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카벤다짐

카벤다짐
카벤다짐 구조식 이미지
카스 번호:
10605-21-7
한글명:
카벤다짐
동의어(한글):
카벤다딘;메틸-N-(2-벤즈이미다조릴)카바메이트;카벤다짐;프리벤톨BCM;카벤다짐(CARBENDAZIM);카르벤다짐
상품명:
Carbendazim
동의어(영문):
MBC;BCM;bmk;a118;g665;MBCA;myco;spin;ek578;stein
CBNumber:
CB5416930
분자식:
C9H9N3O2
포뮬러 무게:
191.19
MOL 파일:
10605-21-7.mol

카벤다짐 속성

녹는점
>300 °C(lit.)
끓는 점
326.92°C (rough estimate)
밀도
1.4500
증기압
1.5 x 10-4 Pa (25 °C)
굴절률
1.6500 (estimate)
인화점
11 °C
저장 조건
APPROX 4°C
용해도
pyridine: soluble1%, clear, very faintly brownish-yellow
물리적 상태
neat
산도 계수 (pKa)
4.48(at 25℃)
수용성
<0.1 g/100 mL at 21 ºC
Merck
13,1799
BRN
649044
InChIKey
TWFZGCMQGLPBSX-UHFFFAOYSA-N
CAS 데이터베이스
10605-21-7(CAS DataBase Reference)
EPA
Carbendazim (10605-21-7)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N,F,Xn
위험 카페고리 넘버 46-60-61-50/53-39/23/24/25-23/24/25-11-52/53
안전지침서 53-45-60-61-36/37-16
유엔번호(UN No.) UN 3077 9/PG 3
WGK 독일 3
RTECS 번호 DD6500000
HS 번호 29339900
유해 물질 데이터 10605-21-7(Hazardous Substances Data)
독성 LD50 oral in rabbit: 8160mg/kg
그림문자(GHS):
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H340 유전적인 결함을 일으킬 수 있음 (노출되어도 생식세포 유전독성을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 생식세포 변이원성 물질 구분 1A, 1B 위험
H360 태아 또는 생식능력에 손상을 일으킬 수 있음 생식독성 물질 구분 1A, 1B 위험
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 P273, P391, P501
예방조치문구:
P201 사용 전 취급 설명서를 확보하시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P308+P313 노출 또는 접촉이 우려되면 의학적인 조치· 조언를 구하시오.
P501 ...에 내용물 / 용기를 폐기 하시오.

카벤다짐 MSDS


1H-Benzimidazole-2-carbamic acid methyl ester

카벤다짐 C화학적 특성, 용도, 생산

화학적 성질

White Solid

화학적 성질

Colorless crystalline solid or light-gray powder. Commercially supplied as dry concentrate that is mixed with water for spraying.

용도

Is a fungicide.

용도

Carbendazim is the most widely used active ingredient in the benzimidazole class of fungicides. It is a systemic fungicide with both protective and curative activities against a wide range of fungal diseases, especially caused by most Ascomycetes spp. and some Basidiomycetes and Deuteromycetes spp. in a wide variety of crop and ornamental uses.

용도

Fungicide.

정의

ChEBI: A member of the class of benzimidazoles that is 2-aminobenzimidazole in which the primary amino group is substituted by a methoxycarbonyl group. A fungicide, carbendazim controls Ascomycetes, Fungi Imperfecti, and Basidiomy etes on a wide variety of crops, including bananas, cereals, cotton, fruits, grapes, mushrooms, ornamentals, peanuts, sugarbeet, soybeans, tobacco, and vegetables.

일반 설명

Light gray or beige powder.

공기와 물의 반응

Insoluble in water. Carbendazim slowly decomposes in alkaline solution. .

반응 프로필

Carbendazim is a carbamate ester-amine. Amines behave as chemical bases. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

건강위험

ACUTE/CHRONIC HAZARDS: When heated to decomposition Carbendazim emits toxic fumes of NOx.

화재위험

Literature sources indicate that Carbendazim is probably nonflammable.

농업용

Fungicide: Carbendazim is a systemic fungicide used as a drench to control a broad range of fungi in cereals, vegetables, oilseed rape, sugar beets, grapes, tomatoes, pome fruit and stone fruit. It is also used in post-harvest storage and as treatment in seed pre-planting, frequently in combination with other fungicides. In some areas, it has been used to combat Dutch elm disease.

상품명

ABACOL®; AIMCOZIM; BAS® 3460; BAS® 67054; BATTAL®; BAVISTIN®; BENDAZIM®; CARBATE®; CARBENDAZIME®; CARBENDAZOL®; CARBENDAZOLE®; CARBENDAZYM®; CARBENDOR; CEKUDAZIM®; CORBEL; CTR® 6669; CUSTOS®; DEFENSOR®; DELSENE®; DEROSAL®; E-965®; DERROPRENE®; EQUITDAZIN®; FUNGISOL®; HOE 17411®; LIGNASAN®; IMISOL®; KEMDAZIN®; MERGAL®; PILLARSTIN®; POLYPHASE®; RODAZIM®; STEMPOR®; SUPERCARB, TRITICOL®; TRITICOL®; U-32.104®

Safety Profile

Moderately toxic by skin contact. Mildly toxic by ingestion. An experimental teratogen. Experimental reproductive effects. Human mutation data reported. An agricultural chemical and pesticide. When heated to decomposition it emits toxic fumes of NOx. See also CARBAMATES.

잠재적 노출

Carbendazim is a benzimidazole/carbamate systemic fungicide used as a drench to control a broad range of fungi in cereals, vegetables, oilseed rape, sugar beets, grapes, tomatoes, pome fruit, and stone fruit. It is also used in postharvest storage and as treatment in seed preplanting, frequently in combination with other fungicides. In some areas, it has been used to combat Dutch Elm disease.

신진 대사 경로

When the mites are exposed to 14C-carbendazim, the major carbendazim metabolite identified in the bulb mites is 5-hydroxy-2-aminobenzimidazole. Low levels of 2-aminobenzimidazole and 5-hydroxy-2- benzimidazole carbamate are also identified.

운송 방법

UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required

Degradation

Carbendazim (MBC, 1) was stable in acidic and neutral solutions (pH 5-7, DT50≥57 days at 22°C), but decomposed rapidly with a DT50 of 22 days (WHO, 1993b) to yield 2-aminobenzimidazole (2, Watluns, 1976; Zbozinek, 1984) under alkaline conditions (pH 9). An increase in the salinity of the water accelerated the degradation rate of MBC in water (Deshpande and Patil, 1987).
Photolysis of MBC in natural sunlight is not a significant dissipation mechanism in the environment. Significant degradation did not occur either on leaf surfaces exposed to natural sunlight or in unamended dilute aqueous solution. Degradation occurred in solution under natural sunlight if photoinitiators such as riboflavin or acetone were present (Fleeker and Lacy, 1977).

비 호환성

Carbamates are incompatible with reducing agents, strong acids, oxidizing acids, peroxides, and bases. Contact with active metals or nitrides cause the release of flammable, and potentially explosive, hydrogen gas.

폐기물 처리

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

카벤다짐 준비 용품 및 원자재

원자재

준비 용품


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