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디메틸아민

디메틸아민
디메틸아민 구조식 이미지
카스 번호:
124-40-3
한글명:
디메틸아민
동의어(한글):
디메틸아민;다이메틸아민,무수(다이메틸아민,무수);디메틸아민(50%수용액);디메틸아민(기체);N-메틸메탄아민;N,N-디메틸아민;디메칠아민;다이메틸아민;7-(아세틸옥시)-4-메틸-2-벤조파이론
상품명:
Dimethylamine
동의어(영문):
DMA-40;DMA-60;DMA-65;(CH3)2NH;ai3-15638-x;Dimethylamin;DIMETHYLAMINE;DiMethylaMine aq;Dimethylamine (I);N N DIMETYLANILINE
CBNumber:
CB8852986
분자식:
C2H7N
포뮬러 무게:
45.08
MOL 파일:
124-40-3.mol

디메틸아민 속성

녹는점
−93 °C(lit.)
끓는 점
7 °C(lit.)
밀도
0.89 g/mL at 25 °C
증기 밀도
1.55 (vs air)
증기압
16.97 psi ( 55 °C)
굴절률
n20/D 1.37
인화점
60 °F
저장 조건
Flammables area
용해도
very soluble in water (163 g/100 g water at 40°C); soluble in ethanol, ethyl ether, and many organic solvents
물리적 상태
Solution
산도 계수 (pKa)
10.68(at 25℃)
색상
Clear slightly yellow
냄새
Ammonical odour
Odor Threshold
0.033ppm
폭발한계
14.4%
수용성
Miscible with water and most organic solvents.
감도
Hygroscopic
Merck
14,3228
BRN
605257
Henry's Law Constant
1.75(x 10-5 atm?m3/mol) at 25 °C (Christie and Crisp, 1967)
노출 한도
TLV-TWA 10 ppm (~18 mg/m3) (ACGIH, MSHA, and OSHA); IDLH 2000 ppm (NIOSH).
안정성
Stable. Generally used as a solution in water at concentrations up to around 40%. Extremely flammable in the pure form. Incompatible with strong oxidizing agents.
CAS 데이터베이스
124-40-3(CAS DataBase Reference)
NIST
Methanamine, N-methyl-(124-40-3)
EPA
Dimethylamine (124-40-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F+,Xn,C,F,T
위험 카페고리 넘버 12-20-37/38-41-34-20/22-11-39/23/24/25-23/24/25-52/53-40-19
안전지침서 3-16-26-29-36/37/39-45-39-61
유엔번호(UN No.) UN 2924 3/PG 2
WGK 독일 2
RTECS 번호 IP8750000
F 고인화성물질 3
자연 발화 온도 753 °F
TSCA Yes
DOT ClassificationII 2.1 (Flammable gas)
위험 등급 3
포장분류 II
HS 번호 29211100
유해 물질 데이터 124-40-3(Hazardous Substances Data)
독성 Acute oral LD50 for guinea pigs 340 mg/kg, mice 316 mg/kg, rats 698 mg/kg, rabbits 240 mg/kg (quoted, RTECS, 1985).
기존화학 물질 KE-11124
그림문자(GHS):
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H220 극인화성 가스 인화성 가스 구분 1 위험 P210, P377, P381, P403
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H280 고압가스; 가열시 폭발할 수 있음 고압가스 압축가스
액화가스
용존 가스
경고 P410+P403
H301 삼키면 유독함 급성 독성 물질 - 경구 구분 3 위험 P264, P270, P301+P310, P321, P330,P405, P501
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 P264, P270, P301+P312, P330, P501
H311 피부와 접촉하면 유독함 급성 독성 물질 - 경피 구분 3 위험 P280, P302+P352, P312, P322, P361,P363, P405, P501
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 P264, P280, P302+P352, P321,P332+P313, P362
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 P280, P305+P351+P338, P310
H331 흡입하면 유독함 급성 독성 물질 흡입 구분 3 위험 P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H332 흡입하면 유해함 급성 독성 물질 흡입 구분 4 경고 P261, P271, P304+P340, P312
H333 흡입하면 유해할 수 있음 급성 독성 물질 흡입 구분 5 P304+P312
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고
H351 암을 일으킬 것으로 의심됨 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
H370 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킴(노출되어도 특정 표적장기 독성을 일으키지 않는다는 결정적인 노출경로가 있다면 노출경로를 기재) 특정 표적장기 독성 - 1회 노출 구분 1 위험 P260, P264, P270, P307+P311, P321,P405, P501
H412 장기적 영향에 의해 수생생물에 유해함 수생 환경유해성 물질 - 만성 구분 3 P273, P501
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P311 의료기관(의사)의 진찰을 받으시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P370+P378 화재 시 불을 끄기 위해 (Section 5. 폭발, 화재시 대처방법의 적절한 소화제)을(를) 사용하시오.
P405 밀봉하여 저장하시오.
P403+P235 환기가 잘 되는 곳에 보관하고 저온으로 유지하시오.
P410+P403 직사광선을 피하고 환기가 잘 되는 곳에 보관하시오.
NFPA 704
4
3 0

