안식향산메틸

안식향산메틸
안식향산메틸 구조식 이미지
카스 번호:
93-58-3
한글명:
안식향산메틸
동의어(한글):
벤조산메틸;메틸벤조에이트;안식향산메틸;메틸벤조에이트;메틸 벤조에이트
상품명:
Methyl benzoate
동의어(영문):
BENZOIC ACID METHYL ESTER;NIOBE OIL;FEMA 2683;Oilofmiobe;Oniobe oil;Oxidate le;OIL OF NIOBE;Methylbenzoat;Slethylbenzoat;METHYL BENZOATE
CBNumber:
CB8252119
분자식:
C8H8O2
포뮬러 무게:
136.15
MOL 파일:
93-58-3.mol
MSDS 파일:
SDS

안식향산메틸 속성

녹는점
-12 °C (lit.)
끓는 점
198-199 °C (lit.)
밀도
1.088 g/mL at 20 °C (lit.)
증기 밀도
4.68 (vs air)
증기압
<1 mm Hg ( 20 °C)
FEMA
2683 | METHYL BENZOATE
굴절률
n20/D 1.516(lit.)
인화점
181 °F
저장 조건
Store at +5°C to +30°C.
용해도
에탄올: 용해성60%, 투명(1mL/4ml)
물리적 상태
액체
Specific Gravity
1.087~1.095 (20℃)
색상
무색~담황색 투명
냄새
디프로필렌 글리콜 중 1.00%. 페놀릭 윈터그린 아몬드 플로럴 카낭가
?? ??
페놀성
폭발한계
8.6-20%(V)
수용성
22.5&C에서 <0.1g/100mL
JECFA Number
851
Merck
14,6024
BRN
1072099
Dielectric constant
6.6(20℃)
안정성
안정적인. 타기 쉬운. 강한 산화제, 강산, 강염기와 호환되지 않습니다.
LogP
2.12-2.2 at 20℃
CAS 데이터베이스
93-58-3(CAS DataBase Reference)
NIST
Benzoic acid, methyl ester(93-58-3)
EPA
Methyl benzoate (93-58-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn
위험 카페고리 넘버 22
안전지침서 36
유엔번호(UN No.) UN 2938
WGK 독일 1
RTECS 번호 DH3850000
자연 발화 온도 510 °C
TSCA Yes
HS 번호 29163100
유해 물질 데이터 93-58-3(Hazardous Substances Data)
독성 LD50 orally in rats: 3.43 g/kg (Smyth)
기존화학 물질 KE-23483
그림문자(GHS): GHS hazard pictograms
신호 어: Warning
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P501 ...에 내용물 / 용기를 폐기 하시오.
NFPA 704
2
1 0

안식향산메틸 C화학적 특성, 용도, 생산

개요

Methyl benzoate is an organic compound. It is an ester with the chemical formula C6H5CO2CH3. It is a colorless liquid that is poorly soluble in water, but miscible with organic solvents. Methyl benzoate has a pleasant smell, strongly reminiscent of the fruit of the feijoa tree, and it is used in perfumery. It also finds use as a solvent and as a pesticide used to attract insects such as orchid bees.

화학적 성질

Methyl Benzoate has been found in essential oils (e.g., ylang-ylang oil). It is a colorless liquid with a strong, dry-fruity, slightly phenolic odor. Methyl benzoate can be converted simply into other benzoates by transesterification. Since methyl benzoate is a fairly large by-product in the manufacture of Terylene, earlier synthetic routes such as those starting from benzoic acid or benzoyl chloride have largely been abandoned.

물리적 성질

Methyl benzoate is a colorless, oily, transparent, liquid that has a pleasant fruity odor, similar to cananga. miscible with ether, soluble in methanol and ether, insoluble in water and glycerol. It is used in perfume bases, such as ylang-ylang and tuberose types.

출처

Methyl benzoate can be isolated from the freshwater fern Salvinia molesta. It is one of many compounds that is attractive to males of various species of orchid bees, which apparently gather the chemical to synthesize pheromones; it is commonly used as bait to attract and collect these bees for study.
Cocaine hydrochloride hydrolyzes in moist air to give methyl benzoate; drug - sniffing dogs are thus trained to detect the smell of methyl benzoate.

정의

ChEBI: Methyl benzoate is a benzoate ester obtained by condensation of benzoic acid and methanol. It has a role as a metabolite and an insect attractant. It is a benzoate ester and a methyl ester.

제조 방법

Methyl benzoate is manufactured by heating benzoic acid and dimethyl sulfate to high temperature, or by exchange between ethyl benzoate and methanol in KOH solution. It may also be produced by the alcoholysis of benzonitrile. It is a by-product of ozonolysis of water.

주요 응용

Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. It is naturally occurring in guava, mango, and kiwifruit. It is one of many compounds that is attractive to males of various species of orchid bees, who apparently gather the chemical to synthesize pheromones. It can also be utilized as a precursor for:
Selective synthesis of benzaldehyde using supported manganese oxide catalysts.
Preparation of benzophenone derivatives by reacting with aryl compounds via Friedel-Crafts acylation.

일반 설명

A crystalline solid or a solid dissolved in a liquid. Denser than water. Contact may slightly irritate skin, eyes and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.

공기와 물의 반응

Slightly soluble in water. Hydrolyzes slowly in contact with water .

반응 프로필

Methyl benzoate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Methyl benzoate reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. .

위험도

Toxic by ingestion.

건강위험

Methyl benzoate is a mild skin irritant. Irritating to the eyes, nose, throat, upper respiratory tract, and skin. May cause allegic skin and respiratory reactions.Theacute oral toxicity in test animals was oflow order. The toxic symptoms in animalsfrom oral administration of this compoundwere tremor, excitement, and somnolence.The LD50 value varies with species. The oralLD50 values in mice and rats are 3330 and1350 mg/kg, respectively.

Safety Profile

Moderately toxic by ingestion. Mildly toxic by skin contact. A skin and eye irritant. Combustible liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical, water to blanket fire. When heated to decomposition it emits acrid smoke and irritating fumes.

잠재적 노출

Used as food additive and as a solvent for cellulose esters and ethers, resins and rubber.

Purification Methods

Wash the ester with dilute aqueous NaHCO3, then water, dry with Na2SO4 and fractionally distil it in a vacuum. [Beilstein 9 IV 283.]

폐기물 처리

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

안식향산메틸 준비 용품 및 원자재

원자재

준비 용품


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