염화나트륨

염화나트륨
염화나트륨 구조식 이미지
카스 번호:
7647-14-5
한글명:
염화나트륨
동의어(한글):
ROCK염;바다소금;벌크공업적인천연의태양의;식탁용소금;염;염,화이트결정,태양의;염화나트륨(SODIUMCHLORDE;할리트;1N(1M)염화나트륨;N/10-염화나트륨(0.1M);N/100-염화나트륨(0.01M);공업염;공통염;나트륨표준(100PPMNA);나트륨모노염화물;염화나트륨;염화나트륨(SODIUMCHLORIDE);소듐클로라이드;씨솔트
상품명:
Sodium chloride
동의어(영문):
NaCl;CHLORIDE;prop-2-en-1-amine;SALT;SALINE;SEA SALT;PAD;Sodium chloride solution;Sodium chloride (NaCl);COMMON SALT
CBNumber:
CB4104636
분자식:
ClNa
포뮬러 무게:
58.44
MOL 파일:
7647-14-5.mol

염화나트륨 속성

녹는점
801 °C (lit.)
끓는 점
1465 °C/1 atm (lit.)
밀도
1.199 g/mL at 20 °C
벌크 밀도
1140kg/m3
증기압
1 mm Hg ( 865 °C)
굴절률
n20/D 1.378
인화점
1413°C
저장 조건
+15C to +30C
용해도
H2O: 용해성
물리적 상태
플레이크 크리스탈
Specific Gravity
2.165
색상
하얀색
수소이온지수(pH)
5.5-6.5(1 tablet in 100 mL purified water)
Flame Color
Orange
수용성
360g/L(20℃)
감도
Hygroscopic
최대 파장(λmax)
λ: 260 nm Amax: 0.02
λ: 280 nm Amax: 0.01
Crystal Structure
NaCl type
crystal system
Cube
Merck
14,8599
BRN
3534976
Space group
Fm3m
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.5640.5640.5649090900.17942
Dielectric constant
5.9(Ambient)
BCS Class
1
안정성
안정적인. 강한 산화제와 호환되지 않습니다.
화장품 원료 기능
ORAL CARE
HUMECTANT
BULKING
ABRASIVE
VISCOSITY CONTROLLING
FRAGRANCE
SKIN CONDITIONING
InChI
1S/ClH.Na/h1H;/q;+1/p-1
InChIKey
FAPWRFPIFSIZLT-UHFFFAOYSA-M
SMILES
[Na+].[Cl-]
CAS 데이터베이스
7647-14-5(CAS DataBase Reference)
NIST
Sodium chloride(7647-14-5)
EPA
Sodium chloride (7647-14-5)
Absorption
≤0.01 at 260
≤0.01 at 280 in H2O at 1M
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36-36/37/38-22
안전지침서 24/25-26-36
WGK 독일 1
RTECS 번호 VZ4725000
F 고인화성물질 3-10
TSCA TSCA listed
HS 번호 38220000
스토리지 클래스 13 - Non Combustible Solids
유해 물질 데이터 7647-14-5(Hazardous Substances Data)
독성 LD50 orally in rats: 3.75 ±0.43 g/kg (Boyd, Shanas)
기존화학 물질 KE-31387
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H303 삼키면 유해할 수 있음 급성 독성 물질 - 경구 구분 5 P312
예방조치문구:
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P403 환기가 잘 되는 곳에 보관하시오.
NFPA 704
0
1 1

염화나트륨 MSDS


Sodium chloride

염화나트륨 C화학적 특성, 용도, 생산

개요

염화 나트륨(鹽化-, NaCl)은 염소와 나트륨의 화합물로 식용 소금의 주성분이다. 해수의 염류 중 차지하는 비율이 가장 많다. 염화 나트륨은 나트륨 이온(Na+)과 염화 이온(Cl-)이 결합하여 극성 구조를 가지기에 같은 극성 용매인 물에 잘 녹는다.염화 나트륨의 결정 구조는 팔면체를 띠는 각 원자는 6개의 가장 가까운 이웃을 가지고 있는 형태이다. 앙금이 아닌 수용성 염이다.