디메틸아민 C화학적 특성, 용도, 생산

물성

물, 에탄올 및 에테르에 용해되고, 쉽게 연소되며 약 알칼리성이며 물에 용해되는 무기산 염이 생성됩니다.

개요

디메틸 아민 (DMA)의 다른 이름 N- 메틸 메탄 아민 (디메틸) 아민은 동식물에 널리 분포되어있다. 디메 폭스 (dimefox) 및 디페 닐 하이드라 민 (diphenhydramine)과 같은 많은 농약 및 의약품 생산을위한 원료입니다. DMA는 20 ℃에서 무색의 가스이며 암모니아 냄새와 유사합니다.

용도

디메틸 아민 (DMA)은 주로 고무 가황 촉진제, 가죽 탈모 방지제, 의약품, 살충제, 섬유 산업용 솔벤트, 염료, 폭발물, 추진제 및 디메틸 히드라진, N, N- 디메틸 포름 아미드 및 유기 중간체의 기타 원료에 사용됩니다.

개요

Dimethylamine is a colourless flammable gas at room temperature. It has a pungent, fishy, or ammonia-like odour at room temperature and is shipped and marketed in compressed liquid form. It is very soluble in water and soluble in alcohol and ether. It is incompatible with oxidising materials, acrylaldehyde, fluorine, maleic anhydride, chlorine, or mercury. Dimethylamine is a precursor to several industrially important compounds. For instance, it used in the manufacture of several products, for example, for the vulcanisation process of rubber, as detergent soaps, in leather tanning, in the manufacture of pharmaceuticals, and also for cellulose acetate rayon treatment.
dimethylamine structure
dimethylamine structure

화학적 성질

Dimethylamine reacts readily with acids to produce salts due to the presence of the unshared electron pair on the nitrogen atom. Similarly, dimethylamine reacts with acid anhydrides, halides, and esters, with CO2 or CS2, or with isocyanic or isothiocyanic acid derivatives. It can also react with nitrite, especially under acidic conditions, and possibly nitrogen oxides (Iqbel 1986) to form N-nitrosodimethylamine, a potent carcinogen in various animal species and a suspect human carcinogen (ATSDR 1989; Scanlan 1983; Zeisel et al 1988). N-Nitrosodimethylamine also can be formed upon storage of aqueous dimethylamine solutions or formulations of the dimethylamine salts of the herbicides 2,4D and MCPA (Wigfield and McLenaghan 1987a,b). Dimethylamine also can be nitrosated photochemically in aqueous solutions containing nitrite with the reaction occurring most readily at alkaline pH (Ohta et al 1982).

물리적 성질

Clear, colorless liquid or gas with a strong, ammonia-like odor. Odor threshold concentrations of 33 ppbv and 47 ppbv were experimentally determined by (Leonardos et al., 1969) and Nagata and Takeuchi (1990), respectively.

용도

Dimethylamine is used in the manufactureof N-methylformamide, N-methylacetamide,and detergent soaps; in tanning; and as anaccelerator in vulcanizing rubber. It is commercially sold as a compressed liquid intubes or as a 33% aqueous solution..

용도

Manufacture of pharmaceuticals; stabilizer in gasoline; in production of insecticides and fungicides; in manufacture of soaps and surfactants

정의

ChEBI: A secondary aliphatic amine where both N-substituents are methyl.

