ChemicalBook
Chinese English Japanese Germany Korea

안스라닐산메틸

안스라닐산메틸
안스라닐산메틸 구조식 이미지
카스 번호:
134-20-3
한글명:
안스라닐산메틸
동의어(한글):
메틸안트라닐레이트;안스라닐산메틸;안트라닐산메릴;메틸안트라닐레이트
상품명:
Methyl anthranilate
동의어(영문):
NEROLI;FEMA 2682;Nevoli oil;2-AMinobenzoic;Methyl anthanilate;methyl anthranlate;Methyl antranilate;METHYL ANTHRANILATE;Carbomethoxyaniline;Methyl anthranylate
CBNumber:
CB0722306
분자식:
C8H9NO2
포뮬러 무게:
151.16
MOL 파일:
134-20-3.mol

안스라닐산메틸 속성

녹는점
24 °C(lit.)
끓는 점
256 °C(lit.)
밀도
1.168 g/mL at 25 °C(lit.)
증기압
1 mm Hg ( 20 °C)
굴절률
n20/D 1.582(lit.)
FEMA
2682 | METHYL ANTHRANILATE
인화점
220 °F
저장 조건
-20°C Freezer
용해도
alcohol: freely soluble(lit.)
물리적 상태
Liquid
산도 계수 (pKa)
pK1:2.23(+1) (25°C)
색상
Clear yellow-brown
수소이온지수(pH)
7.5-8 (H2O, 20℃)Aqueous solution
폭발한계
1.4-7.8%(V)
수용성
slightly soluble
감도
Air Sensitive
Merck
14,6020
JECFA Number
1534
BRN
606965
안정성
Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey
VAMXMNNIEUEQDV-UHFFFAOYSA-N
CAS 데이터베이스
134-20-3(CAS DataBase Reference)
NIST
Benzoic acid, 2-amino-, methyl ester(134-20-3)
EPA
Benzoic acid, 2-amino-, methyl ester(134-20-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 36/37/38
안전지침서 26-36-37/39
WGK 독일 1
RTECS 번호 CB3325000
F 고인화성물질 21
자연 발화 온도 986 °F
TSCA Yes
HS 번호 29224995
유해 물질 데이터 134-20-3(Hazardous Substances Data)
독성 LD50 orally in rats, mice: 2910, 3900 mg/kg, P. M. Jenner et al., Food Cosmet. Toxicol. 2, 327 (1964)
그림문자(GHS):
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H303 삼키면 유해할 수 있음 급성 독성 물질 - 경구 구분 5 P312
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 P264, P280, P302+P352, P321,P332+P313, P362
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 P264, P280, P305+P351+P338,P337+P313P
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

안스라닐산메틸 MSDS


Methyl anthranilate

안스라닐산메틸 C화학적 특성, 용도, 생산

개요

Methyl anthranilate, also known as MA, methyl 2-amino benzoate or carbo methoxy aniline, is an ester of anthranilic acid. Its chemical formula is C8H9NO2.

화학적 성질

Methyl Anthranilate occurs in a large number of blossom essential oils (e.g., neroli, ylang-ylang, and jasmine oils), grapes, and citrus oils. It occurs as white crystals (mp 24–25°C), or a yellowish liquid, that show blue fluorescence and have an orange blossom odor. Methyl anthranilate is prepared by esterification of anthranilic acid with methanol or by reaction of isatoic anhydride with methanol.
It is used in a large number of blossom fragrances. However, its use in perfumes for soaps and cosmetics is limited because it causes discoloration. It is used in flavor compositions (e.g., in grape and citrus flavors).

화학적 성질

Methyl anthranilate has a characteristic orange-flower odor and a slightly bitter, pungent taste. May be prepared by heating anthranilic acid and methyl alcohol in the presence of sulfuric acid and subsequent distillation.

화학적 성질

Methyl anthranilate has a characteristic orange-flower odor and slightly bitter, pungent taste.

