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Lithium nitrate

Chemical properties Solubility in water (g/100ml) Toxicity Application Preparation Explosive characteristics References

CAS No. 7790-69-4
Chemical Name: Lithium nitrate
Synonyms: LiNO3;Lithiumnitrat;thiuM nitrate;LITHIUM NITRATE;LithiumNitrate>97%;LithiumNitrateLiNO3;LITHIUM NITRATE ANYD.;LITHIUM NITRATE REAGENT;lithium standard for ic;LITHIUM NITRATE, 99.999%
CBNumber: CB7400757
Molecular Formula: LiNO3
Formula Weight: 68.95
MOL File: 7790-69-4.mol
Lithium nitrate Property
Melting point : 264 °C(lit.)
Boiling point : 600 °C
density : 2.38
RTECS : QU9330000
Fp : 600°C
storage temp. : Store at +5°C to +30°C.
solubility : H2O: 1 M at 20 °C, clear, colorless
PH: 7-9 (50g/l, H2O, 20℃)
Water Solubility : 90 g/L (28 ºC)
Sensitive : Hygroscopic
Merck : 14,5536
Stability:: Stable. Incompatible with reducing agents, strong acids, organic materials, finely powdered metals. Oxidizer.
CAS DataBase Reference: 7790-69-4(CAS DataBase Reference)
EPA Substance Registry System: Nitric acid, lithium salt(7790-69-4)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : O,Xi
Risk Statements : 8-36/38
Safety Statements : 22-24/25-17-26
RIDADR : UN 2722 5.1/PG 3
WGK Germany : 1
TSCA : Yes
HazardClass : 5.1
PackingGroup : III
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H272 May intensify fire; oxidizer Oxidising liquids;Oxidising solids Category 2
Category 3
Danger
Warning
P210, P220, P221P280, P370+P378,P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220 Keep/Store away from clothing/…/combustible materials.
P221 Take any precaution to avoid mixing with combustibles/…
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.