생산 방법

Methods used commercially for the large-scale production of dimethylamine are generally those used for methylamine synthesis (HSDB 1989). The most widely used process involves heating ammonium chloride and methyl alcohol to about 300°C in the presence of a dehydrating catalyst such as zinc chloride. Dimethylamine has also been prepared from methanol and ammonia or by the catalytic hydrogenation of nitrosodimethylamine (Schweizer et al 1978). It is usually marketed in compressed liquid (anhydrous) form or as a 25-60% aqueous solution.
Dimethylamine is also naturally present in biological systems, probably being formed as a breakdown product from trimethylamine N-oxide (Timofievskaja 1984). Thus it is present in gastric juice of humans, rats, dogs and ferrets at concentrations of 12.6 ± 14 nmol/ml (Zeisel et al 1988); it is a constituent of most foods, especially seafood including squid and octopus, frequently eaten in traditional Chinese and Japanese diets, where it reaches concentrations of 946-2043 p.p.m. (Lin et al 1983,1984). Food processing and cooking markedly increases the dimethylamine contents of foods by increasing the breakdown of constituents such as trimethylamine N-oxide and sarcosine (Lin et al 1983, 1984; Lin and Hurng 1985). Dimethylamine occurs in the air of iron foundries where the amine was used in the casting process (Hansen et al 1985) and also is released from plastic material used in construction (Kiselev et al 1983).
Nitrosation of dimethylamine occurs forming the carcinogenic N-nitrosodimethylamine upon storage of anhydrous and aqueous solutions of dimethylamine or formulations of the dimethylamine salts of the herbicides 2,4-dichlorophenoxyacetic acid (2,4D), 4-chloro-2-methylphenoxyacetic acid (MCPA) and 3,6-dichloro- 2-methoxybenzoic acid (dicamba) (Wigfield and McLenaghan 1987a,b). The volatile N-nitrosodimethylamine is also formed in foods by reaction of dimethylamine with sodium nitrite added as a preservative or by reaction with atmospheric nitrogen oxides during food processing (ATSDR 1989; Gross and Newberne 1977; Scanlan 1983). Concentrations of the nitrosoamine in cheese, apple cider, milk, cereals, vegetables, seafood, cured meats, etc. range between 0.05 and 130 p.p.b. (ATSDR 1989).

공기와 물의 반응

Highly flammable. Water soluble.

반응 프로필

DIMETHYLAMINE is a base, neutralizing acids in exothermic reactions, and a reducing agent. Dimethylamine is temperature sensitive. Reacts vigorously with mercury and chlorine . Reacts violently with strong oxidizing agents and attacks copper and copper compounds [Handling Chemicals Safely, 1980 p. 123]. Reacts with hypochlorites to give N-chloroamines, some of which are explosives when isolated [Bretherick, 1979 p. 108].

위험도

Dimethylamine is an irritant, with a TLV of 10 ppm in air. The four-digit UN identification number is 1032. The NFPA 704 designation is health 3, flammability 4, and reactivity 0. The primary uses are in electroplating and as gasoline stabilizers, pharmaceuticals, missile fuels, pesticides, and rocket propellants.

건강위험

Dimethylamine is a strong irritant to the eyes,skin, and mucous membranes. Spill of liquidinto the eyes can cause corneal damage andloss of vision. Skin contact with the liquidcan produce necrosis. At sublethal concentra tions, inhalation of dimethylamine producedrespiratory distress, bronchitis, pneumonitis,and pulmonary edema in test animals. Theacute oral toxicity was moderate, greater thanfor monomethylamine.
LC50 value, inhalation (rats): 4540 ppm/6 hLD50 value, oral (mice): 316 mg/kg
Buckley and coworkers (1985) have investigated the inhalation toxicity of dimethylamine in F-344 rats and B6C3F1 mice.Animals exposed to 175 ppm for 6 h/day,5 days/week for 12 months showed significant lesions in the nasal passages. Rats developed more extensive olfactory lesions thandid mice. The study indicated that olfactory sensory cells were highly sensitive todimethylamine. Even at a concentration of10 ppm, the current threshold limit value,the rodents developed minor lesions fromexposure.

화재위험

FLAMMABLE. Flashback along vapor trail may occur. May explode if ignited in an enclosed area. Vapors are eye, skin and respiratory irritants.

