푸란-2-카르복실산

푸란-2-카르복실산
푸란-2-카르복실산 구조식 이미지
카스 번호:
88-14-2
한글명:
푸란-2-카르복실산
동의어(한글):
2-푸로산;푸란-2-카르복실산
상품명:
2-Furoic acid
동의어(영문):
Furan-2-carboxylic acid;2-Furancarboxylic acid;FURAN-2-CARBONYL CHLORIDE;Furoica;FUROYL CHLORIDE;2-furancarboxylate;2-Furancarbosylicacid;2-FURANCARBONYL CHLORIDE;2-Furoic;Furoic aci
CBNumber:
CB2189363
분자식:
C5H4O3
포뮬러 무게:
112.08
MOL 파일:
88-14-2.mol
MSDS 파일:
SDS

푸란-2-카르복실산 속성

녹는점
−2 °C(lit.)
끓는 점
173-174 °C(lit.)
밀도
1.324 g/mL at 25 °C(lit.)
증기압
13.732Pa at 25℃
굴절률
n20/D 1.531(lit.)
인화점
185 °F
저장 조건
Keep in dark place,Sealed in dry,Room Temperature
용해도
37g/L
물리적 상태
미세 결정성 분말
산도 계수 (pKa)
3.16(at 25℃)
색상
미색부터 베이지까지
냄새
냄새 없는
?? ??
냄새 없는
수용성
36g/L(20℃)
Merck
14,4307
BRN
110149
InChIKey
SMNDYUVBFMFKNZ-UHFFFAOYSA-N
LogP
0.628 at 25℃
CAS 데이터베이스
88-14-2(CAS DataBase Reference)
NIST
2-Furancarboxylic acid(88-14-2)
EPA
2-Furancarboxylic acid (88-14-2)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C,Xi
위험 카페고리 넘버 34-36/37/38
안전지침서 26-36/37/39-45-36-37/39
유엔번호(UN No.) UN 3265 8/PG 2
WGK 독일 3
RTECS 번호 LV1763000
F 고인화성물질 10-19-21
TSCA Yes
HS 번호 29321900
그림문자(GHS): GHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
예방조치문구:
P260 분진·흄·가스·미스트·증기·...·스프레이를 흡입하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P330+P331 삼켰다면 입을 씻어내시오. 토하게 하려 하지 마시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
0
2 0

푸란-2-카르복실산 MSDS


2-Furancarboxylic acid

푸란-2-카르복실산 C화학적 특성, 용도, 생산

개요

2-Furoic acid is an organic compound, consisting of a furan ring and a carboxylic acid side-group. Along with other furans, its name is derived from the Latin word furfur, meaning bran, from which these compounds were first produced. The salts and esters of furoic acids are known as furoates. 2-Furoic acid is most widely encountered in food products as a preservative and a flavouring agent, where it imparts a sweet, earthy flavour.

화학적 성질

white to light yellow crystal powder. 1g is dissolved in 26ml cold water or 4ml boiling water, easily soluble in ethanol and ether. Sublimation at 130-140°C (6.65-8kPa).

용도

2-Furoic acid is an heterocyclic carboxylic acid that is widely used in food products as a preservative and flavouring agent. It is also used in the synthesis of methylfuran, furoamide and furoic acid esters and salts. In the plastics industry, it can be used as plasticizer, thermosetting resin, etc. substitute for chloropicrin in disinfecting grain elevators.

주요 응용

2-Furoic acid (FA) is a preservative, acting as a bactericide and fungicide. Some of the applications of 2-furoic acid include:
Synthesis of a single-molecule magnet, Mn11Gd2 based high-nuclearity heterometallic complex.
Synthesis of orally active antidiabetic vanadyl complex, bis(α-furancarboxylato)oxovanadium(IV).
As a ligand in the synthesis of luminescent 4f-3d heterometallic one-dimensional coordination polymers.
Synthesis of biocompatible multifunctional dextran furoate nanospheres.
FA is often used as a starting material for the production of furoate esters.
FA and its derivatives are also used in the production of nylons principally applied in biomedical researches.

정의

ChEBI: 2-furoic acid is a furoic acid having the carboxylic acid group located at position 2. It has a role as an inhibitor, a human xenobiotic metabolite, a Saccharomyces cerevisiae metabolite, a plant metabolite and a bacterial xenobiotic metabolite. It is a conjugate acid of a 2-furoate.

제조 방법

2-furoic acid can be synthesized by the oxidation of furfural. The reaction was carried out at 45°C with vigorous stirring. The reactant is filtered to recover the catalyst copper oxide, the filtrate is acidified with 50% sulfuric acid to pH 3-2.5, suction filtered, washed with water, and dried to obtain 2-furoic acid.

위험도

Strong irritant to eyes and skin.

Purification Methods

Crystallise the acid from hot water (charcoal), dry it at 120o for 2hours, then recrystallise it from CHCl3, and again dry it at 120o for 2hours. For use as a standard in volumetric analysis, good quality commercial acid should be crystallised from CHCl3 and dried as above or sublimed at 130-140o/50-60mm or less. [Beilstein 18 I 438, 18 II 265, 18 III/IV 3914, 18/6 V 102.]

푸란-2-카르복실산 준비 용품 및 원자재

원자재

준비 용품


푸란-2-카르복실산 공급 업체

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