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3-아세틸피리딘

3-아세틸피리딘 구조식 이미지

카스 번호:: 350-03-8

한글명:: 3-아세틸피리딘

동의어(한글):: 3-아세틸피리딘

상품명:: 3-Acetylpyridine

동의어(영문):: 3-Acetylpiridine;methylpyridylketone;1-(3-PYRIDINYL)ETHANONE;Ethanone,1-(3-pyridinyl)-;NSC 761;FEMA 3424;Imatinib-int A;3-ActylPyridine;3-ACETOPYRIDINE;3-ACETYLPYRIDNE

CBNumber:: CB9286704

분자식:: C7H7NO

포뮬러 무게:: 121.14

MOL 파일:: 350-03-8.mol

Request For Quotation

속성 안전 MSDS 용도 공급 업체 566

3-아세틸피리딘 속성

녹는점: 11-13 °C (lit.)

끓는 점: 220 °C (lit.)

밀도: 1.102 g/mL at 25 °C (lit.)

FEMA: 3424 | 3-ACETYLPYRIDINE

굴절률: n20/D 1.534(lit.)

인화점: 302 °F

저장 조건: Inert atmosphere,Room Temperature

산도 계수 (pKa): pK1: 3.256(+1) (25°C)

물리적 상태: Liquid

색상: Clear colorless to yellow

Specific Gravity: 1.102

수소이온지수(pH): 6.5-7.5 (H2O, 20℃)

수용성: SOLUBLE IN HOT WATER

Merck: 14,6116

JECFA Number: 1316

BRN: 107751

InChIKey: WEGYGNROSJDEIW-UHFFFAOYSA-N

CAS 데이터베이스: 350-03-8(CAS DataBase Reference)

NIST: Ethanone, 1-(3-pyridinyl)-(350-03-8)

EPA: Ethanone, 1-(3-pyridinyl)- (350-03-8)

안전

위험 및 안전 성명
위험 및 사전주의 사항 (GHS)

위험품 표기	T,Xi,Xn
위험 카페고리 넘버	25-36/38-36/37/38-20/21/22
안전지침서	45-37/39-28A-26-36
유엔번호(UN No.)	UN 2810 6.1/PG 3
WGK 독일	3
RTECS 번호	OB5425000
F 고인화성물질	8-10
위험 참고 사항	Irritant
TSCA	Yes
위험 등급	6.1
포장분류	II
HS 번호	29333999
독성	LD50 orl-rat: 46 mg/kg JACTDZ 1,681,92

그림문자(GHS):

신호 어:

Danger

유해·위험 문구:

암호	유해·위험 문구	위험 등급	범주	신호 어	P- 코드
H300	삼키면 치명적임	급성 독성 물질 - 경구	구분 1,2	위험	P264, P270, P301+P310, P321, P330,P405, P501
H301	삼키면 유독함	급성 독성 물질 - 경구	구분 3	위험	P264, P270, P301+P310, P321, P330,P405, P501
H315	피부에 자극을 일으킴	피부부식성 또는 자극성물질	구분 2	경고	P264, P280, P302+P352, P321,P332+P313, P362
H319	눈에 심한 자극을 일으킴	심한 눈 손상 또는 자극성 물질	구분 2A	경고	P264, P280, P305+P351+P338,P337+P313P

예방조치문구:

P264	취급 후에는 손을 철저히 씻으시오.
P264	취급 후에는 손을 철저히 씻으시오.
P270	이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P280	보호장갑/보호의/보안경/안면보호구를 착용하시오.
P309	노출되었거나 몸이 편치 않은 경우
P310	즉시 의료기관(의사)의 진찰을 받으시오. 삼켰다면 즉시 의료기관(의사)의 도움을 받으시오.
P301+P310	삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P305+P351+P338	눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P405	밀봉하여 저장하시오.
P501	...에 내용물 / 용기를 폐기 하시오.

NFPA 704

	0
3		0

3-아세틸피리딘 MSDS

Methyl 3-pyridyl ketone

3-아세틸피리딘 C화학적 특성, 용도, 생산

화학적 성질

clear colorless to yellow liquid

출처

Reported found in roasted filberts, beer, brandy, coffee, malt and wheaten bread.

용도

3-Acetylpyridine used as an intermediate for the synthesis of risedronate sodium, inhibitor of bone resorption. It is also used in perfumery.

제조 방법

Dry distillation of calcium nicotinate with calcium acetate.

정의

It is a nicotinic acidantagonist.