공업 용도

Dimethylamine is used as an accelerator in vulcanizing rubber, as an antiknock agent for fuels, in photography, as a plasticizer, ion exchange agent, as an acid gas absorbent, a flotation agent, a dehairing agent in the tanning of leather and in electroplating (HSDB 1989; Sax and Lewis 1987; Windholz et al 1983). Dimethylamine also serves as the base for a large number of commercial products including detergent soaps, dyes, pharmaceuticals, textile chemicals, surfactants and in the manufacture of unsymmetrical dimethylhydrazine (used in missile fuels), the solvent dimethylacetanilide and in the synthesis of dimethylformamide, one of the most commonly used organic solvents. Usage of dimethylamine in 1972 was estimated at 50% for production of dimethylformamide and dimethylacetamide (used as spinning solvents for acrylic fibers), 15% as an intermediate in the preparation of the surfactant laurel dimethylamine oxide, 15% as an intermediate for rubber chemicals (including thorium accelerators), and 20% for other applications including the production of unsymmetrical dimethylhydrazine in rocket fuels and the dimethylamine salt of 2,4-dichlorophenoxyacetic acid (HSDB 1989). U.S. production and sales of dimethylamine in 1985 was 65.9 million pounds.

Safety Profile

Poison by ingestion. Moderately toxic by inhalation and intravenous routes. Mutation data reported. An eye irritant. Corrosive to the eyes, skin, and mucous membranes. A flammable gas. When heated to decomposition it emits toxic fumes of Nx,. Incompatible with acrylddehyde, fluorine, and maleic anhydride

Carcinogenicity

In a 2 year inhalation study in male F344 rats exposed to 175 ppm, no evidence of carcinogenicity was observed, and in addition, despite severe tissue destruction in the anterior nose following a single 6 h exposure, the nasal lesions exhibited very little evidence of progression, even at 2 years of exposure. The authors concluded that this indicated possible regional susceptibility to DMA toxicity or a degree of adaptation by the rat to continued DMA exposure.
A detailed evaluation of mucociliary apparatus function and response to alterations of nasal structure was presented by the authors.

Source

Dimethylamine naturally occurs in soybean seeds (8 ppm), cauliflower (14 ppm), kale leaves (5.5 ppm), barleygrass seeds (1.6 ppm), tobacco leaves, hawthorne leaves, hops flower (1.4 ppm), cabbage leaves (2–2.8 ppm), corn (1–3.5 ppm), celery (5.1 ppm), grapes, grape wine, and grape juice (Duke, 1992).

환경귀착

Photolytic. Dimethylnitramine, nitrous acid, formaldehyde, N,N-dimethylformamide and carbon monoxide were reported as photooxidation products of dimethylamine with NOx. An additional compound was tentatively identified as tetramethylhydrazine (Tuazon et al., 1978). In the atmosphere, dimethylamine reacts with OH radicals forming formaldehyde and/or amides (Atkinson et al., 1978). The rate constant for the reaction of dimethylamine and ozone in the atmosphere is 2.61 x 10-18 cm3/molecule?sec at 296 K (Atkinson and Carter, 1984).
Soil. After 2 d, degradation yields in an Arkport fine sandy loam (Varna, NY) and sandy soil (Lake George, NY) amended with sewage and nitrite-N were 50 and 20%, respectively. NNitrosodimethylamine was identified as the major metabolite (Greene et al., 1981). Mills and Alexander (1976) reported that N-nitrosodimethylamine also formed in soil, municipal sewage, and lake water supplemented with dimethylamine (ppm) and nitrite-N (100 ppm). They found that nitrosation occurred under nonenzymatic conditions at neutral pHs.
Photolytic. Low et al. (1991) reported that the photooxidation of aqueous secondary amine solutions by UV light in the presence of titanium dioxide resulted in the formation of ammonium and nitrate ions.
Chemical/Physical. In an aqueous solution, chloramine reacted with dimethylamine forming N-chlorodimethylamine (Isaac and Morris, 1983).
Reacts with mineral acids forming water soluble ammonium salts and ethanol (Morrison and Boyd, 1971).

