Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Structure
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) structure
CAS No.
72287-26-4
Chemical Name:
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
Synonyms
PDCL2(DPPF);(dppf)2PdCl2;dichloropalladiuM;1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II);1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE;Palladium(II) chloride-1,1’-bis(diphenylphosphino)ferrocene,complex with CH2Cl2;CX93;oropaL;Pd（dppf）;pddppfcl2
CBNumber:
CB3276259
Molecular Formula:
C34H28Cl2FeP2Pd
Molecular Weight:
731.7
MDL Number:
MFCD00015757
MOL File:
72287-26-4.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-04-24 14:58:38
Product description Number Pack Size Price
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 697230 1g $81.5
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 697230 5g $250
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 697230 25 g $1040
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 697230 1 unit $981
[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 697230 1 unit $981
More product size
Request For Quotation

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Properties

Melting point 275-280 °C(lit.)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Soluble in dichloromethane.
form powder
color red to very dark red
Stability Hygroscopic
InChI InChI=1S/2C17H11P.2ClH.Fe.Pd/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;;;;/h2*1-6,9-12,18H;2*1H;;/q;;;;+2;/p-2
InChIKey LMSWLYFMTLONFK-UHFFFAOYSA-L
SMILES [Cl-][Pd+2]1(P(C2C=CC=CC=2)(C2C=CC=CC=2)[C-]23C4=C5C6=C2[Fe+2]27893456C3C2=C7[C-]8(C9=3)P1(C1C=CC=CC=1)C1C=CC=CC=1)[Cl-]
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xn,Xi
Risk Statements  20/21/22-36/37/38-40
Safety Statements  23-24/25-26-36/37
WGK Germany  3
TSCA  No
HazardClass  IRRITANT
HS Code  28439000
Storage Class 6.1D - Non-combustible acute toxic Cat.3
toxic hazardous materials or hazardous materials causing chronic effects
Hazard Classifications Carc. 1B Inhalation

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 1g $81.5 2026-03-19 Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 5g $250 2026-03-19 Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 25 g $1040 2026-03-19 Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 1 unit $981 2025-07-31 Buy
Sigma-Aldrich 697230 [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 72287-26-4 1 unit $981 2025-07-31 Buy
Product number Packaging Price Buy
697230 1g $81.5 Buy
697230 5g $250 Buy
697230 25 g $1040 Buy
697230 1 unit $981 Buy
697230 1 unit $981 Buy

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Chemical Properties,Uses,Production

Uses

[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), is a palladium catalyst used in chemical synthesis of various compounds. Is used in preparation of Nucleosides as Ectonucleotidase inhibitors.

Chemical Properties

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is Red solid

Uses

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) is used as a catalyst for Suzuki and Stile couplings.

Uses

suzuki reaction

Uses

Catalyst for C-C and C-N coupling reaction.

Application

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) may be used as an effective palladium catalyst in the following reactions:
Cross-coupling of sec-alkyl and n-alkyl Grignard reagents with high yield and selectivity.
Suzuki coupling of aryl boronic esters with [11C]methyl iodide to form functionalized [11C]toluene derivatives.
Kumada cross-coupling of 1,3,5-tribromobenzene with Grignard reagents to form star-shaped oligothiophenes.

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

Mechanism of action

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (pd(dppf)cl2) catalysis has gained widespread use in industrial and academic synthetic chemistry laboratories as a powerful methodology for the formation of C-C and C-Heteroatom bonds.
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) uses
R = usually sp2 hybridised carbon
X = usually I, Br, Cl or OTf
The nature of R' and M are dependant upon
the specic coupling being performed

Synthesis

A method for the preparation of 1,1'-bis(diphenylphosphino)ferrocene palladium dichloride II (dppfPdCl2) comprising the steps of:

(a) adding palladium chloride to concentrated hydrochloric acid, heating to 40-80C to dissolve, the amount of hydrochloric acid is 0.2-1.0 times the mass of palladium chloride, diluting with ethanol, the amount of ethanol is 10-50 times the mass of palladium chloride;

