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[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

CAS No.
72287-26-4
Chemical Name:
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Synonyms
PDCL2(DPPF);(dppf)2PdCl2;dichloropalladiuM;1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II);Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,complex with CH2Cl2;oropaL;[1,1′JACS-72287-26-4;CHEMWISH IC30255;[1,1'-Bis(diphenyL
CBNumber:
CB3276259
Molecular Formula:
C34H28Cl2FeP2Pd
Molecular Weight:
731.7
MDL Number:
MFCD00015757
MOL File:
72287-26-4.mol
Last updated:2023-12-25 17:47:29

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Properties

Melting point 275-280 °C(lit.)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Soluble in dichloromethane.
form powder
color red to very dark red
Stability Hygroscopic

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xn,Xi
Risk Statements  20/21/22-36/37/38-40
Safety Statements  23-24/25-26-36/37
WGK Germany  3
TSCA  No
HazardClass  IRRITANT
HS Code  28439000

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) price More Price(37)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 1g $74.3 2024-03-01 Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 5g $227 2024-03-01 Buy
Alfa Aesar 046503 Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), Pd 13.5-15.5% 72287-26-4 1g $72.5 2023-06-20 Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 250g $9580 2024-03-01 Buy
TRC B430465 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 1g $100 2021-12-16 Buy
Product number Packaging Price Buy
697230 1g $74.3 Buy
697230 5g $227 Buy
046503 1g $72.5 Buy
697230 250g $9580 Buy
B430465 1g $100 Buy

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chemical Properties,Uses,Production

Uses

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds. Is used in preparation of Nucleosides as Ectonucleotidase inhibitors.

Chemical Properties

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is Red solid

Uses

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings.

Uses

suzuki reaction

Uses

Catalyst for C-C and C-N coupling reaction.

Application

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions:
Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

Mechanism of action

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds.
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) uses
R = usually sp2 hybridised carbon
X = usually I, Br, Cl or OTf
The nature of R' and M are dependant upon
the specic coupling being performed

12150-46-8
90243-59-7
72287-26-4
Synthesis of [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) from 1,1'-Bis(diphenylphosphino)ferrocene and Palladium, bis(acetonitrile)dichloro-, (SP-4-2)-
Global( 488)Suppliers
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Wuhan Huahan Dingcheng New Material Technology Co., Ltd
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View Lastest Price from [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) pictures 2024-04-23 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
US $80.00 / kilograms 10kilograms 99 10 Hebei Dangtong Import and export Co LTD
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) pictures 2023-12-26 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) pictures 2023-11-15 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
US $30.00-9.00 / kg 1kg 0.99 15 tons Hebei Yanxi Chemical Co., Ltd.
1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II) 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II) dichloromethane add 1,1'-Bis(diphenylphosphino)ferroceneüpalladium(II) chloride, 1:1 complex with dichloromethane [bis(diphenylphosphino)ferrocene]PdCl2/ dichloromethane 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99% [1,1'-Bis(diphenylphosphino)ferrocene]dichloropall 1,1'-Bis(diphenylphosphino)ferrocene-palladium dichloride,98% 1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride [Pd(dppf)Cl2] Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) 1'-Bis(diphenylphosphino)ferrocene-palladiuM(II) dichloride 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99.9% [1,1′-Bis(diphenylph [1,1'-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloromethane complex (1:1) -Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II): 99.9% (II)dichloromethane adduct 1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane Palladium, 1,1-bis(diphenylphosphino-.kappa.P)ferrocenedichloro-, (SP-4-2)- [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(ii) dichloromethane complex (1:1) [1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloride dichloromethane complex (1:1) (1,1'-Bis(diphenylphosphimoferrocene)dichloropalladium (II)-CH2CL2 [1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADI [1,1''-Bis-(diphenylphosphino)-ferrocene]-palladous dichloride [1,1''-Bis(diphenyphosphino)ferrocene]dichloropalladium(II) [1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) PdCl2(dppf) 1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM() COMPLEX WITH DICHLOROMETHANE (1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE)-P ALLADIUM(II) CHLORIDE CH2CL2 COMPL DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II) 1,1'-Bis(diphenylphosphino)ferrocenepalladiuM( II) dichloride Pd DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II) DICHLOROMETHANE ADDUCT [1,1'-Bis(diphenylphosphino)ferrocen]dichloropalladiuM(II), coMplex with dichloroMethane -Bis(diphenylphosphino)ferrocene-palladiuM(II)dichloride dichloroMethane coMplex 1,1'-Bis(diphenylphosphiNA)ferrocene palladiuM(II)dichloride Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II), (DPPF)PdCl2 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(Ⅱ) [1,1'-Bis(diphenylphosphino)ferrocene]Pd(II)Cl2 CHEMWISH IC30255 JACS-72287-26-4 1,1'-Bis(diphenylphosphino)ferrocene palladiuM(II)dichlorid (Diphenylphosphino)Ferrocene PalladiuM Dichlorid 1,1'-BIS(DIPHENYLPHOSPHINO) 1,1'-BIS(DIPHENYLPHOSP [1,1&prime 1'1-Bis(diphenylphosphino)fewocene palladium(Ⅱ)chloride [1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (Pd(dppf)Cl2) [1,1'-Bis(diphenyL oropaL phosphino)ferrocene]dichL 1,1 '- bis (diphenylphosphino) ferrocene palladium dichloride (II) 1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II),Pd 14.5% Diphenylphosphinoferrocene dichloropalladium 1’1-Bis(diphenylphosphino)fewocene Palladium(Ⅱ)chloride [1,1 '- bis (diphenylphosphonyl) ferrocene] palladium dichloride [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Basic information