몰리네이트

몰리네이트
몰리네이트 구조식 이미지
카스 번호:
2212-67-1
한글명:
몰리네이트
동의어(한글):
몰리네이트;몰린산;1H-아제핀-1-카르보티오산 헥사하이드로-S-에틸에스테르
상품명:
Molinate
동의어(영문):
G 10;sc998;BUD31;Yalan;Yulan;Felan;Jalan;ordam;HYDRAM;R-4572
CBNumber:
CB4768126
분자식:
C9H17NOS
포뮬러 무게:
187.3
MOL 파일:
2212-67-1.mol
MSDS 파일:
SDS

몰리네이트 속성

녹는점
<25 °C
끓는 점
202°C (10 mmHg)
밀도
1.06
굴절률
1.5250 (estimate)
인화점
100 °C
저장 조건
0-6°C
용해도
클로로포름(약간 용해됨), 에틸아세테이트(약간 용해됨), 메탄올(약간 용해됨)
용해도
클로로포름(약간), 에틸아세테이트(약간), 메탄올(약간)에 용해됨
산도 계수 (pKa)
-1.22±0.20(Predicted)
물리적 상태
액체
색상
호박색
수용성
0.08g/100mL
BRN
1239196
LogP
3.210
CAS 데이터베이스
2212-67-1(CAS DataBase Reference)
NIST
Molinate(2212-67-1)
EPA
Molinate (2212-67-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N,Xn
위험 카페고리 넘버 20/22-40-43-48/22-63-50/53-62
안전지침서 36/37-46-60-61
유엔번호(UN No.) 2902
WGK 독일 3
RTECS 번호 CM2625000
위험 등급 6.1(b)
포장분류 III
유해 물질 데이터 2212-67-1(Hazardous Substances Data)
독성 LC50 (96-hour) for bluegill sunfish 29–30 mg/L, goldfish 30 mg/L, mosquito fish 16.4 mg/L, rainbow trout 0.2–1.3 mg/L (Hartley and Kidd, 1987); acute oral LD50 of technical molinate for rats and mice 720 and 795 mg/kg, respectively (Ashton and Monaco, 1991), 501 mg/kg (RTECS, 1985).
기존화학 물질 KE-18553
유해화학물질 필터링 97-1-89
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 몰리네이트 및 이를 25% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H351 암을 일으킬 것으로 의심됨 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
H361 태아 또는 생식능력에 손상을 일으킬 것으로 의심됨 생식독성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P201 사용 전 취급 설명서를 확보하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.

몰리네이트 MSDS


Molinate

몰리네이트 C화학적 특성, 용도, 생산

용도

Selective herbicide used to control the germination of annual grasses and broadleaved weeds in rice crops.

일반 설명

Clear liquid with aromatic odor. Non corrosive. Used as an herbicide.

공기와 물의 반응

Water soluble. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids.

반응 프로필

Molinate is a thiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

농업용

Herbicide: Molinate is a selective herbicide used on rice for the control of water grass and other weeds.

상품명

ARROSOLO®; FELAN®; HIGALNATE®; HYDRAM®; JALAN®; MALERBANE-GIAVONI-L®;ORDAM®; ORDRAM®; R-4572®; RICECO; SAKKIMOL®; STAUFFER R 4,572®; YALAN®; YULAN®

환경귀착

Soil. Hydrolyzes in soil forming ethyl mercaptan, carbon dioxide and dialkylamine (half-life approximately 2–5 weeks) (Hartley and Kidd, 1987). At recommended rates of application, the half-life of molinate in moist loam soils at 21–27°C is approximately 3 weeks (Humburg et al., 1989). Rajagopal et al. (1989) reported that under flooded conditions, molinate was hydroxylated at the 3- and 4-position with subsequent oxidation forming many compounds including molinate sulfoxide, carboxymethyl molinate, hexahydroazepine- 1-carbothioate, 4-hydroxymolinate, 4-hydroxymolinate sulfoxide, hexahydroazepine, S-methyl hexahydroazepine-1-carbothioate, 4-ketomolinate, 4-hydroxyhexahydroazepine, 4-hydroxy-N-acetyl-hexahydroazepine, carbon dioxide and bound residues.
Plant. Molinate is rapidly metabolized by plants releasing carbon dioxide and naturally occurring plant constituents (Humburg et al., 1989).
Photolytic. Molinate in a hydrogen peroxide solution (120 mM) was irradiated by UV light (l = 290 nm) at 23°C. The major photooxidation products were the two isomers of 2-oxomolinate (20% yield) and s-molinate oxide (5% yield) (Draper and Crosby, 1984).
Half-lives of 180 and 120 hours were observed using one and two equivalents of hydrogen peroxide, respectively (Draper and Crosby, 1984). Molinate has a UV absorption maximum at 225 nm and no absorption at wavelengths >290 nm. Therefore, molinate is not expected to undergo aqueous photolysis under natural sunlight (l = 290 nm). In the presence of tryptophan, a naturally occurring photosensitizer, molinate in aqueous solution photodegraded to form 1-((ethylsulfinyl)carbonyl)hexahydro-1H-azepine, S-ethyl hexahydro-2- oxo-1H-azepine-1-carbothioate and hexamethyleneimine (Soderquist et al., 1977).
Chemical/Physical. Metabolites identified in tap water were molinate sulfoxide, 3- and 4-hydroxymolinate, ketohexamethyleneimine and 4-ketomolinate (Verschueren, 1983).

신진 대사 경로

Juvenile white sturgeon and common carp are exposed to 14C-molinate in a flow-through metabolism system and oxidize molinate to form several products and hydrolyze or conjugate with glutathione (GSH), the sulfoxide, or sulfone. Both fish form a D-glucuronic acid conjugate. The higher toxicity of molinate in common carp may be due to greater bioconcentration, slower depuration, and less efficient metabolic deactivation. In the blood of common carp, molinate is oxidized by erythrocytes to the sulfoxide and possibly the sulfone, then conjugated with GSH or cysteine and cleaved to form mercapturic acid in both erythrocytes and plasma. Conjugation and possible hemoglobin carbamylation occur only after sulfoxidation of molinate. Molinate is distributed uniformly throughout the soil layers, and its degradation products are identified as 2-oxomolinate, 4-oxomolinate, molinate acid, and hexamethyleneimine. In rice plants, 4-hydroxymolinate, 2-oxomolinate, 4-oxomolinate, S-ethyl-N-carboxymethylthiocarbamate, molinate acid, and molinate alcohol are detected. By the soil microorganisms, oxidation of the S-ethyl moiety is considered to be the main pathway, and hydroxy and oxoderivatives on the azepine ring are identified.

몰리네이트 준비 용품 및 원자재

원자재

준비 용품


몰리네이트 공급 업체

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Aladdin Scientific
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