Safety Profile

Poison by ingestion. Moderately toxic by intraperitoneal routeMutation data reported. A flammable liquid. When heated to decomposition emits toxic fumes of NOx,. See also KETONES

Purification Methods

It is purified by dissolving in HCl, extracting with Et2O to remove the possible impurity of nicotinic acid, basified with NaOH and extracted with Et2O. The dried extract is filtered, evaporated and the residual oil is distilled. If the NMR spectrum indicates further impurities, then convert it to the phenylhydrazone (m 137o, yellow needles from EtOH). This is hydrolysed with HCl [Engler & Kiby Chem Ber 22 597 1889], the phenylhydrazine HCl is removed by filtration, NaNO2 is added, the solution is basified with aqueous NaOH and extracted with Et2O as before and distilled at atmospheric pressure to give 3-acetylpyridine as a colourless oil. Purification can also be achieved by shaking with 50% aqueous KOH, extracting with Et2O, drying the extract and distilling it at atmospheric pressure or in vacuo. [Kloetzel & Chubb J Am Chem Soc 79 4226 1957.] The hydrochloride has m 180-181o (from MeOH/EtOH), the picrate has m 133.8-134.8o (from H2O), and the phenylhydrazone has m 137o (129-130o)(needles, from EtOH) [Webb & Webb J Am Chem Soc 71 2285 1949]. The ketoxime has m 112o (from EtOH or *C6H6). [Strong & McElvain J Am Chem Soc 55 816 1933, Kolloff & Hunter J Am Chem Soc 63 490 1941, Beilstein 21/7 V 394.]

3-아세틸피리딘 준비 용품 및 원자재

원자재

니코틴산 아세트산 칼슘 (S)-1-(3-PYRIDYL)ETHANOL

준비 용품

5-(Pyridin-3-yl)-1H-pyrazole-3-carboxamide ,97% 3-ACETYL-2-CHLOROPYRIDINE 5-PYRIDIN-3-YL-1H-PYRAZOLE-3-CARBOXYLIC ACID 1-(3-Pyridyl)-3-(dimethylamino)-2-propen-1-one ETHYL 3-PYRIDYLACETATE 3-(2-Bromoacetyl)pyridine hydrobromide 5-(PYRIDIN-3-YL)-1H-PYRAZOLE-3-CARBOXYLIC ACID ETHYL ESTER 4-(3-Pyridinyl)-2-aminopyrimidine 5-(Pyridin-3-yl)-1H-pyrazole-3-carbohydrazide ,97% 2-Amino-3-acetylpyridine 5-Acetyl-2-cyanopyridine 4-Methyl-3-[[4-(3-pyridinyl)-2-pyrimidinyl]amino]benzoic acid 1-(1-Oxido-3-pyridinyl)-ethanone 1H-Pyrrole-2-carboxylicacid,4-formyl-,methylester(9CI) 4-Methyl-3-[[4-(3-pyridinyl)-2-pyrimidinyl]amino]benzoic acid methyl ester

3-아세틸피리딘 공급 업체

글로벌( 566)공급 업체

공급자	전화	이메일	국가	제품 수	이점
Anqing Chico Pharmaceutical Co., Ltd.	15380796838	chloewu@chicopharm.cn	CHINA	341	58
Henan DaKen Chemical CO.,LTD.	+86-371-66670886	info@dakenchem.com	China	16666	58
Hi-Tech Chemistry Corp	0519-86626038	yuhh@hitechem.com	CHINA	811	58
Henan Tianfu Chemical Co.,Ltd.	0371-55170693	info@tianfuchem.com	China	22021	55
Hangzhou FandaChem Co.,Ltd.	+8615858145714	fandachem@gmail.com	China	9382	55
Guangzhou PI PI Biotech Inc	+8618371201331	87478684@qq.com	China	3640	55
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418679	info@tnjchem.com	China	2995	55
Shanghai Zheyan Biotech Co., Ltd.	18017610038	zheyansh@163.com	CHINA	3623	58
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29959	58
Zhejiang ZETian Fine Chemicals Co. LTD	18957127338	stella@zetchem.com	China	2010	58

3-아세틸피리딘 관련 검색:

아세트산 메틸 아크릴산메틸 메틸알콜 쿠레톡심메틸 이염화파라콰트 메틸파라벤 2,4-펜탄디온 아세토나이트릴 3-아세틸피리딘 메틸 바이올렛 (2B) 4-아세틸피리딘 2,6-디아세틸피리딘 2-아세틸피리딘 4-Chloromethyl-N-[4-methyl-3-[[4-(pyridin-3-yl)pyrimidin-2-yl]amino]phenyl]benzamide N-DESMETHYL IMATINIB Imatinib Impurity 7 1-(3-Pyridyl)-3-(dimethylamino)-2-propen-1-one N-(5-Amino-2-methylphenyl)-4-(3-pyridyl)-2-pyrimidineamine