 10.24±0.10(Predicted)
color White to beige
Water Solubility <0.1 g/100 mL at 23.5 ºC
Merck 14,1082
BRN 119867
Stability Stable. Incompatible with strong oxidizing agents.
LogP 0.88-1.66 at 20-25℃
CAS DataBase Reference 583-39-1(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 619CVM6HOK
NIST Chemistry Reference 2-Mercaptobenzimidazole(583-39-1)
EPA Substance Registry System 2-Mercaptobenzimidazole (583-39-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08
Signal word  Danger
Hazard statements  H301-H317-H373-H412
Precautionary statements  P260-P273-P280-P301+P310-P302+P352-P314
Hazard Codes  Xn
Risk Statements  20/21/22-36/37/38-22
Safety Statements  26-36-24/25
RIDADR  UN 2811 6.1/PG 3
WGK Germany  2
RTECS  DE1050000
Autoignition Temperature 480 °C
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29339910
Toxicity LD50 orally in Rabbit: 300 mg/kg
NFPA 704
1
3 0

2-Mercaptobenzimidazole price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich PHR3123 Rabeprazole Related Compound C pharmaceutical secondary standard, certified reference material 583-39-1 50MG $534 2024-03-01 Buy
Sigma-Aldrich 1598042 Rabeprazole Related Compound C United States Pharmacopeia (USP) Reference Standard 583-39-1 25mg $1300 2024-03-01 Buy
Sigma-Aldrich 51810 2-Mercaptobenzimidazole analytical standard 583-39-1 50mg $63 2022-05-15 Buy
TCI Chemical B0055 2-Mercaptobenzimidazole >98.0%(HPLC)(T) 583-39-1 25g $16 2024-03-01 Buy
TCI Chemical B0055 2-Mercaptobenzimidazole >98.0%(HPLC)(T) 583-39-1 500g $85 2024-03-01 Buy
Product number Packaging Price Buy
PHR3123 50MG $534 Buy
1598042 25mg $1300 Buy
51810 50mg $63 Buy
B0055 25g $16 Buy
B0055 500g $85 Buy

2-Mercaptobenzimidazole Chemical Properties,Uses,Production

Description

2-Mercaptobenzimidazole is a very useful corrosion inhibitor and cleaner. It can be used to remove the mercury (II) from aqueous solutions and chlor-alkali industry wastewater1. It can be added to the surface film to inhibit the corrosion of metals like copper2-3 and mild steel4. It can also be used as the carrier for the coated-wire mercury (II)-selective electrodes5.
2-Mercaptobenzimidazole is also used as an anti-degradant. It is utilized for protecting rubber from oxidation. It is also employed as an intermediate in the preparation of rabeprazole. Further, it finds application in anti-leprosy drugs in medicine6.

Reference

  1. Manohar, D. M., K. A. Krishnan, and T. S. Anirudhan. "Removal of mercury (II) from aqueous solutions and chlor-alkali industry wastewater using 2-mercaptobenzimidazole-clay." Water Research 36.6(2002):1609.
  2. Chadwick, D., and T. Hashemi. "Electron spectroscopy of corrosion inhibitors: Surface films formed by 2-mercaptobenzothiazole and 2-mercaptobenzimidazole on copper." Surface Science 89.1(1979):649-659.
  3. Trachli, B., et al. "Protective effect of electropolymerized 2-mercaptobenzimidazole upon copper corrosion." Progress in Organic Coatings 44.1(2002):17-23.
  4. Wang, Lin. "Evaluation of 2-mercaptobenzimidazole as corrosion inhibitor for mild steel in phosphoric acid." Corrosion Science 43.12(2001):2281-2289.
  5. Mazloum, M, M. K. Amini, and I. Mohammadpoor-Baltork. "Mercury selective membrane electrodes using 2-mercaptobenzimidazole, 2-mercaptobenzothiazole, and hexathiacyclooctadecane carriers." Sensors & Actuators B Chemical 63.1(2000):80-85.
  6. https://www.alfa.com/en/catalog/A18350/

Chemical Properties

yellow or white crystals

Uses

An antidegradant, protecting rubber from oxidation. An intermediate in the synthesis of Rabeprazole (R070500)

Uses

2-Mercaptobenzimidazole is used as an antidegradant. It is utilized for protecting rubber from oxidation. It is also employed as an intermediate in the preparation of rabeprazole. Further, it finds application in anti-leprosy drugs in medicine. In addition to this, it is used as a copper plating brightener.

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 4, p. 569, 1963
The Journal of Organic Chemistry, 29, p. 3209, 1964 DOI: 10.1021/jo01034a020

General Description

White to yellow crystals or cream colored powder. Slight odor.

Air & Water Reactions

Dust explosion: 0.140 oz/ft3. Insoluble in water. 2-Mercaptobenzimidazole is moisture sensitive. .

Reactivity Profile

An organosulfide and an amine. Organosulfides are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Fire Hazard

Flash point data for 2-Mercaptobenzimidazole are not available; however, 2-Mercaptobenzimidazole is probably combustible.

Flammability and Explosibility

Non flammable

Safety Profile

Poison by intraperitoneal and intravenous routes. Moderately toxic by ingestion. Skin and eye irritant. When heated to decomposition it emits toxic fumes of SO, and NO,. See also MERCAPTANS.

Purification Methods

Crystallise it from aqueous EtOH, AcOH or aqueous ammonia. It complexes with many metals. [Brown J Chem Soc 1976 1958, Beilstein 24 II 65, 24 III/IV 287.]

