ChemicalBook
Chinese english Germany Japanese Korea

Eisentrichlorid Produkt Beschreibung

Ferric chloride Struktur
7705-08-0
CAS-Nr.
7705-08-0
Bezeichnung:
Eisentrichlorid
Englisch Name:
Ferric chloride
Synonyma:
DB03;FeCl3;Molysite;TDA REAGENT;floresmartis;Flores martis;IRON CHLORIDE;Iron(III) chL;FERRIC CHLORID;Molysite Cl3Fe
CBNumber:
CB5444364
Summenformel:
Cl3Fe
Molgewicht:
162.2
MOL-Datei:
7705-08-0.mol

Eisentrichlorid Eigenschaften

Schmelzpunkt:
304 °C(lit.)
Siedepunkt:
316 °C
Dichte
2,804 g/cm3
Dampfdichte
5.61 (vs air)
Dampfdruck
1 mm Hg ( 194 °C)
Brechungsindex
n20/D1.414
Flammpunkt:
316°C
storage temp. 
Store below +30°C.
Löslichkeit
H2O: soluble
Aggregatzustand
powder
Farbe
Yellow
Wichte
2.804
PH
1 (200g/l, H2O, 20℃)
Wasserlöslichkeit
920 g/L (20 ºC)
Sensitive 
Hygroscopic
Merck 
14,4019
Stabilität:
Stable. Very sensitive to moisture. Incompatible with strong oxidizing agents; forms explosive mixtures with sodium, potassium. Hygroscopic.
CAS Datenbank
7705-08-0(CAS DataBase Reference)
NIST chemische Informationen
Ferric chloride(7705-08-0)
EPA chemische Informationen
Ferric chloride (7705-08-0)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher C,Xn,Xi
R-Sätze: 41-38-22-34-37/38-10-36
S-Sätze: 26-39-45-36/37/39
RIDADR  UN 2582 8/PG 3
WGK Germany  1
RTECS-Nr. LJ9100000
TSCA  Yes
HS Code  2827 39 20
HazardClass  8
PackingGroup  III
Giftige Stoffe Daten 7705-08-0(Hazardous Substances Data)
Toxizität LD50 orally in Rabbit: 316 mg/kg
Bildanzeige (GHS)
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H226 Flüssigkeit und Dampf entzündbar. Entzündbare Flüssigkeiten Kategorie 3 Warnung
H290 Kann gegenüber Metallen korrosiv sein. Korrosiv gegenüber Metallen Kategorie 1 Warnung P234, P390, P404
H302 Gesundheitsschädlich bei Verschlucken. Akute Toxizität oral Kategorie 4 Warnung P264, P270, P301+P312, P330, P501
H314 Verursacht schwere Verätzungen der Haut und schwere Augenschäden. Ätzwirkung auf die Haut Kategorie 1B Achtung P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung P264, P280, P302+P352, P321,P332+P313, P362
H318 Verursacht schwere Augenschäden. Schwere Augenschädigung Kategorie 1 Achtung P280, P305+P351+P338, P310
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizität (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung
H411 Giftig für Wasserorganismen, mit langfristiger Wirkung. Langfristig (chronisch) gewässergefährdend Kategorie 2
Sicherheit
P261 Einatmen von Staub vermeiden.
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P309 BEI Exposition oder Unwohlsein:
P310 Sofort GIFTINFORMATIONSZENTRUM/Arzt/ anrufen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.

Eisentrichlorid Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD

SCHWARZE BIS BRAUNE HYGROSKOPISCHE KRISTALLE.

CHEMISCHE GEFAHREN

Zersetzung beim Erhitzen über 200°C unter Bildung giftiger und ätzender Gase mit Chlor und Chlorwasserstoff. Zersetzung bei Kontakt mit Wasser unter Bildung von Chlorwasserstoff. Mittelstarke Säure in wässriger Lösung. Reagiert sehr heftig mit Alkalimetallen, Allylchlorid, Ethylenoxid, Styrol und Basen unter Explosionsgefahr. Greift Metall an unter Bildung brennbarer/explosionsfähiger Gase (z.B. Wasserstoff, ICSC-Nr. 0001).

