과탄산 나트륨

과탄산 나트륨
과탄산 나트륨 구조식 이미지
카스 번호:
15630-89-4
한글명:
과탄산 나트륨
동의어(한글):
나트륨탄산염과산화물;탄산디나트륨염,화합물,함유수소과산화물(2:3);퍼옥시나트륨탄산염;과탄산나트륨;탄산디나트륨염,화합물,함유수소과산화물(H2O2);탄산나트륨·과산화수소화물;과탄산나트륨;소듐카보네이트퍼옥사이드;과탄산 나트륨;PCS;과산화수소를 가진 화합물;다이소듐 카보네이트;소듐 카보네이트 퍼옥시하이드레이트;퍼카보네이트
상품명:
Sodium percarbonate
동의어(영문):
PCS;SODIUM CARBONATE PEROXYHYDRATE;SODIUM CARBONATE PEROXIDE;SODIUM CARBONATE HYDROGEN PEROXIDE;SODIUM PERCARBONATE 13% AVAILABLE OXYGEN;ECOX-C;oxyper;perdox;OxiClean;Oxyper S 142
CBNumber:
CB4853147
분자식:
CH5NaO5
포뮬러 무게:
120.04
MOL 파일:
15630-89-4.mol
MSDS 파일:
SDS

과탄산 나트륨 속성

밀도
2.09[at 20℃]
증기압
< 10-3 Pa at 25°C
물리적 상태
과립분말
색상
하얀색
수소이온지수(pH)
About 10.5 at 1% concentration (20°C)
냄새
냄새 없는
수용성
물에 용해됩니다.
감도
Moisture Sensitive
분해온도
> 131 °F (> 55 °C)
LogP
-0.809 (est)
CAS 데이터베이스
15630-89-4(CAS DataBase Reference)
EPA
Sodium percarbonate (15630-89-4)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 O,Xn
위험 카페고리 넘버 8-22-41-36/38
안전지침서 17-26-39-37/39
유엔번호(UN No.) UN 1479 5.1/PG 3
WGK 독일 1
RTECS 번호 FG0750000
F 고인화성물질 21
TSCA Yes
위험 등급 5.1
포장분류 II
HS 번호 28369990
유해 물질 데이터 15630-89-4(Hazardous Substances Data)
독성 mouse,LD50,oral,2200mg/kg (2200mg/kg),BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)LUNGS, THORAX, OR RESPIRATION: DYSPNEA,Toksikologicheskii Vestnik. Vol. (3), Pg. 46, 1994.
기존화학 물질 KE-05-0572
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H272 화재를 강렬하게 함; 산화제 산화성 액체;산화성 고체 구분 2
구분 3
위험
경고
GHS hazard pictograms P210, P220, P221P280, P370+P378,P501
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 GHS hazard pictograms P280, P305+P351+P338, P310
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P220 의류 그리고 가연성 물질로부터 멀리하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
0
2 1
OX

과탄산 나트륨 MSDS


Sodium percarbonate

과탄산 나트륨 C화학적 특성, 용도, 생산

개요

과탄산소다는 소다회와 과산화수소를 원료로 사용하여 제조되는 백색 과립상의 제품으로 상온에서 안정한 알칼리성의 산소계 표백제입니다.

용도

세제원료, 표백제, 세정제 원료, 폐수처리제, 산소발생제.

화학적 성질

Sodium percarbonate is a white granular powder of sodium carbonate and hydrogen peroxide.
Sodium percarbonate
Sodium percarbonate is mainly used as a bleaching chemical in laundry detergents (tablets, compact or regular powders), laundry additives and machine dishwashing products. It is an oxidizing agent and ingredient in a number of home and laundry cleaning products, including eco-friendly bleach products such as OxiClean and Tide laundry detergent. Dissolved in water, it releases hydrogen peroxide and soda ash (sodium carbonate):
2(Na2CO31.5H202)→2Na2CO3+3H202

용도

Sodium percarbonate is an addition salt of hydrogen peroxide and sodium carbonate that provides a solid source of hydrogen peroxide. When dissolved in water, sodium percarbonate liberates hydrogen peroxide. Sodium percarbonate is a white, granular or powdered solid oxidizer. It is used primarily as a bleaching agent in cleaning products. Other uses include algaecides, fungicides, chemical synthesis and environmental applications such as control of odor at waste treatment facilities. A small amount is used in denture cleaners and toothpaste.
Multifunctional reagent for the preparation of optically active 4-hydroxy-2-isoxazolines.

제조 방법

Sodium percarbonate is produced by the reaction of sodium carbonate with hydrogen peroxide, which can be done via dry, spray and wet processes. In the dry process aqueous hydrogen peroxide solution is sprayed on solid sodium carbonate; a solid-liquid reaction yields sodium percarbonate. In the spray process sodium percarbonate is produced by a fluid bed process. Solutions of sodium carbonate and hydrogen peroxide are sprayed into a drying chamber where the water is evaporated. In the wet process sodium percarbonate is usually prepared by cristallisation possibly in combination with salting out.

화학 반응

Sodium percarbonate naturally decomposes, very slowly, to form sodium carbonate and hydrogen peroxide. The hydrogen peroxide may further decompose to form water and oxygen and liberate some heat. The decomposition proceeds according to the reaction below:
2Na2CO3 • 3H2O2 → 2Na2CO3 + 3H2O + 1.5 O2 + Heat

일반 설명

A colorless, crystalline solid. Denser than water. May combust in contact with organic materials. Contact may irritate skin, eyes and mucous membranes. May be toxic by ingestion. Used to make other chemicals.

공기와 물의 반응

Soluble in water.

반응 프로필

Oxidizing agents, such as SODIUM PERCARBONATE, can react with reducing agents to generate heat and products that may be gaseous (causing pressurization of closed containers). The products may themselves be capable of further reactions (such as combustion in the air). The chemical reduction of materials in this group can be rapid or even explosive, but often requires initiation (heat, spark, catalyst, addition of a solvent). Explosive mixtures of inorganic oxidizing agents with reducing agents often persist unchanged for long periods if initiation is prevented. Such systems are typically mixtures of solids, but may involve any combination of physical states. Some inorganic oxidizing agents are salts of metals that are soluble in water; dissolution dilutes but does not nullify the oxidizing power of such materials. Organic compounds, in general, have some reducing power and can in principle react with compounds in this class. Actual reactivity varies greatly with the identity of the organic compound. Inorganic oxidizing agents can react violently with active metals, cyanides, esters, and thiocyanates.

건강위험

Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.

화재위험

These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.

Safety Profile

Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating vapors

Synthesis

Sodium percarbonate is prepared by the reaction of dihydrogen peroxide and sodium carbonate. The specific synthesis steps are as follows:
With florisil In water addn. of small amounts of MgSiO3 and water glass to 500kg H2O2 (dild. to 20% soln.), addn. of 1051kg Na2CO3 at 18°C, cooling to 5°C, cooling to -4°C after addn. of 500kg NaCl; centrifugation, drying, reuse of mother-liquor, finally sodium percarbonate (yield: 85.5%) is obtained.
Sodium percarbonate synthesis

환경귀착

Sodium percarbonate is not persistent in the environment and readily decomposes to soda ash (sodium carbonate) and hydrogen peroxide which will subsequently decompose to water and oxygen when exposed to soils, sediments, and surface or ground waters.

과탄산 나트륨 준비 용품 및 원자재

원자재

준비 용품


과탄산 나트륨 공급 업체

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