2-Mercaptobenzimidazole Preparation Products And Raw materials

Raw materials

Ethanol Potassium hydroxide Sodium sulfide 2-Nitrochlorobenzene Carbon disulfide
2-Nitroaniline o-Phenylenediamine 1,2,3-TRIPHENYLGUANIDINE Aniline

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Preparation Products

1H-BENZIMIDAZOLE-2-SULFONIC ACID Lansoprazole 4,4'-DIPYRIDYL SULFIDE 2-(METHYLTHIO)BENZIMIDAZOLE 2-BROMO-1H-BENZIMIDAZOLE

2-Mercaptobenzimidazole Suppliers

Global( 868)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd 		+8613288715578 sales@hbmojin.com China 12456 58
Kindchem(Nanjing)Co.,Ltd 		+86-025-025-85281586 +8618651653755 sales@kindchem.cn China 1227 58
Henan Bao Enluo International TradeCo.，LTD 		+86-17331933971 +86-17331933971 deasea125996@gmail.com China 2503 58
Zibo Hangyu Biotechnology Development Co., Ltd 		+86-0533-2185556 +8617865335152 Mandy@hangyubiotech.com China 11013 58
Hebei Saisier Technology Co., LTD 		+86-18400010335 +86-13102810335 admin@hbsaisier.cn China 747 58
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Shanghai Time Chemicals CO., Ltd. 		+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1807 55
Hangzhou FandaChem Co.,Ltd. 		008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
Supplier Advantage
Hebei Mojin Biotechnology Co., Ltd 		58
Kindchem(Nanjing)Co.,Ltd 		58
Henan Bao Enluo International TradeCo.，LTD 		58
Zibo Hangyu Biotechnology Development Co., Ltd 		58
Hebei Saisier Technology Co., LTD 		58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
Shanghai Time Chemicals CO., Ltd. 		55
Hangzhou FandaChem Co.,Ltd. 		55

View Lastest Price from 2-Mercaptobenzimidazole manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Mercaptobenzimidazole pictures 2024-04-18 2-Mercaptobenzimidazole
583-39-1
 US $6.00 / KG 1KG More than 99% 2000KG/Month Hebei Saisier Technology Co., LTD
2-Mercaptobenzimidazole pictures 2024-01-02 2-Mercaptobenzimidazole
583-39-1
 US $0.00-0.00 / kg 1kg 98% 100 Kindchem(Nanjing)Co.,Ltd
2-Mercaptobenzimidazole pictures 2024-01-02 2-Mercaptobenzimidazole
583-39-1
 US $75.00-750.00 / kg 10kg 0.99 20tons Zibo Hangyu Biotechnology Development Co., Ltd

2-Mercaptobenzimidazole Spectrum

2-Mercaptobenzimidazole(583-39-1)MS2-Mercaptobenzimidazole(583-39-1)1HNMR2-Mercaptobenzimidazole(583-39-1)13CNMR2-Mercaptobenzimidazole(583-39-1)IR12-Mercaptobenzimidazole(583-39-1)IR22-Mercaptobenzimidazole(583-39-1)Raman

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1,3-dihydro-2h-benzimidazole-2-thion 1,3-Dihydro-2H-benzimidazole-2-thione 1,3-Dihydro-benzoimidazole-2-thione 1H-Benzimidazol-2-yl hydrosulfide 2,3-Dihydro-1H-benzimidazole-2-thiol 2-Benzimidazolethione 2-Benzimidazolinethione 2-benzimidazolinthion 2H-Benzimidazole-2-thione, 1,3-dihydro- 2H-Benzimidazole-2-thione,1,3-dihydro- 2-Mercaptobenzoimidazole usafek-6540 usafxf-21 Vulkanox MB Vulkanox MBI 2-Mercaptobenzimidazole≥ 99.5% 2-Benzimidazolethiol 1H-Benzo[d]imidazole-2-thiol 1,3-dihydro-2H-Benzimidazole-2-thione Antioxidant MB 2-benzimidazolinthion 2-Mercaptobenzimidaz 2-MercaptobenziMidazole, 98% 100GR 2-MercaptobenziMidazole, 98% 250GR 2-MercaptobenziMidazole, 98% 5GR 2-Mercapto-1H-benziMidazole o-Phenyleneth Sandant MB Lansoprazole related substance E 2-Mercapto beziMidazole 1H-BenziMidazol-2-thiol Lansoprazole EP IMpurity E 1H-benzo[d]iMidazole-2(3H)-thione 2-Mercapto-1H-benzimidazole, 2-Sulphanyl-1H-benzimidazole Rabeprazole Related CoMpound C 2-MercaptobenziMidazole, 98.0%(T) 2 - Mercapto benzene and iMidazole 2-Mercaptobenzimidazole, MBI 2-merkaptobenzimidazol 2-Thiobenzimidazole 2-Thiol benzimidazole Anitiegene MB Antiegene MB antiegenemb Antigen MB Antigene MB Antioxidant mb AntioxidantMB AOMB Asm MB asmmb Mercaptobenzoimidazole Merkaptobenzimidazol NCI-C56268 nci-c60980 Nocrac MB o-Phenylenethiourea Permanax 21 USAF ek-6540 USAF xf-21 Mercaptophenylimidazole Zinc salt of 2-Mercaptobenzimidazole (MBZ antioxidant)