ARBEITSPLATZGRENZWERTE

TLV: (Lösliche Eisensalze, als Fe) 1 mg/m? (ACGIH 2005).
MAK nicht festgelegt (DFG 2005).

AUFNAHMEWEGE

Aufnahme in den Körper durch Verschlucken.

INHALATIONSGEFAHREN

Verdampfung bei 20°C vernachlässigbar; eine gesundheitsschädliche Partikelkonzentration in der Luft kann jedoch beim Dispergieren schnell erreicht werden.

WIRKUNGEN BEI KURZZEITEXPOSITION

WIRKUNGEN BEI KURZZEITEXPOSITION:
Die Substanz reizt die Augen, die Haut und die Atemwege. ätzend beim Verschlucken.

LECKAGE

Verschüttetes Material in Kunststoffbehältern sammeln; falls erforderlich durch Anfeuchten Staubentwicklung verhindern. NICHT in die Umwelt gelangen lassen. Persönliche Schutzausrüstung: Atemschutzgerät, P2-Filter für schädliche Partikel.

R-Sätze Betriebsanweisung:

R41:Gefahr ernster Augenschäden.
R38:Reizt die Haut.
R22:Gesundheitsschädlich beim Verschlucken.
R34:Verursacht Verätzungen.

S-Sätze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S39:Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.

Beschreibung

Ferric chloride (iron(IH)chloride, FeCl3, CAS No. 7705-08-0) may be prepared from iron and chlorine or from ferric oxide and hydrogen chloride. The pure material occurs as hydroscopic, hexagonal, dark crystals. Ferric chloride hexahydrate (iron(III)chloride hexahydrate, FeCl3*6H2O, CAS No. 10025-77-1) is readily formed when ferric chloride is exposed to moisture.

Chemische Eigenschaften

Ferric Chloride is a black-brown, dark-green, or black crystalline solid.

Chemische Eigenschaften

Ferric chloride,FeCl3, is a brown crystalline solid and is soluble in water,alcohol,and glycerol. It is also known as anhydrous ferric chloride,ferric trichloride, Flores martis,and iron chloride. Ferric chloride is used as a coagulant for sewage and industrial wastes, as an oxidizing and chlorinating agent,as a disinfectant, in copper etching, and as amordant. In addition, this compound is employed in the ferric chloride test,which is used to assess the relative corrosion resistance of stainless and nickel-base alloys. The ferric chloride test has been shown to be an appropriate measure of the suitability of such alloys for service in paper mill bleach plants and seawater.

Verwenden

Treatment of sewage and industrial wastes; etching agent for engraving, photography, and printed circuitry; condensation catalyst in FriedelCrafts reactions; mordant; oxidizing, chlorinating, and condensing agent; disinfectant; pigment; feed additive; wat

Verwenden

Ferric Chloride is a nutrient and dietary supplement that serves as a source of iron.

Allgemeine Beschreibung

Ferric chloride is an orange to brown-black solid. Ferric chloride is slightly soluble in water. Ferric chloride is noncombustible. When wet Ferric chloride is corrosive to aluminum and most metals. Pick up and remove spilled solid before adding water. Ferric chloride is used to treat sewage, industrial waste, to purify water, as an etching agent for engraving circuit boards, and in the manufacture of other chemicals.

Air & Water Reaktionen

Very hygroscopic. Slightly water soluble, where a 0.1M solution has a pH of 2.0.

Reaktivität anzeigen

Alkali metal hydroxides, acids, anhydrous chlorides of iron, tin, and aluminum, pure oxides of iron and aluminum, and metallic potassium are some of the catalysts that may cause ethylene oxide to rearrange and polymerize, liberating heat, [J. Soc. Chem. Ind. 68:179(1949)]. Explosions occur , although infrequently, from the combination of ethylene oxide and alcohols or mercaptans, [Chem. Eng. News 20:1318(1942)]. Allyl chloride may polymerize violently under conditions involving an acid catalyst, such as sulfuric acid, Ferric chloride, aluminum chloride, Lewis acids, and Ziegler type catalysts (initiators), [Ventrone (1971)].