용도

양념, 식품의 저장, 화학 공업의 원료 따위로 쓴다.

개요

Sodium chloride is widely distributed in nature. Oceans are the vast source of sodium chloride. It occurs in seawater at an average concentration of 2.68 wt%. It also occurs in many inland saline waters and in salt deposits in sedimentary rocks, as the mineral halite.
Sodium chloride
Sodium chloride is probably the most important salt of both sodium and chlorine. Sodium chloride, common table salt, is an essential component of most food preparation, imparting flavor to food and providing the sodium nutritional requirement. Also, it is used for preserving food. Therapeutically, NaCl solution is used to combat dehydration as an electrolyte replenisher, and it is an emetic.
The most important applications of sodium chloride in the chemical industry are in making a number of important industrial chemicals such as hydrochloric acid, sodium hydroxide, sodium carbonate, and metallic sodium. It is the starting material in manufacturing these substances. Other uses are in dyeing and printing fabrics, glazing pottery, in making soap, and for curing hides. Sodium chloride is a component of many freezing mixtures.

물리적 성질

Sodium chloride is the familiar compound commonly referred to as salt or table salt. Its mineral form, called halite, is found in natural deposits worldwide and constitutes approximately 2.7% by weight of the dissolved minerals in seawater. As an ionic compound, it exists as a white crystalline solid with a cubic structure composed of alternating sodium and chloride ions. Sodium chloride is essential for life, with the average adult requiring an intake of about 1 to 2 grams per day. It supplies sodium, which performs numerous vital functions, including maintaining cellular water balance, facilitating nerve signal transmission, and enabling muscle contraction.
Sodium chloride, NaCl crystal structure
The space lattice of NaCl belongs to the cubic system, and its rock salt structure has a lattice constant of a=0.55870 nm and Na–Cl=0.27935 nm. The cleavage plane is (100).

용도

sodium chloride (table salt) is used as a preservative, astringent, and anti-septic to treat inflamed lesions. It can also be used to mask odor, reduce product density, and control viscosity. Diluted solutions are not considered irritating.

제조 방법

Sodium chloride is produced by solar evaporation of seawater or brine from underground salt deposits. It also is produced by mining rock salt. The commercial product contains small amounts of calcium and magnesium chlorides.

생산 방법

Sodium chloride occurs naturally as the mineral halite. Commercially, it is obtained by the solar evaporation of sea water, by mining, or by the evaporation of brine from underground salt deposits.

정의

ChEBI: Sodium chloride is an inorganic chloride salt with sodium(1+) as the counterion. Chemically, a salt is a compound produced by the neutralization reaction between an acid and a base, where the acid's hydrogen ions are replaced by metal or other cations. While most salts (e.g., NaCl, NH₄NO₃) are crystalline ionic compounds, certain covalent metal compounds like TiCl₄ are also broadly categorized as salts.

일반 설명

A white crystalline solid. Commercial grade usually contains some chlorides of calcium and magnesium which absorb moisture and cause caking.

공기와 물의 반응

Water soluble.

반응 프로필

Sodium chloride is generally unreactive. Releases gaseous hydrogen chloride if mixed with a concentrated nonvolatile acid such as sulfuric acid.

화재위험

Literature sources indicate that Sodium chloride is nonflammable.

농업용

Halite is a naturally occurring sodium chloride (NaCl) deposit. The most abundant potash mineral deposit is sylvite (KCl). Sylvite with halite forms the common potash ore, called sylvinite.

Pharmaceutical Applications

Sodium chloride is widely used in a variety of parenteral and nonparenteral pharmaceutical formulations, where the primary use is to produce isotonic solutions.
Sodium chloride has been used as a lubricant and diluent in capsules and direct-compression tablet formulations in the past, although this practice is no longer common. Sodium chloride has also been used as a channeling agent and as an osmotic agent in the cores of controlled-release tablets. It has been used as a porosity modifier in tablet coatings, and to control drug release from microcapsules.
The addition of sodium chloride to aqueous spray-coating solutions containing hydroxypropyl cellulose or hypromellose suppresses the agglomeration of crystalline cellulose particles.(13) Sodium chloride can also be used to modify drug release from gels and from emulsions. It can be used to control micelle size, and to adjust the viscosity of polymer dispersions by altering the ionic character of a formulation.