Lithium nitrate Chemical Properties,Usage,Production

Chemical properties
Lithium Nitrate is an inorganic compound with the formula LiNO3 with highly water solubility. All metallic nitrates are inorganic salts of a given metal cation and the nitrate anion. The nitrate anion is a univalent (-1 charge) polyatomic ion composed of a single nitrogen atom ionically bound to three oxygen atoms for a total formula weight of 62.05. Nitrate compounds are generally soluble in water.
Lithium Nitrate is white trigonal crystal. It is soluble in water, ethanol, pyridine and ammonia. The aqueous solution is neutral.
Solubility in water (g/100ml)
Dissolved amount (g) per 100 milliliters of water at different temperatures (° C)
53.4g/0℃;60.8g/10℃;70.1g/20℃;138g/30℃;152g/40℃;175g/60℃
Toxicity
  • Lithium nitrate can be toxic to the body when ingested by targeting the central nervous system, thyroids, kidneys, and cardio-vascular system. When exposed to the skin, eyes, and mucous membranes, lithium nitrate can cause irritation to these areas.
  • It releases toxic and irritating nitrogen oxides when it burns. It decomposes at high temperatures, producing toxic nitroxides. When people inhale these, they will be poisoned. Others refer to sodium nitrate.
Application
  • Used as liquid ammonia stabilizer in refrigeration equipment, rocket propellant, oxidants of pyrotechnic manufacture, glass etchants, antistatic agents, composition of molten salt in metallurgical industry.
  • Used as an analytical reagent; dissolving and cooling agent; heat exchange carrier; catalyst for the paint; raw materials of other nickel salt; mordant of reducing dye.
  • Used for the manufacture of a phosphor, other lithium salt, nickel batteries and for ceramics and metal coloring.
  • Used in the electroplating industry; organic synthesis and production of hardening oil.
  • Lithium Nitrate has been proposed as a medium to store heat collected from the sun for cooking.
  • Lithium nitrate is also a very good oxidizing agent in the manufacture of red-colored fireworks and flares.
  • Currently, lithium nitrate is being tested to see if it can be applied to concrete-pavement to withstand weathering effects.
Preparation
Lithium hydroxide or lithium carbonate is added to the reactor containing distilled water, and nitric acid is slowly added under stirring and heating to carry out the reaction. Then we evaporate it to dryness and heat it under vacuum at about 200 ° C, finally we get lithium nitrate. HNO3+LiOH→LiNO3+H2O
Explosive characteristics
May cause the acceleration of the burning of combustible materials. Prolonged exposure to heat or flames may result in an explosion.
References
https://pubchem.ncbi.nlm.nih.gov/compound/Lithium_nitrate#section=Top
https://www.americanelements.com/lithium-nitrate-7790-69-4
https://en.wikipedia.org/wiki/Lithium_nitrate
Chemical Properties
White crystal
Uses
Used in ceramics, heat-exchange media, refrigeration systems.
Definition
ChEBI: The inorganic nitrate salt of lithium.
General Description
A white to light yellow colored crystalline solid. Denser than water. Contact with the material may cause irritation to skin, eyes, and mucous membranes. May be toxic by ingestion. May cause the acceleration of the burning of combustible materials. Prolonged exposure to heat or flames may result in an explosion.
Air & Water Reactions
Deliquescent. Soluble in water.
Reactivity Profile
Lithium nitrate is an oxidizing agent. Mixtures with alkyl esters may explode owing to the formation of alkyl nitrates; mixtures with phosphorus, tin(II) chloride, or other reducing agents may react explosively [Bretherick 1979. p. 108-109].
Health Hazard
Inhalation, ingestion or contact (skin, eyes) with vapors or substance may cause severe injury, burns or death. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may cause pollution.
Fire Hazard
These substances will accelerate burning when involved in a fire. Some may decompose explosively when heated or involved in a fire. May explode from heat or contamination. Some will react explosively with hydrocarbons (fuels). May ignite combustibles (wood, paper, oil, clothing, etc.). Containers may explode when heated. Runoff may create fire or explosion hazard.
Lithium nitrate Preparation Products And Raw materials
Raw materials
Lithium hydroxide Lithium carbonate Nitric acid
Preparation Products
LITHIUM MANGANESE OXIDE LITHIUM MANGANITE
Lithium nitrate Suppliers      Global( 169)Suppliers     
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7790-69-4(Lithium nitrate)Related Search:
Sodium nitrate Aluminum nitrate Calcium nitrate Ammonium nitrate Sodium nitrite Lithium chloride Miconazole nitrate nitric acid Silver nitrate Potassium nitrate Miconazole Nitrate lithium nitrite Lithium hydroxide Lithium hydroxide Lithium nitrate Litium Magnesium nitrate NITRATE
LiNO3 Lithiumnitrat LITHIUM NITRATE 7790-69-4 LITHIUM NITRATE ANYD. LITHIUM NITRATE EXTRA PURE LITHIUM NITRATE REAGENTPLUS(TM) LITHIUM NITRATE SIGMAULTRA LITHIUM ATOMIC SPECTROSCOPY STAND. SOL. FLUKA, IN NITRIC AC. LITHIUM NITRATE, REAGENTPLUS, LITHIUM NITRATE, 99.99% METALS BASIS LITHIUM ICP STANDARD SOLUTION FLUKA, FOR ICP LithiumNitrateLiNO3 LithiumNitrate>97% Lithiumnitrate,anhydrous,99.98%(metalsbasis) Lithiumnitrate,anhydrous,99% LITHIUM NITRATE ANHYDROUS Lithium nitrate, extra pure, 99+% LITHIUM NITRATE BIO-REFINED LITHIUM NITRATE REAGENT LITHIUM NITRATE, 99.999% lithium nitrate solution lithium standard for aas lithium standard for ic lithium standard for icp LITHIUMNITRATE,BIOTECHGRADE LITHIUMNITRATE,CRYSTAL,REAGENT Inorganics Nitric acid lithium salt LITHIUM COMPOUNDS Lithium nitrate hydrate, Puratronic(R), 99.999% (metals basis) Lithium nitrate, anhydrous, 99.999% (metals basis) LITHIUM NITRATE extrapure AR Essential Chemicals Reagent Plus Routine Reagents ICP CRMsAnalytical Standards ICP-OES/-MS ICPSpectroscopy AAS AAS CRMsAnalytical Standards AASSpectroscopy Alphabetic Application CRMs L Spectroscopy Inorganic Salts Lithium Synthetic Reagents Lithium nitrate, 99+%, extra pure LiNO3xH2Ox05 Lithium nitrate hydrate, Puratronic, 99.999% (metals basis) Lithium Nitrate, Anhydrous (Metals Basis) metal nitrate salts thiuM nitrate LithiuM nitrate, extra pure, 99+% 1KG LithiuM nitrate, extra pure, 99+% 250GR LithiuM nitrate, 99.999%, (trace Metal basis)
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