Hazard

Toxic by ingestion, strong irritant to skin and tissue.

Health Hazard

Inhalation of dust may irritate nose and throat. Ingestion causes irritation of mouth and stomach. Dust irritates eyes. Prolonged contact with skin causes irritation and burns.

Brandgefahr

Special Hazards of Combustion Products: Irritating hydrogen chloride fumes may form in fire.

Industrielle Verwendung

Ferric chloride (FeCl3) is obtained by an iron chlorination method at a temperature of 600–700 °C. Very limited data are available on the use of ferric chloride in the mineral processing industry. Ferric chloride has a depressing effect on barite and can be used in barite–celestite separation. It was also evaluated as a depressant during niobium– zirconium separation. In general, ferric and ferrous compounds are not selective depressants and in many cases are detrimental for flotation of oxidic and industrial minerals as in the case of anionic flotation, fatty acid, iron complexes or oleate iron complexes.

Sicherheitsprofil

Poison by ingestion and intravenous routes. Experimental reproductive effects. Corrosive. Probably an eye, skin, and mucous membrane irritant. Mutation data reported. Reacts with water to produce toxic and corrosive fumes. Catalyzes potentially explosive polymerization of ethylene oxide, chlorine + monomers (e.g., styrene). Forms shock sensitive explosive mixtures with some metals (e.g., potassium, sodium). Violent reaction with all$ chloride. When heated to decomposition it emits highly toxic fumes of HCl.

mögliche Exposition

Iron chloride is used to treat sewage and industrial waste. It is also used as an etchant for photo engraving and rotogravure; in textiles; photography; as a disinfectant; as a feed additive.

Versand/Shipping

UN1773 Ferric chloride, anhydrous, Hazard class: 8; Labels: 8-Corrosive material. UN2582 Ferric chlo ride, solution, Hazard class: 8; Labels: 8-Corrosive material

läuterung methode

Sublime it at 200o in an atmosphere of chlorine. It is an “iron-black” coloured powder with green irridescence. Store it in a weighing bottle inside a desiccator as it absorbs moisture from air to form the yellow hexahydrate (see next entry). [Tarr Inorg Synth III 191 1950, Pray Inorg Synth V 153 1957, Epperson Inorg Synth VII 163 1963.]

Structure and conformation

The crystalline solid has a semicovalent layer structure with hexagonal packing of chloride ions, each iron atom being surrounded octahedrally by six chlorines in a BiI3 type structure. The dimers in the vapour phase have a structure similar to that of Al2Cl6 with the iron atoms surrounded by chlorines in a roughly tetrahedral fashion. The magnetic properties of iron(III) chloride in its different environments have been investigated extensively. The magnetic moment at 290°K is 5-73 B.M. and is independent of the field strength. In aqueous hydrochloric acid the room temperature moment is 5-94 B.M. and the hexahydrate has a similar moment (5-95 B.M.).

Inkompatibilitäten

Aqueous solutions are a strong acid. Violent reaction with bases, allyl chloride; sulfuric acid; water. Shock- and friction-sensitive explosive material forms with potassium, sodium and other active metals. Attacks metals when wet.

Waste disposal

Neutralize with lime or soda ash and bury in an approved landfill.

