Ammoniak, wssrige Lsung Chemische Eigenschaften,Einsatz,Produktion Methoden
ERSCHEINUNGSBILD
LEICHT FLüCHTIGE, FARBLOSE LöSUNG VON AMMONIAK IN WASSER MIT STECHENDEM GERUCH.
CHEMISCHE GEFAHREN
Reagiert mit vielen Schwermetallen und -salzen unter Bildung explosionsfähiger Verbindungen. Greift viele Metalle unter Bildung brennbarer/explosionsfähiger Gase an (z.B. Wasserstoff, ICSC-Nr. 0001). Die wässrige Lösung ist eine starke Base, sie reagiert sehr heftig mit Säuren.
ARBEITSPLATZGRENZWERTE
TLV: (als NH_3) 25 ppm (als TWA); 35 ppm (als STEL); (ACGIH 2005).
MAK: 20 ppm, 14 mg/m? Spitzenbegrenzung: überschreitungsfaktor I(2); Schwangerschaft: Gruppe C; (DFG 2005).
AUFNAHMEWEGE
Aufnahme in den Körper durch Inhalation der Dämpfe oder des Aerosols und durch Verschlucken.
INHALATIONSGEFAHREN
Beim Verdampfen bei 20°C kann sehr schnell eine gesundheitsschädliche Kontamination der Luft eintreten.
WIRKUNGEN BEI KURZZEITEXPOSITION
WIRKUNGEN BEI KURZZEITEXPOSITION: Die Substanz verätzt die Augen, die Haut und die Atemwege. ätzend beim Verschlucken. Inhalation hoher Dampfkonzentrationen kann zu Kehlkopfödem, Entzündungen der Atemwege und Lungenentzündung führen. Die Auswirkungen treten u.U. verzögert ein.
WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION
Risiko der Lungenschädigung bei wiederholter oder längerer Dampf- oder Aerosol-Exposition.
LECKAGE
Gefahrenbereich verlassen! Fachmann zu Rate ziehen bei großen Mengen verschütteten Materials! Belüftung. Ausgelaufene Flüssigkeit vorsichtig mit verdünnter Säure, z.B. verdünnter Schwefelsäure neutralisieren. Reste mit viel Wasser wegspülen. NICHT in die Umwelt gelangen lassen. Persönliche Schutzausrüstung: Vollschutzanzug mit umgebungsluftunabhängigem Atemschutzgerät.
R-Sätze Betriebsanweisung:
R34:Verursacht Verätzungen.
R50:Sehr giftig für Wasserorganismen.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Aussehen Eigenschaften
NH5O, Salmiakgeist. 25 %ige Lösung in Wasser. Farblose Flüssigkeit mit stechendem Geruch.
Gefahren für Mensch und Umwelt
Verursacht Verätzungen. Reizt die Atmungsorgane. Einatmen führt zu Reizungen bis hin zum Lungenödem. Nach Verschlucken kommt es zu blutigem Erbrechen. Perforationsgefahr besteht für Magen und Speiseröhre.
Nicht mit Laugen, Iod und starken Säuren in Berührung bringen.
LD
50 (oral, Ratte): 350 mg/kg
Schutzmaßnahmen und Verhaltensregeln
Geeignete Schutzhandschuhe als kurzzeitiger Spritzschutz.
Verhalten im Gefahrfall
Dämpfe nicht einatmen.
Mit flüssigkeitsbindendem Material, z.B. Rench Rapid aufnehmen. Der Entsorgung zuführen. Nachreinigen.
Wasser, Schaum.
Im Brandfall kann Ammoniak freigesetzt werden. Dämpfe mit Wasser niederschlagen.
Erste Hilfe
Nach Hautkontakt: Mit reichlich Wasser abspülen. Abtupfen mit Polyethylenglycol 400.
Nach Augenkontakt: Mit reichlich Wasser bei geöffnetem Lidspalt mindestens 10 Minuten ausspülen. Sofort Augenarzt hinzuziehen.
Nach Einatmen: Frischluft. Arzt hinzuziehen.
Nach Verschlucken: Reichlich Wasser trinken lassen. Erbrechen vermeiden (Perforationsgefahr!). Sofort Arzt hinzuziehen. Keine Neutralisationsversuche!
Nach Kleidungskontakt: Kontaminierte Kleidung sofort entfernen.
Ersthelfer: siehe gesonderten Anschlag
Sachgerechte Entsorgung
Nach vorsichtiger Neutralisation mit z.B. Salzsäure zu den wässrigen, alkalischen Salzlösungen geben.
Beschreibung
Ammonium hydroxide is a colorless, liquid solution with a characteristic and pungent odor. It is ammonia combined with water. Ammonia (NH3) is a compound consisting of nitrogen and hydrogen. Both ammonia and ammonium hydroxide are very common compounds, found naturally in the environment (in air, water, and soil) and in all plants and animals, including humans. Ammonia is a source of nitrogen, an essential element for plants and animals. Ammonia is also produced by the human body – by our organs and tissues and by beneficial bacteria living in our intestines.