(b) bis-diphenylphosphinoferrocene (dppf) 3.0-5.0 times the mass of palladium chloride is added to a solution of tetrahydrofuran and heated to 40-80C until dissolved, and the amount of tetrahydrofuran is 20-30 times the mass of palladium chloride;

(c) the solution obtained in step (a) was added dropwise to the solution obtained in step (b), and after the dropwise addition was completed, it was held at 45-80C for 0.5-3h, and then cooled, filtered, washed, and dried in vacuum, to obtain 1,1'-bis(diphenylphosphino)ferrocene palladium dichloride II red crystals.

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) synthesis

12150-46-8
90243-59-7
72287-26-4
Synthesis of [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) from 1,1'-Bis(diphenylphosphino)ferrocene and Palladium, bis(acetonitrile)dichloro-, (SP-4-2)-

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Preparation Products And Raw materials

Raw materials

Acetonitrile Ethanol 1,1'-Bis(diphenylphosphino)ferrocene Toluene Palladium chloride
Dichloromethane Methanol Lithium chloride

1of2

Preparation Products

Vanadyl acetylacetonate 4-AMINO-3-METHOXYPHENYLBORONIC ACID, PINACOL ESTER 4-Nitrophenylboronic acid 3-MORPHOLINOPHENYLBORONIC ACID PINACOL ESTER 2-Ethoxycarbonylphenylboronic acid pinacol ester

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Suppliers

Global( 541)Suppliers
Supplier Tel Email Country ProdList Advantage
Wuhan Huahan Dingcheng New Material Technology Co., Ltd
+undefined-027-81388558 +undefined086-1878077615 huahandingcheng@sina.com China 342 58
Hebei Chuanghai Biotechnology Co., Ltd 		+8615350571055 Sibel@chuanghaibio.com China 8738 58
Hebei Yanxi Chemical Co., Ltd. 		+8618531123677 faithe@yan-xi.com China 5853 58
Henan Bao Enluo International TradeCo.，LTD 		+86-17331933971 deasea125996@gmail.com China 2472 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20124 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718; +8613336195806 sales@capot.com China 29640 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-2158073036 info@dakenam.com China 13815 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21591 55
Nanjing ChemLin Chemical Industry Co., Ltd. 		025-83697070 product@chemlin.com.cn CHINA 3009 60
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 33024 60
Supplier Advantage
Wuhan Huahan Dingcheng New Material Technology Co., Ltd
58
Hebei Chuanghai Biotechnology Co., Ltd 		58
Hebei Yanxi Chemical Co., Ltd. 		58
Henan Bao Enluo International TradeCo.，LTD 		58
Henan Fengda Chemical Co., Ltd 		58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
Nanjing ChemLin Chemical Industry Co., Ltd. 		60
ATK CHEMICAL COMPANY LIMITED 		60

View Lastest Price from [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) pictures 2026-03-20 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
 US $10.00 / KG 100KG 99% 100 mt Hebei Chuanghai Biotechnology Co., Ltd
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) pictures 2026-02-25 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
 US $80.00 / kilograms 10kilograms 99 10 Hebei Dangtong Import and export Co LTD
[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) pictures 2025-12-01 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)
72287-26-4
 US $0.00-0.00 / KG 1KG 98 10000KGS Shaanxi Dideu New Materials Co. Ltd

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Spectrum

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)(72287-26-4)1HNMR[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)(72287-26-4)31PNMR[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)(72287-26-4)FT-IR

72287-26-4([1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II))Related Search:

Diphenylphosphine oxide Dicyclohexylchlorophosphine Chlorodiphenylphosphine ETHYNYLFERROCENE Tricyclohexyl phosphine
Acetylferrocene Ferrocene Tetrakis(triphenylphosphine)platinum [1,2-Bis(diphenylphosphino)ethane]dichloropalladium(II) Dichloro(1,5-cyclooctadien)ruthenium(II) polymer
1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride, DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]PALLADIUM(II) Palladium chloride 1,1'-Bis(diphenylphosphino)ferrocene Dichloro(1,1-bis(diphenylphosphino)ferrocene)palladium(II) acetone adduct
ISOPROPYLDIPHENYLPHOSPHINE Palladium 1,3-Cyclopentadiene

