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Thiophosgene

CAS No.
463-71-8
Chemical Name:
Thiophosgene
Synonyms
CSCl2;Thiocarbonyl dichloride;Carbonothioyl dichloride;Thiophosg;Thiofosgen;THIOPHOSGENE;thio-phosgen;Phosgene, thio-;Thiophosgene,97%;thiofosgen(czech)
CBNumber:
CB7117651
Molecular Formula:
CCl2S
Lewis structure
cscl2 lewis structure
Molecular Weight:
114.98
MDL Number:
MFCD00004918
MOL File:
463-71-8.mol
Last updated:2023-05-17 14:12:08

Thiophosgene Properties

Melting point <25 °C
Boiling point 73 °C
Density 1.508
vapor density 4 (vs air)
refractive index n20/D 1.548(lit.)
Flash point 62 °C
storage temp. 2-8°C
solubility Chloroform
form Liquid
color A reddish liquid
Water Solubility slow decomposition in cold, fast in hot water
BRN 1633495
Stability Stable. but reacts violently with water to produce toxic fumes. Incompatible with water, alcohols. Refrigerate at 2-8 C.
CAS DataBase Reference 463-71-8(CAS DataBase Reference)
EWG's Food Scores 1-2
FDA UNII 067FQP576P
NIST Chemistry Reference Carbonothioic dichloride(463-71-8)
EPA Substance Registry System Thiophosgene (463-71-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06
Signal word  Danger
Hazard statements  H302-H315-H318-H331-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P304+P340+P311-P305+P351+P338
Hazard Codes  T
Risk Statements  22-23-36/37/38
Safety Statements  7-9-36/37-45-7/9
RIDADR  UN 2474 6.1/PG 2
WGK Germany  1
RTECS  XN2450000
19-21
HazardClass  6.1(a)
PackingGroup  II
HS Code  28530090

Thiophosgene price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 115150 Thiophosgene 463-71-8 5g $36.9 2024-03-01 Buy
Sigma-Aldrich 115150 Thiophosgene 463-71-8 25g $103 2024-03-01 Buy
Sigma-Aldrich 115150 Thiophosgene 463-71-8 100g $119.2 2024-03-01 Buy
TRC T368200 Thiophosgene 463-71-8 50g $195 2021-12-16 Buy
Oakwood 005987 Thiophosgene 463-71-8 100g $210 2021-12-16 Buy
Product number Packaging Price Buy
115150 5g $36.9 Buy
115150 25g $103 Buy
115150 100g $119.2 Buy
T368200 50g $195 Buy
005987 100g $210 Buy

Thiophosgene Chemical Properties,Uses,Production

Chemical Properties

A clear dark red to reddish-yellow liquid. Sharp, choking odor.

Chemical Properties

Reddish liquid. Decomposes in water and alcohol; soluble in ether.

Uses

Thiophosgene is a photo degradation product of the agricultural fungicide Folpet (F402000).

Definition

ChEBI: Thiophosgene is a thiocarbonyl compound and a one-carbon compound.

General Description

A reddish liquid. Boiling point 73.5°C. A severe eye irritant. May severely burn skin on contact. Very toxic by inhalation and by skin absorption.

Air & Water Reactions

Reacts with water to evolve hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot.

Reactivity Profile

Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids.

Hazard

Toxic by ingestion and inhalation.

Health Hazard

Inhalation causes irritation of respiratory system and delayed pulmonary edema. Vapor irritates eyes. Liquid burns skin and eyes. Ingestion causes irritation of mouth and stomach.

Safety Profile

Poison by intravenous route. Moderately toxic by ingestion. A skin, mucous membrane, and severe eye irritant. When heated to decomposition it emits very toxic fumes of Cland SOx. See also PHOSGENE.

Potential Exposure

Primary irritant (w/o allergic reaction). There is not large-scale production of the chemical in the United States It is used to make other chemicals and in laboratory synthesis.

Shipping

UN2474 Thiophosgene, Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard; Inhalation Hazard Zone B. PG 2. STN: 49 232 98.

Incompatibilities

Vapors may form explosive mixture with air. Incompatible with water and alcohols. Reacts with water releasing toxic hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot. Decomposes above 200℃ to highly flammable carbon bisulfide and carbon tetrachloride. Corrodes metals, rubber and some plastics in the presence of moisture. Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

Global( 163)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Wuhan Chemwonders Technology Inc.
027-85778276 info@chemwonders.com CHINA 176 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49390 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-81138252 +86-18789408387 1057@dideu.com China 3537 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9641 58

View Lastest Price from Thiophosgene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Thiophosgene pictures 2023-07-19 Thiophosgene
463-71-8
US $30.00 / KG 1KG 99% 20 Tons Wuhan wingroup Pharmaceutical Co., Ltd
Thiophosgene pictures 2023-05-18 Thiophosgene
463-71-8
US $0.00 / mg 2mg 99% HPLC 20kg Zhuzhou New Peptides Tech Co.,Ltd.
Carbon chlorosulfide pictures 2023-05-18 Carbon chlorosulfide
463-71-8
US $0.00 / mg 2mg 99% HPLC 20kg Zhuzhou New Peptides Tech Co.,Ltd.
  • Thiophosgene pictures
  • Thiophosgene
    463-71-8
  • US $30.00 / KG
  • 99%
  • Wuhan wingroup Pharmaceutical Co., Ltd
  • Thiophosgene pictures
  • Thiophosgene
    463-71-8
  • US $0.00 / mg
  • 99% HPLC
  • Zhuzhou New Peptides Tech Co.,Ltd.

Thiophosgene Spectrum

Carbon chlorosulfide carbonchlorosulfide Carbonic dichloride, thio- carbonothioicdichloride Carbonyl chloride, thio- Dichlorothiocarbonyl Phosgene, thio- Thiocarbonic dichloride THIOPHOSGENE THIOCARBONYL CHLORIDE Thiophosgene, AcroSeal, 97% Carbon Dichloride Sulfide Carbonyl Sulfide Dichloride DichlorothioforMaldehyde Thiophosgene, 95%, AcroSeal Chlorothioformic acid chloride Dichloromethanethione Thiophosgene,97% thio-carbonicdichlorid thiocarbonicdichloride thio-carbonylchlorid thiocarbonyldichloride Thiofosgen thiofosgen(czech) Thiokarbonylchlorid thiokarbonylchlorid(czech) thio-phosgen Thiophosgene, 95%, J&KSeal Thiophosg Thiophosgene (Thiocarbonyl chloride) 463-71-8 Thiophosgene Thiophosgene, 85%, AcroSeal&trade CSCl2 Carbonothioyl dichloride Thiocarbonyl dichloride 463-71-8 CCl2S Coupling Phosgene Derivatives Synthetic Reagents Organics