Eisentrichlorid Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Eisentrichlorid Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 339)Lieferanten
Firmenname Telefon Fax E-Mail Land Produktkatalog Edge Rate
Shanghai Time Chemicals CO., Ltd.
+8618017249410 +86-021-57951555
+86-021-57951555 jack.li@time-chemicals.com CHINA 1365 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679
86-0551-65418697 info@tnjchem.com China 3000 55
Tianjin Zhongxin Chemtech Co., Ltd.
022-66880623
022-66880086 sales@tjzxchem.com CHINA 537 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 29955 58
City Chemical LLC
2039322489
203.937.8400 sales@citychemical.com United States 97 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 linda@hubeijusheng.com CHINA 23035 58
Shanghai Longyu Biotechnology Co., Ltd.
+8615821988213
+86 15821988213 info@longyupharma.com China 2473 58
Chongqing Chemdad Co., Ltd
+86-13650506873
sales@chemdad.com CHINA 37282 58
HENAN BON INDUSTRIAL CO.,LTD
0371-55170695
info@hnbon.com CHINA 26742 58

7705-08-0(Eisentrichlorid)Verwandte Suche:


  • FERRIC CHLORIDE, ANHYDROUS, 97%FERRIC CHLORIDE, ANHYDROUS, 97%FERRIC CHLORIDE, ANHYDROUS, 97%
  • Ferric Chloride Manufacturer
  • Ferric chloride test solution(ChP)
  • Ferricchloride,anhydrous
  • Flores martis
  • floresmartis
  • Iron chloride (Fe2Cl3)
  • Iron chloride (FeCl3)
  • Iron perchloride
  • Iron sesquichloride
  • ironchloride(fecl3)
  • ironperchloride
  • naturalmolysite
  • Perchlorure de fer
  • perchloruredefer
  • IRON TRICHLORIDE
  • IRON(III) CHLORIDE
  • IRON (III) CHLORIDE ON SILICA
  • IRON CHLORIDE
  • IRON ATOMIC SPECTROSCOPY STANDARD
  • IRON(+3)CHLORIDE
  • Iron (III) chloride anhydrous
  • Iron(III) chloride, 5 wt.%
  • Ironchlorideanhydrous
  • FERRIC CHLORID
  • Iron(Ⅲ) chloride anhydrous
  • Iron(III) chloride, anhydrous, powder, 99.99+%
  • IRON(III) CHLORIDE SOLUTION 0.25 G/L IN
  • IRON(III) CHLORIDE SOLUTION 45 % FECL3, PURE
  • DB03
  • IRON(III) CHLORIDE 5 WT. % ON SILICA G&
  • IRON(III) CHLORIDE, 5 WT. % ON SILICA GE L
  • IRON(III) CHLORIDE REAGENT GRADE 97%
  • IRON ATOMIC SPECTROSCOPY STANDARD CONC. 1.00 G FE, AMPOULE
  • FerricChlorideAnydrous
  • Iron(Iii)ChlorideSolution
  • FerricChlorideGrAnhydrous
  • Ferricchloridesolution15%Fe
  • Iron(III) chloride, anhydrous, pure, 98%
  • Iron(III)chloride,anhydrous,98%
  • iron atomic spectroscopy standard concentrate 1.00 g fe
  • iron standard concentrate 10.00 g fe
  • FERRICCHLORIDE,41BSOLUTION
  • FERRICCHLORIDE,ANHYDROUS,POWDER,PURIFIED
  • FERRICCHLORIDE,ANHYDROUS,SUBLIMED,POWDER,REAGENT
  • FERRICCHLORIDE,ANHYDROUSTECH(BULK
  • FERRICCHLORIDE,SOLUTION(BULK
  • Eisen(III)-chlorid8
  • Iron(III) chloride anhydrous, powder, >=99.99% trace Metals basis
  • PROTEIN MW MARKER WIDE RANGE BIOTECH GR
  • SERAFREE CRYOPRESERVATION MEDIA TC GRADE
  • Iron(Ⅲ) Chloride Solution
  • Ferric chloride, anhydrous, Chemistry
  • Ferric Chloride Solution, 40% w/v
  • Ferric Chloride Solution, 0.025% (w/v)
  • Iron(III) chloride subliMed grade, >=99.9% trace Metals basis
  • Molysite
  • Iron(III) chloride on silica gel powder, extent of labeling: 5 wt. % loading
Copyright 2019 © ChemicalBook. All rights reserved