1of4

1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II) 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE Dichloro(1,1'-bis(diphenylphosphino)ferrocene)palladium (II) dichloromethane add 1,1'-Bis(diphenylphosphino)ferroceneüpalladium(II) chloride, 1:1 complex with dichloromethane [bis(diphenylphosphino)ferrocene]PdCl2/ dichloromethane 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99% [1,1'-Bis(diphenylphosphino)ferrocene]dichloropall 1,1'-Bis(diphenylphosphino)ferrocene-palladium dichloride,98% 1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride [Pd(dppf)Cl2] Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) 1'-Bis(diphenylphosphino)ferrocene-palladiuM(II) dichloride 1,1'-Bis(diphenylphosphino)ferrocene palladium dichloride ,99.9% [1,1′-Bis(diphenylph [1,1'-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloromethane complex (1:1) -Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 1,1-BIS(DIPHENYLPHOSPHINO)FERROCENEDICHLOROPALLADIUM(II): 99.9% (II)dichloromethane adduct 1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane Palladium, 1,1-bis(diphenylphosphino-.kappa.P)ferrocenedichloro-, (SP-4-2)- [1,1'-bis(diphenylphosphino)ferrocene]dichloropalladium(ii) dichloromethane complex (1:1) [1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloride dichloromethane complex (1:1) (1,1'-Bis(diphenylphosphimoferrocene)dichloropalladium (II)-CH2CL2 [1,1-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADI [1,1''-Bis-(diphenylphosphino)-ferrocene]-palladous dichloride [1,1''-Bis(diphenyphosphino)ferrocene]dichloropalladium(II) [1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) PdCl2(dppf) 1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM() COMPLEX WITH DICHLOROMETHANE (1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE)-P ALLADIUM(II) CHLORIDE CH2CL2 COMPL DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II) 1,1'-Bis(diphenylphosphino)ferrocenepalladiuM( II) dichloride Pd DICHLORO-((BIS-DIPHENYLPHOSPHINO)FERROCENYL)-PALLADIUM(II) DICHLOROMETHANE ADDUCT [1,1'-Bis(diphenylphosphino)ferrocen]dichloropalladiuM(II), coMplex with dichloroMethane -Bis(diphenylphosphino)ferrocene-palladiuM(II)dichloride dichloroMethane coMplex 1,1'-Bis(diphenylphosphiNA)ferrocene palladiuM(II)dichloride Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II), (DPPF)PdCl2 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(Ⅱ) [1,1'-Bis(diphenylphosphino)ferrocene]Pd(II)Cl2 CHEMWISH IC30255 JACS-72287-26-4 1,1'-Bis(diphenylphosphino)ferrocene palladiuM(II)dichlorid (Diphenylphosphino)Ferrocene PalladiuM Dichlorid 1,1'-BIS(DIPHENYLPHOSPHINO) 1,1'-BIS(DIPHENYLPHOSP [1,1&prime 1'1-Bis(diphenylphosphino)fewocene palladium(Ⅱ)chloride [1,1’-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (Pd(dppf)Cl2) [1,1'-Bis(diphenyL oropaL phosphino)ferrocene]dichL 1,1 '- bis (diphenylphosphino) ferrocene palladium dichloride (II) 1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)，Pd 14.5% Diphenylphosphinoferrocene dichloropalladium 1’1-Bis(diphenylphosphino)fewocene Palladium(Ⅱ)chloride [1,1 '- bis (diphenylphosphonyl) ferrocene] palladium dichloride [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Basic information 1,1'-Bis(diphenylphosphino)ferrocene - dichloropalladium (1:1) Palladium, [1,?1'-?bis(diphenylphosphin?o-?κP)?ferrocene]?dichloro-?, (SP-?4-?2)?-