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Bromoacetaldehyde dimethyl acetal

CAS No.
7252-83-7
Chemical Name:
Bromoacetaldehyde dimethyl acetal
Synonyms
2-BROMO-1,1-DIMETHOXYETHANE;BADA;Dimethylbromoacetal;BADMA;2,2-Dimethoxybromoethane;2-Brom-1,1-dimethoxyethan;2,2-DIMETHOXYETHYL BROMIDE;2-BROMO-1,1-DIMETHYLETHANE;1,1-Dimethoxy-2-bromoethane;1-Bromo-2,2-dimethoxyethane
CBNumber:
CB7146143
Molecular Formula:
C4H9BrO2
Molecular Weight:
169.02
MDL Number:
MFCD00000213
MOL File:
7252-83-7.mol
MSDS File:
SDS
Last updated:2023-07-25 18:34:57

Bromoacetaldehyde dimethyl acetal Properties

Boiling point 148-150 °C (lit.)
Density 1.43 g/mL at 25 °C (lit.)
refractive index n20/D 1.445(lit.)
Flash point 129 °F
storage temp. 2-8°C
form clear liquid
color Colorless to Light orange to Yellow
Specific Gravity 1.445
Water Solubility insoluble
Sensitive Moisture Sensitive
BRN 1280132
CAS DataBase Reference 7252-83-7(CAS DataBase Reference)
FDA UNII 7BKM28RJ5D
NIST Chemistry Reference Ethane, 2-bromo-1,1-dimethoxy-(7252-83-7)
EPA Substance Registry System Ethane, 2-bromo-1,1-dimethoxy- (7252-83-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H315-H319
Precautionary statements  P210-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  10-36-36/37/38
Safety Statements  26-36/39-28A-16
RIDADR  UN 1989 3/PG 3
WGK Germany  3
8-9-21
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29110000
NFPA 704
2
3 1

Bromoacetaldehyde dimethyl acetal price More Price(33)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 242500 2-Bromo-1,1-dimethoxyethane 97% 7252-83-7 25g $65.7 2024-03-01 Buy
Sigma-Aldrich 242500 2-Bromo-1,1-dimethoxyethane 97% 7252-83-7 100g $250 2024-03-01 Buy
TCI Chemical B1097 Bromoacetaldehyde Dimethyl Acetal (stabilized with K2CO3) >97.0%(GC) 7252-83-7 25g $36 2024-03-01 Buy
TCI Chemical B1097 Bromoacetaldehyde Dimethyl Acetal (stabilized with K2CO3) >97.0%(GC) 7252-83-7 100g $102 2024-03-01 Buy
Alfa Aesar A11324 Bromoacetaldehyde dimethyl acetal, 97+%, stab. with potassium carbonate 7252-83-7 25g $27.65 2024-03-01 Buy
Product number Packaging Price Buy
242500 25g $65.7 Buy
242500 100g $250 Buy
B1097 25g $36 Buy
B1097 100g $102 Buy
A11324 25g $27.65 Buy

Bromoacetaldehyde dimethyl acetal Chemical Properties,Uses,Production

Description

2-Bromo-1,1-dimethoxyethane (Bromoacetaldehyde dimethyl acetal) is used in the synthesis of 2,3-O-acetal via reaction with 2,3-diol in the presence of 10-camphorsulphonic acid (CSA). 2-bromo-1,1-dimethoxyethane was used to react with 4-hydroxylbenzaldehyde, and finally aldehyde substituted prodrug was generated by TFA-mediated deacetalization. It is widely used in chemistry for the synthesis of a variety of antibiotics (including erythromycin and cephalosporins) and other drugs. It is an important and highly reactive bifunctional compound with a good leaving group and a masked aldehyde function. It can be used as a starting material in a variety of reactions to provide N-alkylated compounds, lactams, aldehydes, oximes, azides, and acyclic di-/polyselenides.

Reference

Gotkowska, Joanna. "Bromoacetaldehyde Diethyl Acetal." Synlett26.15(2015):2185-2186.