화학적 성질

yellow to orange liquid with a smell of orange blossom

출처

Methyl anthranilate naturally occurs in the Concord grapes and other Vitis labrusca grapes or hybrids thereof, and in bergamot, black locust, champaca , gardenia, jasmine, lemon, mandarin, neroli, oranges, rue oil, strawberry, tuberose, wisteria, galangal and ylang ylang. It is also a primary component of the essential apple flavor, along with ethyl acetate and ethyl butyrate.It is also secreted by the musk glands of foxes and dogs, and lends a "sickly sweetness" to the smell of rotting flesh.

용도

Methyl anthranilate acts as a bird repellent. It is food-grade and can be used to protect corn, sunflowers, rice, fruit, and golf courses. Dimethyl anthranilate (DMA) has a similar effect. It is also used for the flavor of grape Kool Aid. It is used for flavoring of candy, soft drinks (e.g. grape soda), gums, and drugs.
Methyl anthranilate both as a component of various natural essential oils and as a synthesised aroma-chemical is used extensively in modern perfumery . It is also used to produce Schiff's Bases with aldehydes, many of which are also used in perfumery. In a perfumery context the most common Schiff's Base is known as aurantiol - produced by combining methyl anthranilate and hydroxyl citronellal.

용도

A useful synthetic intermediate.

용도

As perfume for ointments; manufacture of synthetic perfumes.

정의

ChEBI: A benzoate ester that is the methyl ester of anthranilic acid.

제조 방법

By heating anthranilic acid and methyl alcohol in the presence of sulfuric acid and subsequent distillation.

Aroma threshold values

Detection: 3 ppb

Taste threshold values

Taste characteristics at 25 ppm: sweet, fruity, concord grape, with a musty and berry nuance.

일반 설명

Clear colorless to tan liquid with an odor of grapes. Has light blue fluorescence.

공기와 물의 반응

Methyl anthranilate is sensitive to air and light. Slightly water soluble .

반응 프로필

An amine and ester. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

화재위험

Methyl anthranilate is combustible.

Safety Profile

Moderately toxic by ingestion. Experimental reproductive effects. A skin irritant. See also ESTERS. Combustible liquid. When heated to decomposition it emits toxic fumes of NOx.

Toxicology

Methyl anthranilate is a colorless liquid that has a sweet, fruity, grape-like flavor. It is found in the essential oils of orange, lemon, and jasmine and has been widely used to create imitation Concord grape flavor. Table 10.8 shows the acute toxicity of methyl anthranilate. Methyl anthranilate promotes some allergic reactions on human skin, which has led to it being prohibited for use in cosmetic products.

안스라닐산메틸 준비 용품 및 원자재

원자재

준비 용품


안스라닐산메틸 공급 업체

글로벌( 308)공급 업체
공급자 전화 팩스 이메일 국가 제품 수 이점
JingJiang Connect Chemical manufacturing Co., Ltd.
0523-80501690 15252623102
0523-84506952 andy@katchemical.com CHINA 59 55
Capot Chemical Co.,Ltd.
+86 (0)571-855 867 18
+86 (0)571-858 647 95 sales@capotchem.com China 19919 60
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21924 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20680 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32457 55
Hefei TNJ Chemical Industry Co.,Ltd.
86-0551-65418684 18949823763
86-0551-65418684 info@tnjchem.com China 1750 55
Chongqing Chemdad Co.,Ltd
+86-19923101450
sales@chemdad.com CHINA 342 58
Xiamen AmoyChem Co., Ltd
+86 (0)592-605 1114
sales@amoychem.com CHINA 6374 58
Henan Xiangtong Chemical Co., Ltd.
86-371-61312303
86-371-86017988 xtchem2019@gmail.com CHINA 157 58
Shanghai Zheyan Biotech Co., Ltd.
18017610038
zheyansh@163.com CHINA 3623 58

안스라닐산메틸 관련 검색:

Copyright 2019 © ChemicalBook. All rights reserved