메티오캅

메티오캅
메티오캅 구조식 이미지
카스 번호:
2032-65-7
한글명:
메티오캅
동의어(한글):
메티오캅
상품명:
Mercaptodimethur
동의어(영문):
METHIOCARB;MXMC;Club;OMS93;H 321;Draza;b37344;certan;dcr736;Esurol
CBNumber:
CB1254073
분자식:
C11H15NO2S
포뮬러 무게:
225.31
MOL 파일:
2032-65-7.mol
MSDS 파일:
SDS

메티오캅 속성

녹는점
119°C
밀도
1.1838 (rough estimate)
증기압
1.5 x 10-5 Pa (20 °C)
굴절률
1.4790 (estimate)
저장 조건
0-6°C
용해도
DMF: 20 mg/ml,DMSO: 20 mg/ml,DMSO:PBS (pH 7.2) (1:1): 0.5 mg/ml,Ethanol: 10 mg/ml
물리적 상태
결정질 고체
끓는 점
310.7±42.0 °C(Predicted)
산도 계수 (pKa)
12.16±0.46(Predicted)
색상
하얀색
수용성
불용성
BRN
1881431
안정성
감광성
CAS 데이터베이스
2032-65-7(CAS DataBase Reference)
NIST
4-Methylthio-3,5-xylyl methylcarbamate(2032-65-7)
EPA
Methiocarb (2032-65-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T;N,N,T
위험 카페고리 넘버 25-50/53
안전지침서 22-37-45-60-61
유엔번호(UN No.) UN 2811/2757
WGK 독일 3
RTECS 번호 FC5775000
위험 등급 6.1(a)
포장분류 II
유해 물질 데이터 2032-65-7(Hazardous Substances Data)
독성 LD50 in male, female rats (mg/kg): 70, 60 orally (Gaines)
기존화학 물질 KE-05-0988
유해화학물질 필터링 97-1-77
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 메티오캅 및 이를 1% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H300 삼키면 치명적임 급성 독성 물질 - 경구 구분 1,2 위험 GHS hazard pictograms P264, P270, P301+P310, P321, P330,P405, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P273 환경으로 배출하지 마시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P391 누출물을 모으시오.
P405 밀봉하여 저장하시오.
NFPA 704
0
4 0

메티오캅 C화학적 특성, 용도, 생산

개요

Methiocarb was originally developed by Bayer as an insecticide. The bird-repellent properties of the compound were quickly recognized, however, and a number of applications for bird damage management followed (42).
Methiocarb is a secondary repellent, and repellency occurs through aversive conditioning, by which birds that feed on treated food become sick and associate either the food or characteristics of the food with the discomfort (21). As a result, affected birds learn to avoid that food item. Often the avoidance response is locationdependent. For example, common ravens (Corvus corax) that learn not to eat eggs at one site will still feed on eggs at a different location (43).

화학적 성질

Methiocarb is a colorless crystalline powder.

용도

Insecticide; molluscicide; bird repellent.

정의

ChEBI: A carbamate ester obtained by the formal condensation of the phenolic group of 3,5-dimethyl-4-(methylsulfanyl)phenol with the carboxy group of methylcarbamic acid.

일반 설명

White crystalline powder with a mild odor. Used as an insecticide and immobilizing agent for birds, acaricide and molluscicide.

반응 프로필

Mercaptodimethur is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

건강위험

As a carbamate insecticide, Mercaptodimethur is a reversible cholinesterase inhibitor and acts on the nervous system. It is classified as very toxic, and the probable oral lethal dose for humans is 50-500 mg/kg or between 1 teaspoon and 1 ounce for a 150 lb. adult.

화재위험

When heated to decomposition, Mercaptodimethur emits very toxic fumes of nitrogen and sulfur oxides.

농업용

Acaricide, Molluscicide, Insecticide: Used to control slugs and snails, soil insects and spider mites in pome fruit, stone fruit, hops, strawberries, potatoes, beets, maize, vegetables and ornamentals. Also used as seed treatment to control fruit flies on maize and bird repellant on berries and cherries. Methiocarb producers deleted all food uses from their product labels between 1989-92. It is A U.S. EPA restricted Use Pesticide (RUP) except for residential application.