Chemical Properties

clear colourless to light yellow liquid

Uses

2-Bromo-1,1-dimethoxyethane (Bromoacetaldehyde dimethyl acetal) was used in the synthesis of 2,3-O-acetal via reaction with 2,3-diol in the presence of 10-camphorsulphonic acid (CSA).

Uses

2-Bromo-1,1-dimethoxyethane (Bromoacetaldehyde dimethyl acetal) was used in the synthesis of 2,3-O-acetal via reaction with 2,3-diol in the presence of 10-camphorsulphonic acid (CSA). 2-bromo-1,1-dimethoxyethane was used to react with 4-hydroxylbenzaldehyde, and finally aldehyde substituted prodrug was generated by TFA-mediated deacetalization.

67-56-1
17157-48-1
7252-83-7
Synthesis of Bromoacetaldehyde dimethyl acetal from Methanol and Bromoacetaldehyde
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View Lastest Price from Bromoacetaldehyde dimethyl acetal manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bromoacetaldehyde dimethyl acetal pictures 2023-09-06 Bromoacetaldehyde dimethyl acetal
7252-83-7
US $0.00-0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
Bromoacetaldehyde dimethyl acetal pictures 2023-07-26 Bromoacetaldehyde dimethyl acetal
7252-83-7
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Bromoacetaldehyde dimethyl acetal pictures 2023-06-26 Bromoacetaldehyde dimethyl acetal
7252-83-7
US $0.00 / kg 1kg 99% 20tons Zouping mingyuan import & export trading co., ltd
Ethane,2-broMo-1,1-diMethoxy- 2-BroMo-1,1-diMethoxyethane, 98%+ 2-Bromo-1,1-dimethoxyethane 2,2-Dimethoxyethyl Bromide 2 - broMine - 1, 1 - diMethoxy ethane BROMOACETALDEHYDE DIMETHYL ACETAL (BADA) Bromoacetaldehyde dimethyl acetal, 97+%, stab. with potassium carbonate Bromoacetaldehyde Dimethyl Acetal (stabilized with K2CO3) Bromoacetoaldehyde dimethyl acetal ,98% 1,1-Dimethoxy-2-bromoethane Bromoacetaldehyde dimethyl acetal,97%,stabilized BROMOACETALDEHYDE METHYL ACETAL Bromoacetoaldehyde dimethyl acetal 2-Brom-1,1-dimethoxyethan 1-Bromo-2,2-dimethoxyethane 2,2-Dimethoxybromoethane 2-bromo-1,1-dimethoxy-ethan 2-Bromoacetaldehyde dimethyl acetal Acetaldehyde, bromo-, dimethyl acetal BADMA BROMOACETALDEHYDE DIMETHYL ACETAL 2,2-DIMETHOXYETHYL BROMIDE BROMOACETALDEHYDE DIMETHYL ACETAL, STAB. BROMOACETALDEHYDE DIETHYL ACETAL(2-BROMIDE-1,1-DIETHOXYETHANE) 2-BROMO-1,1-DIMETHYOXYERHANE BromoacetaldehydeDimethylacetal(Stabilized)97% 2-BROMO-1,1-DIMETHYLETHANE Bromoacetaldehyde dimethyl acetal, stabilized, 97% BROMOACETALDEHYDE DIMETHYL ACETAL , STABILIZED WITH POTASSIUM CARBONATE Bromoacetaldehyde dimethyl acetal,stab. with potassium carbonate Bromoacetaldehyde Dimethyl Acetal (stabilized with K2CO3) > romoacetaldehyde dimethyl acetal Bromoacetaldehyde dimethyl acetala TIANFU-CHEM CAS:7252-83-7 Bromoacetaldehyde dimethyl acetal Bromoacetaldehyde Dimethyl Acetal pure (Stabilized), 97% Dimethylbromoacetal BADA 2-BROMO-1,1-DIMETHOXYETHANE Inosine Impurity 17 Monomer 7252-83-7 C4H9O2Br BrCH2CHOCH32 C4H9BrO2 ALDEHYDE Building Blocks Organic Building Blocks Acetals/Ketals/Ortho Esters Oxygen Compounds Aromatic Aldehydes & Derivatives (substituted) Other Products Pharmaceutical Intermediates bc0001 7252-83-7