Ammonia plays an important role in protein synthesis in the human body. In brief summary, all living things need proteins, which are comprised of some 20 different amino acids. While plants and microorganisms can synthesize most amino acids from the nitrogen in the atmosphere, animals cannot. For humans, some amino acids cannot be synthesized at all and must be consumed as intact amino acids. Other amino acids, however, can be synthesized by microorganisms in the gastrointestinal tract with the help of ammonia ions. Thus, ammonia is a key player in the nitrogen cycle and in protein synthesis. Ammonia also helps maintain the body's pH balance.
Chemische Eigenschaften
Ammonium hydroxide exists only in the form of an aqueous solution. The compound is prepared by dissolving NH3 in H2O and usually is referred to in industrial trade as aqua ammonia. For industrial procurements, the concentration of NH3 in solution is normally specified in terms of the specific gravity (degrees Baum′e, °Be). Common concentrations are 20 °Be and 26 °Be. The former is equivalent to a sp gr of 0.933, or a concentration of about 17.8% NH3 in solution; the latter is equivalent to a sp gr of 0.897, or a concentration of about 29.4% NH3. These figures apply at a temperature of 60 °F (15.6 °C). Reagent grade NH4OH usually contains approximately 58% NH4OH (from 28 to 30% NH3 in solution).
Verwenden
Ammonium hydroxide is used as a cleaning agent and sanitizer in many household and industrial cleaners. Ammonium hydroxide is also used in the manufacture of products such as fertilizer, plastic, rayon and rubber. Aqueous ammonia is corrosive to aluminum alloys, copper, copper alloys, and galvanized surfaces. Aqueous ammonia is an excellent acid neutralizer.
Definition
Ammonium hydroxide,NH40H, is a hydrate of anunonia and exists in crystalline form at -79°C. Normally, it is only found in an aqueous solution also known as aquaanunonia and anunonia water. It is prepared by dissolving NH3 inH20. Reagent grade anunonium hydroxide contains from 28 to 30% NH3 at 15.6 °C. Industrial sales specify the concentration of NH3 in solution in terms of specific gravity. Common concentrations are 20 °Be, which would bea concentration of 17.8% NH3 (specific gravity 0.933) and 26 °Be (specific gravity 0.897), or a concentration of 29.4% NH3. Ammonium hydroxide is an excellent medium for the reaction of NH3 (which becomes the NH4 radical in solution) with other compounds for the preparation of anunonium salts and other nitrogen-containing chemicals. It is an ingredientin deodorants, etching compounds, and cleaning and bleaching materials. Ammoniumhydroxide, as aqua ammonia, finds wide use as a neutralizing agent,because it is inexpensive and strongly alkaline.
Allgemeine Beschreibung
Ammonium hydroxide is a colorless aqueous solution. Concentration of ammonia ranges up to approximately 30%. Ammonia vapors (which arise from the solution) irritate the eyes.
Air & Water Reaktionen
Water soluble. Generates a small amount of heat when diluted with water.
Reaktivität anzeigen
Ammonium hydroxide reacts exothermically with acids. Evolves toxic gaseous ammonia with strong bases. Reacts extremely violently with dimethyl sulfate [NFPA 491M 1991]. Reacts with aqueous silver nitrate sodium hydroxide to give a black precipitate of silver nitride. Such a precipitate can explode on stirring [MCA Case History 1554 1968]. Aqueous ammonia and Hg react to form an explosive solid, likely a fulminate. (Thodos, G. Amer. Inst. Chen. Engrs. J., 1964, 10, 274.).
Hazard
Liquid and vapor extremely irritating, especially to eyes.
Health Hazard
Ammonium hydroxide solutions are alkaline solutions, meaning they have high pH level. As a result, ammonium hydroxide is a severe eye, skin, and respiratory tract irritant, and readily burns tissue with which it comes in contact. Splashes to the eye may be serious, as contact may cause severe burns, irritation pain and possibly blindness. Direct contact with skin may cause severe burns if the chemical is not quickly rinsed away with copious amounts of water. Inhaling mists of ammonium hydroxide may result in irritation of the nose and throat with symptoms including burning, coughing, choking and pain. Inhaling concentrated mist may result in pulmonary edema and shock. Ingesting ammonium hydroxide may cause pain and burns of the esophagus and gastrointestinal tract.
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Brandgefahr
Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
Flammability and Explosibility
Ammonia vapor is slightly flammable (NFPA rating = 1) and ignites only with
difficulty. Ammonia forms explosive mixtures with air in the range 16 to 25%.
Water, carbon dioxide, or dry chemical extinguishers should be used for ammonia
fires.
Landwirtschaftliche Anwendung
Ammonium hydroxide is also known as ammonia
solution, aqua ammonia, aqueous ammonia or
ammonia liquor. It is the solution of ammonia in water
and is commonly referred to as ammonium hydroxide. It
is the simplest nitrogen solution made by forcing
compressed ammonia (anhydrous ammonia) gas into
water.