상품명

AI3-25726®; ALCO SLUB”M[C]; B 37344®; BAY 5024®; BAY 9026®; BAY 37344®; BAYER 37344®; DCR 736®; DRAZA®; DRAZA G MICROPELLETS®; H 321®; MESUROL®; METHIOCARBE®; OMS- 93®; PBI SLUG GARD®; PROVADA®; SD 9228®; SLUG-GETA®[C]

색상 색인 번호

Methiocarb is an insecticide or molluscicide with a cholinesterase inhibiting effect. A case of contact dermatitis was reported in a carnation grower.

Pharmacology

Methiocarb is a carbamate, and its mode of action is via the inhibition of acetylcholinesterase at synapses in the nervous system. Unlike many cholinesterase-inhibiting compounds, however, the effects of methiocarb are rapidly reversible, and the animal experiences only transitory disruption.

Safety Profile

Poison by ingestion, skin contact, and intraperitoneal routes. Used as an insecticide, molluscicide, and bird repellent. When heated to decomposition it emits very toxic fumes of NOx and SOx. See also ESTERS and CARBAMATES.

잠재적 노출

A potential danger to those involved in the manufacture, formulation, and application of this nonsystemic acaricide and insecticide.

환경귀착

Soil. Methiocarb was oxidized, probably by singlet oxygen, to the corresponding sulfoxide and trace amounts (<5% yield) of sulfone when sorbed on soil and exposed to sunlight. The photosensitized oxidation was faster in soils containing the lowest organic carbon content (Gohre and Miller, 1986).
Plant. On and/or in bean plants, the methylthio group is rapidly oxidized to the sulfoxide and sulfone (Abdel-Wahab et al., 1966) followed by hydrolysis yielding the corresponding thiophenol, methylsulfoxide phenol and methylsulphonyl phenol (Har
Photolytic. When methiocarb in ethanol was irradiated by UV light, only a few unidentified cholinesterase inhibitors were formed (Crosby et al., 1965).
Chemical/Physical. Emits toxic fumes of nitrogen and sulfur oxides when heated to decomposition (Sax and Lewis, 1987).

신진 대사 경로

Methiocarb is oxidised to a sulfoxide and a sulfone in biological media. The resulting two carbamate esters and the parent compound are hydrolysed in soils and plants to the corresponding phenols. Hydroxylation of the N-methyl group on the carbamate function occurs in mammalian preparations in vitro.

운송 방법

UN2757 Carbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required

폐기물 처리

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform to EPA regulations governing storage, transportation, treatment, and waste disposal. Remove material with contaminated soil and place in impervious containers. May be incinerated in a pesticide incinerator at the specified temperature/dwell-time combination. Any liquids, sludges, or solid residues generated should be disposed of in accordance with all applicable federal, state, and local pollution control requirements. If appropriate incineration facilities are not available, material may be buried in a chemical waste landfill. May be amenable to biological treatment at a municipal sewage treatment plant. (Sax/DPIMR).

메티오캅 준비 용품 및 원자재

원자재

준비 용품


메티오캅 공급 업체

글로벌( 102)공급 업체
공급자 전화 이메일 국가 제품 수 이점
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28180 58
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845
sales@amoychem.com China 6387 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873
sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 49392 58
career henan chemical co
+86-0371-86658258 +8613203830695
factory@coreychem.com China 29822 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578
sales@hbmojin.com China 12446 58
SIMAGCHEM CORP
+86-13806087780
sale@simagchem.com China 17367 58
TargetMol Chemicals Inc.
+1-781-999-5354 +1-00000000000
marketing@targetmol.com United States 19892 58
LEAP CHEM CO., LTD.
+86-852-30606658
market18@leapchem.com China 24738 58
Hebei Guanlang Biotechnology Co., Ltd.
+8619930503259
cherry@crovellbio.com China 18420 58

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