신진 대사

Dimethylamine is normally present in the stomach and urine of animals and humans. The secondary amine is formed from trimethylamine (a breakdown product of dietary choline) via trimethylamine N-oxide (Zeisel et al 1985) and probably also from dietary lecithin and creatine (Lewis et al 1985). Enzymes within gut bacteria catalyze these conversions. The resulting dimethylamine is readily absorbed primarily from the small intestine, and to a much lesser extent, the stomach, and excreted in the urine (Ishiwata et al 1984; Zeisel et al 1983). Humans consuming a diet high in fish show at least a 4-fold increase in urinary dimethylamine excretion (Zeisel and Dacosta 1986).
Although dimethylamine may arise primarily from trimethylamine in a process catalyzed by bacteria, when rats were fed a commercial diet containing 23.6 p.p.m. dimethylamine, nearly 50% of the amine was recovered in the stomach with progressively declining amounts found towards lower regions of the gastrointestinal tract (Ishiwata et al 1984). Using ligated sections, the t1/2 of dimethylamine was found to be 198 min in the stomach with the intestines and caecum varying from 8.3-31.5 min. The results indicated that dimethylamine is rapidly absorbed from the intestine and into the blood from where it disappears quickly, to be excreted predominately in the urine with a small amount excreted into the bile.
In rats fed a choline deficient diet, or rats devoid of gut bacteria, dimethylamine was still excreted in the urine (Zeisel et al 1985). This suggests that mammalian cells may possess other, as yet undefined, endogenous pathways for forming dimethylamine. The absorption, distribution and secretion of dimethylamine in the digestive tract and its biliary and urinary excretion was studied in male Wistar rats (Ishiwata et al 1984). Animals were fed diets containing 1 or 23.6 p.p.m. dimethylamine for one wk and then killed. Single i.v. doses also were administered to control and bile-duct cannulated rats and the urine collected over a 24 h period. The authors found high dimethylamine concentrations in the upper part of the gastrointestinal tract and a low concentration in the lower intestine. The half-life for injected dimethylamine was 12.5 min and excretion was primarily via the bile.
The disposition and pharmacokinetics of [14C]-dimethylamine were also studied in male Fischer 344 rats following 6 h inhalation of 10 or 175 p.p.m. of the labeled amine (McNulty and Heck 1983). At 72 h after exposure, the disposition at both doses was similar with greater than 90% of the radioactivity appearing in the urine and feces, 7-8% in various tissues and 1.5% exhaled as 14CO2. Over 98% of the urinary radioactivity was the parent [14C]-dimethylamine. However, some formation of small quantities of dimethylamine oxidative metabolites was seen.
Much of the concern over the presence of dimethylamine in humans stems from its ability to serve as a precursor for the formation of the putative carcinogen, N-nitrosodimethylamine. Accordingly, several studies have been conducted to assess the potential for exogenously administered dimethylamine to form this nitroso compound. When dimethylamine was given intravenously to dogs and ferrets, the amine was rapidly transported from the blood into the gastric fluid, where N-nitrosodimethylamine formation can occur (Zeisel et al 1986). Nnitrosodimethylamine was formed in vitro when sodium nitrite was added to dog (Lintas et al 1982) or human gastric fluid (Zeisel et al 1988). The resulting N-nitrosamine then is rapidly absorbed from the stomach. When conventional and germfree male Wistar rats were treated with dimethylamine and sodium nitrite, severe liver necrosis was observed at 48 h only in the germfree animals (Sumi and Miyakawa 1983). This may indicate, at least in this species, that metabolism of dimethylamine by intestinal microflora may minimize nitrosamine formation. 7V-nitrosodimethylamine requires metabolic activation to form the reactive alkylating species responsible for the carcinogenic and mutagenic activity of the nitrosamine (ATSDR 1989).

저장

Dimethylamine should be stored in a cool, dry, well-ventilated area in tightly sealed containers that are labeled in accordance with OSHA’s Hazard Communication Standard [29 CFR 1910.1200]. Containers of dimethylamine should be protected from physical damage and ignition sources, and should be stored separately from oxidizing materials, acrylaldehyde, fl uorine, maleic anhydride, chlorine, and mercury. Outside or detached storage is preferred. If stored inside, a standard flammable liquids cabinet or room should be used. Ground and bond metal containers and equipment when transferring liquids. Empty containers of dimethylamine should be handled appropriately.

Purification Methods

Dry dimethylamine by passage through a KOH-filled tower, or by standing with sodium pellets at 0o during 18hours. [Beilstein 4 IV 128.]

주의 사항

During handling of dimethylamine, workers should use proper fume hoods, personal protective clothing and equipment, avoid skin contact, and use gloves, sleeves, and encapsulating suits. Dimethylamine is extremely flammable and may be ignited by heat, sparks, or open flames. Liquid dimethylamine will attack some forms of plastic, rubber, and coatings and is flammable. The vapors of dimethylamine are an explosion and poison hazard. Containers of dimethylamine may explode in the heat of a fi re and require proper disposal. Workers should use dimethylamine with adequate ventilation and containers must be kept properly closed.

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