Sicherheitsprofil
A human poison by
ingestion. An experimental poison by
inhalation and ingestion. A severe eye
irritant. Human systemic irritant effects by
ocular and inhalation routes. Mutation data
reported. Incompatible with acrolein,
nitromethane, acrylic acid, chlorosulfonic
acid, dimethyl sulfate, halogens, (Au + aqua
regia), HCl, HF, HNO3, oleum, ppropiolactone,
propylene oxide, AgNO3,
Ag2O, (Ag20 + C2H5OH), AgMn04,
H2SO4. Dangerous; liquid can inflict burns.
Use with adequate ventilation. When
heated to decomposition it emits NH3 and
NO2.
mögliche Exposition
It is used in detergents, stain removers,
bleaches, dyes, fibers, and resins.
Lager
All work with this substance should be
conducted in a fume hood to prevent exposure by inhalation, and splash goggles and
impermeable gloves should be worn at all times to prevent eye and skin contact.
Containers should be tightly sealed to prevent escape of vapor and should be stored
in a cool area separate from halogens, acids, and oxidizers. Containers stored in
warm locations may build up dangerous internal pressures of ammonia gas.
Versand/Shipping
UN2672 Ammonia solutions, relative density
between 0.880 and 0.957 at 15 C in water, with .10% but
not .35% ammonia, Hazard class: 8; Labels: 8-Corrosive
material.
Inkompatibilitäten
Solution is strongly alkaline. Violent
reaction with strong oxidizers, acids (exothermic reaction
with strong mineral acids). Shock-sensitive compounds
may be formed with halogens, mercury oxide; silver oxide.
Fire and explosions may be caused by contact with β-propiolactone,
silver nitrate; ethyl alcoho; silver permanganate;
trimethylammonium amide; 1-chloro-2,4-dinitrobenzene,
o-chloronitrobenzene, platinum, trioxygen difluoride; selenium
difluoride dioxide; boron halides; mercury, chlorine,
iodine; bromine, hypochlorites, chlorine bleach; amides,
organic anhydrides; isocyanates, vinyl acetate; alkylene
oxides; epichlorohydrin; aldehydes. Attacks some coatings,
plastics and rubber. Attacks copper, brass, bronze, aluminum,
steel, zinc, and their alloys.
Waste disposal
Dilute with water, neutralize
with HCl and discharge to sewer.
Ammoniak, wssrige Lsung Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
cytochrome C solution
Neomycin, Sulfat (Salz)
2-Amino-3,6,8-naphthalenetrisulfonic acid
N,1,3-Trimethyl-1H-pyrazole-5-carboxamide ,97%
Triammoniumtrioxalatoferrat
2-ANTHRACENECARBOXYLIC ACID
(1-METHYL-1H-BENZIMIDAZOL-2-YL)METHYLAMINE
1,2-Benzisothiazol-3(2H)-on-1,1-dioxid, Ammoniumsalz
2-AMINO-3-PYRIDINECARBOXALDEHYDE HCL
2,4-Dimethyl-1H-imidazol
2,6-Dimethylpyridin-3-ol
Ammoniumethylcarbamoylphosphonat
Ammonium-2-amino-4-(hydroxymethyl-phosphinyl)butyrat
Ethyl 3-amino-4,4,4-trifluorocrotonate
aluminium oxide sol
3-(2-Methoxyphenoxy)-1,2-propandiol-1-carbamat
6-Chlorpyridazin-3-amin
Hydrofining catalyst FH-5
adhesive for electrostatic flocking EX-1
N,1,5-Trimethyl-1H-pyrazole-3-carboxamide ,97%
(S)-O-6-Amino-6-desoxy-α-D-glucopyranosyl-(1-4)-O-[3-desoxy-4-C-methyl-3-(methylamino)-β-L-arabinopyranosyl-(1-6)]-1,3-diamino-N1-(3-aminolactoyl)-1,2,3-tridesoxy-D-scyllo-inosit
2,4-Dichlorbenzonitril
Doxycycline monohydrate
4-Nitrobenzenesulfonamide
2-CHLORO-6-METHYLPYRIMIDIN-4-AMINE
polyalumium sulfate chloride
(6-BROMO-2-PYRIDINYL)-CARBAMIC ACID,1,1-DIMETHYLETHYL ESTER
1,3-DIMETHYL-1H-PYRAZOLE-5-CARBOXAMIDE
DL-Cystin
2,4,5-TRIMETHYL-3-OXAZOLINE
Ammonium-L-glutamat
Triammonium-12-molybdophosphat
synthetic thickener KG-201
Direct Blue 199
Kaliumtetrakis(cyano-C)aurat
emulsifier SOPE-15
Epinephrin
1,5-Dimethyl-1H-pyrazole-3-carboxamide ,97%
5-Methylchinolin-8-ol
6-BROMONAPHTHALEN-2-AMINE
