ChemicalBook--->CAS DataBase List--->18368-64-4

18368-64-4

18368-64-4 Structure

18368-64-4 Structure
IdentificationMore
[Name]

2-Chloro-5-methylpyridine
[CAS]

18368-64-4
[Synonyms]

2-CHLORO-5-METHYLPYRIDINE
2-CHLORO-5-PICOLINE
6-CHLORO-3-METHYL PYRIDINE
6-CHLORO-3-PICOLINE
2-chloro-5-methyl-pyridin
2-chloro-5-methylpyrdine
2-CHLORO-5-METHYLPYRIDINE,97%
2-CHLORO-5-PICOLINE 2-CHLORO-5-METHYLPYRIDINE
2-CHLORO-5-METHYLPYRIDINE (2-CHLORO-5-PICOLINE)
2-Chloro-3-methypyridine
2-Chloro-5-methylpyridine ,95%
[EINECS(EC#)]

418-050-0
[Molecular Formula]

C6H6ClN
[MDL Number]

MFCD00792460
[Molecular Weight]

127.57
[MOL File]

18368-64-4.mol
Chemical PropertiesBack Directory
[Appearance]

clear light yellow to straw-yellow liquid
[Boiling point ]

97 °C/30 mmHg (lit.)
[density ]

1.169 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.53(lit.)
[Fp ]

195 °F
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[form ]

Liquid
[pka]

0.54±0.10(Predicted)
[color ]

Clear light yellow to straw-yellow or light pink-orange
[Specific Gravity]

1.169
[Water Solubility ]

Slightly soluble in water.
[Detection Methods]

GC
[InChI]

InChI=1S/C6H6ClN/c1-5-2-3-6(7)8-4-5/h2-4H,1H3
[InChIKey]

VXLYOURCUVQYLN-UHFFFAOYSA-N
[SMILES]

C1(Cl)=NC=C(C)C=C1
[CAS DataBase Reference]

18368-64-4(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302+H312-H315-H412
[Precautionary statements ]

P273-P280-P301+P312+P330-P302+P352+P312
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R21/22:Harmful in contact with skin and if swallowed .
R38:Irritating to the skin.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S25:Avoid contact with eyes .
S36/37:Wear suitable protective clothing and gloves .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

2
[RTECS ]

US6740000
[REACH Registrations]

Active
[HS Code ]

29333990
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Acute Tox. 4 Dermal
Acute Tox. 4 Oral
Aquatic Chronic 3
Skin Irrit. 2
[Toxicity]

rat,LD50,oral,1gm/kg (1000mg/kg),National Technical Information Service. Vol. OTS0545693,
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrochloric acid-->Sodium nitrite-->Chlorobenzene-->Diisopropylamine-->Acetamide-->Propylene-->2-Amino-5-methylpyridine-->2-Chloro-3-methylpyridine-->3-Picoline-N-oxide-->Nitrous acid methyl ester
[Preparation Products]

Admire-->2-Chloronicotinic acid-->2-Chloro-5-trifluoromethylpyridine-->2-Chloro-5-(chloromethyl)pyridine-->2,3-Dichloro-5-(trifluoromethyl)pyridine-->6-Boc-hydrazinonicotinic acid-->6-(Methylthio)pyridine-3-carboxylic acid-->Acetamiprid-->2-Mercapto-5-methylpyridine-->Pyridine, 5-(bromomethyl)-2-chloro- (9CI)-->2-Chloro-5-methylpyridine-3-carboxylic acid-->2-Pyridinecarboxylicacid,5-methyl-,methylester(9CI)-->2-chloro-5-methylpyridin-4-amine
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Chloro-5-methylpyridine(18368-64-4).msds
Hazard InformationBack Directory
[Chemical Properties]

clear light yellow to straw-yellow liquid
[Uses]

2-Chloro-5-methylpyridine may be used in the synthesis of:
  • 2-methylthio-5-pyridinemethylene amine
  • 5-methyl-2,2′-bipyridine
  • 1-(5′-methyl-2,2′-bipyridin-5-yl)-2,5-dimethyl-1H-pyrrole
[General Description]

2-Chloro-5-methylpyridine is a pesticide intermediate. Its synthesis by many methods has been reported.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Chloro-5-methylpyridine(18368-64-4)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Chloro-5-picoline, 94%(18368-64-4)
[Sigma Aldrich]

18368-64-4(sigmaaldrich)
[TCI AMERICA]

6-Chloro-3-picoline,>97.0%(GC)(18368-64-4)
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