Safety Profile

Poison by intraperitoneal and intracervical routes. Moderately toxic by ingestion, intravenous, and subcutaneous routes. An experimental teratogen. Human systemic effects by ingestion: blood pressure increase. Human reproductive effects by intraplacental route: terminates pregnancy. Experimental reproductive effects. Human mutation data reported. A skin and eye irritant. When bulk sodium chloride is heated to high temperature, a vapor is emitted that is irritating, particularly to the eyes. Ingestion of large amounts of sodium chloride can cause irritation of the stomach. Improper use of salt tablets may produce this effect. Potentially explosive reaction with dichloromaleic anhydride + urea. Electrolysis of mixtures with nitrogen compounds may form the explosive nitrogen trichloride. Reaction with burning lithmm forms the dangerously reactive sodmm. The molten salt at 11 00' reacts explosively with water. Violent reaction with BrF3. When heated to decomposition it emits toxic fumes of Cland Na2O.

Safety

Sodium chloride is the most important salt in the body for maintaining the osmotic tension of blood and tissues. About 5–12 g of sodium chloride is consumed daily, in the normal adult diet, and a corresponding amount is excreted in the urine. As an excipient, sodium chloride may be regarded as an essentially nontoxic and nonirritant material. However, toxic effects following the oral ingestion of 0.5–1.0 g/kg body-weight in adults may occur. The oral ingestion of larger quantities of sodium chloride, e.g. 1000 g in 600mL of water, is harmful and can induce irritation of the gastrointestinal tract, vomiting, hypernatremia, respiratory distress, convulsions, or death.
In rats, the minimum lethal intravenous dose is 2.5 g/kg bodyweight.
LD50 (mouse, IP): 6.61 g/kg
LD50 (mouse, IV): 0.65 g/kg
LD50 (mouse, oral): 4.0 g/kg
LD50 (mouse, SC): 3.0 g/kg
LD50 (rat, oral): 3.0 g/kg

저장

Aqueous sodium chloride solutions are stable but may cause the separation of glass particles from certain types of glass containers. Aqueous solutions may be sterilized by autoclaving or filtration. The solid material is stable and should be stored in a well-closed container, in a cool, dry place.
It has been shown that the compaction characteristics and the mechanical properties of tablets are influenced by the relative humidity of the storage conditions under which sodium chloride was kept.

Purification Methods

It is recrystallised from a saturated aqueous solution (2.7mL/g) by passing in HCl gas, or by adding EtOH or acetone. It can be freed from bromide and iodide impurities by adding chlorine water to an aqueous solution and boiling it for some time to expel free bromine and iodine. Traces of iron can be removed by prolonged boiling of solid NaCl in 6M HCl; the crystals are then washed with EtOH and dried at ca 100o. Sodium chloride has been purified by sublimation in a stream of pre-purified N2 and collected by electrostatic discharge [Ross & Winkler J Am Chem Soc 76 2637 1954]. For use as a primary analytical standard, analytical reagent grade NaCl should be finely ground, dried in an electric furnace at 500-600o in a platinum crucible, and allowed to cool in a desiccator. For most purposes, however, drying at 110-120o is satisfactory.

비 호환성

Aqueous sodium chloride solutions are corrosive to iron. They also react to form precipitates with silver, lead, and mercury salts. Strong oxidizing agents liberate chlorine from acidified solutions of sodium chloride. The solubility of the antimicrobial preservative methylparaben is decreased in aqueous sodium chloride solutions and the viscosity of carbomer gels and solutions of hydroxyethyl cellulose or hydroxypropyl cellulose is reduced by the addition of sodium chloride.

Regulatory Status

GRAS listed. Included in the FDA Inactive Ingredients Database (injections; inhalations; nasal, ophthalmic, oral, otic, rectal, and topical preparations). Included in nonparenteral and parenteral medicines licensed in the UK. Included in the Canadian List of Acceptable Non-medicinal Ingredients.

염화나트륨 준비 용품 및 원자재

원자재

준비 용품


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