tert-부틸나이트라이트
|
|
tert-부틸나이트라이트 속성
- 끓는 점
- 61-63 °C(lit.)
- 밀도
- 0.867 g/mL at 25 °C(lit.)
- 증기압
- 13.466kPa at 25℃
- 굴절률
- n
20/D 1.368(lit.)
- 인화점
- −10 °F
- 저장 조건
- 2-8°C
- 용해도
- 알코올: 매우 용해됨(lit.)
- 물리적 상태
- 액체
- 색상
- 맑은 노란색
- 수용성
- 약간 용해됨
- Merck
- 14,1583
- BRN
- 1209339
- LogP
- 2.24 at 20℃
- CAS 데이터베이스
- 540-80-7(CAS DataBase Reference)
- NIST
- (CH3)3CONO(540-80-7)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | F,Xn | ||
---|---|---|---|
위험 카페고리 넘버 | 11-20/22 | ||
안전지침서 | 16-24-46 | ||
유엔번호(UN No.) | UN 2351 3/PG 2 | ||
WGK 독일 | 1 | ||
RTECS 번호 | RA0802000 | ||
F 고인화성물질 | 8 | ||
위험 등급 | 3 | ||
포장분류 | II | ||
HS 번호 | 29209085 |
tert-부틸나이트라이트 C화학적 특성, 용도, 생산
화학적 성질
clear yellow liquid용도
tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.일반 설명
tert-Butyl nitrite (TBN) is an efficient NO source. TBN participates in photocatalyzed conversion of aryl- and heteroarylamines to selenides. It also participates in radical multifunctionalization reactions of aliphatic alkenes.Purification Methods
If it is free from OH bands (IR) then distil it through a 12inch helices packed column under reduced pressure, otherwise wash with aqueous 5% NaHCO3 (effervescence), then H2O, dry (Na2SO4) and fractionate it through a 10 theoretical plates column at ca 10mm pressure. [Allen J Chem Soc 1968 1954, Coe & Doumani J Am Chem Soc 70 1516 1948, UV: Ungnade & Smiley J Org Chem 21 993 1956, IR: Terte Bull Soc Chim Belg 60 240 1951, Beilstein 1 IV 1622.]tert-부틸나이트라이트 준비 용품 및 원자재
원자재
질산 은
클로로-2-메틸프로판
질소 테트라산화물
산화 질소
Benzyln-butylether
tert-butoxy
TERT-BUTYL NITRATE
2-Methyl-2-nitropropane
tert-부틸알코올
3차부틸 하이드로 퍼옥사이드
3,3-Dimethylbutyraldehyde
2-브로모-2-메틸프로판
준비 용품
8-Quinolineboronic acid
2-Bromo-5-hydroxypyridine radical ion(1+)
2-Chloro-5-cyano-3-methylpyridine
Goserelin
2-CHLORO-5-IODO-3-METHYLPYRIDINE
4,7-DIHYDRO-4-OXO-3H-PYRROLO[2,3-D][1,2,3]TRIAZINE-5-CARBOXAMIDE
2-Bromo-5-fomylthiazole
2,6-Dibromoanthraquinone
3,5-Diiodobenzoic acid
4-CHLORO-2-NITROPHENOL
tert-butyl 2-bromo-6,7-dihydrothiazolo[5,4-c]pyridine-5(4H)-carboxylate
S-NITROSOGLUTATHIONE
tert-부틸나이트라이트 공급 업체
글로벌( 417)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Henan Fengda Chemical Co., Ltd | +8613613820652 |
info@fdachem.com | China | 4685 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21703 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 |
fandachem@gmail.com | China | 9359 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32480 | 60 |
career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29919 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 |
sales@amoychem.com | China | 6387 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 |
sales@chemdad.com | China | 39916 | 58 |
Alchem Pharmtech,Inc. | 8485655694 |
sales@alchempharmtech.com | United States | 63711 | 58 |