ChemicalBook >제품 카탈로그 >유기 화학>탄화수소 및 유도체>할로겐화 탄화수소>p-클로로톨루엔

p-클로로톨루엔

p-클로로톨루엔 구조식 이미지

카스 번호:: 106-43-4

한글명:: p-클로로톨루엔

동의어(한글):: 4-클로로톨루엔;p-클로로톨루엔

상품명:: 4-Chlorotoluene

동의어(영문):: 1-CHLORO-4-METHYLBENZENE;P-CHLOROTOLUENE;chlorotoluenes;1-chloro-4-methyl-benzen;4-CHLORO-1-METHYLBENZENE;UPD;p-ChL;p-Chlortoluol;4-Chlortoluol;4-Chlorotoluen

CBNumber:: CB9852675

분자식:: C7H7Cl

포뮬러 무게:: 126.58

MOL 파일:: 106-43-4.mol

MSDS 파일:: SDS

속성

안전

MSDS

용도

공급 업체 381

p-클로로톨루엔 속성

녹는점: 6-8 °C(lit.)

끓는 점: 162 °C(lit.)

밀도: 1.07 g/mL at 25 °C(lit.)

증기 밀도: 4.38 (vs air)

증기압: 10 mm Hg ( 45 °C)

굴절률: n20/D 1.52(lit.)

인화점: 121 °F

저장 조건: 2-8°C

용해도: 0.040g/L

물리적 상태: 액체

색상: 투명한

수소이온지수(pH): 7.4 (H2O)(saturated aqueous solution)

폭발한계: 0.7-12.2%(V)

수용성: 20°C에서 <0.1g/100mL

Merck: 14,2171

BRN: 1903635

Dielectric constant: 6.0800000000000001

안정성: 안정적인. 타기 쉬운. 강한 산화제와 호환되지 않습니다.

LogP: 3.33 at 20℃

CAS 데이터베이스: 106-43-4(CAS DataBase Reference)

NIST: Benzene, 1-chloro-4-methyl-(106-43-4)

EPA: p-Chlorotoluene (106-43-4)

안전

위험 및 안전 성명
위험 및 사전주의 사항 (GHS)

위험품 표기	Xn,N,T,F
위험 카페고리 넘버	20-51/53-39/23/24/25-23/24/25-11-10-43
안전지침서	24/25-61-45-36/37-16-7
유엔번호(UN No.)	UN 2238 3/PG 3
WGK 독일	2
RTECS 번호	XS9010000
위험 참고 사항	Harmful
TSCA	Yes
위험 등급	3
포장분류	III
HS 번호	29036990
HS 번호	29337900
유해 물질 데이터	106-43-4(Hazardous Substances Data)
기존화학 물질	KE-05730

그림문자(GHS):

신호 어:

Warning

유해·위험 문구:

암호	유해·위험 문구	위험 등급	범주	신호 어	P- 코드
H226	인화성 액체 및 증기	인화성 액체	구분 3	경고
H317	알레르기성 피부 반응을 일으킬 수 있음	피부 과민성 물질	구분 1	경고	P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H332	흡입하면 유해함	급성 독성 물질 흡입	구분 4	경고	P261, P271, P304+P340, P312
H411	장기적 영향에 의해 수생생물에 유독함	수생 환경유해성 물질 - 만성	구분 2

예방조치문구:

P210	열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P233	용기를 단단히 밀폐하시오. 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 보관하시오.
P273	환경으로 배출하지 마시오.
P280	보호장갑/보호의/보안경/안면보호구를 착용하시오.
P303+P361+P353	피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.

NFPA 704

	2
2		0

p-클로로톨루엔 MSDS

4-Chlorotoluene

p-클로로톨루엔 C화학적 특성, 용도, 생산

화학적 성질

Colorless oily liquid. Slightly soluble in water. Soluble in ethanol, ether, acetone, benzene and chloroform.

용도

4-Chlorotoluene is used in a variety of organic synthesis, such as acting as coupling precursors for palladium-catalyzed acylation of acetanilides. It is also used for the preparation model gas of 4-chlorotoulene by passing synthesized air into liquid 4-chlorotoulene.

주요 응용

4-chlorotoluene is used as a solvent and intermediate for dyes and other organic chemicals. It is used mainly to produce p-chlorobenzotrichloride, from whichis obtained p-chlorobenzotrifluoride, an important precursor of herbicides (e.g., trifluralin:α,α,α,-trifluoro-2,6-dinitro-N,Ndipropyl-p-toluidine). Other side-chain-chlorinated products or their derivatives are 4- chlorobenzyl chloride (for pharmaceuticals, rice herbicides, and pyrethrin insecticides), 4- chlorobenzaldehyde (for dyes and pharmaceuticals), 4-chlorobenzoyl chloride (for pharmaceuticals and peroxides), and 4-chlorobenzoic acid (for dyes). 4-Chlorotoluene is also a starting material in the synthesis of 2,4- and 3,4-dichlorotoluene and of 4-chlorobenzonitrile. [ChemicalBook]

정의

ChEBI: 4-Chlorotoluene is a member of monochlorobenzenes. It is an intermediate for the manufacture of Fenvalerate, Paclobutrazol, Uniconazole, Trifluralin,Thiobencarb, Daimuron and other pesticides.

제조 방법

4-Chlorotoluene is obtained from p-toluidine by diazotization and substitution. Add p-toluidine and hydrochloric acid to the reaction pot and stir and heat until dissolved at 60℃, then cool to below 15℃ and add sodium nitrite solution dropwise. After reaching the end point, continue to stir for 0.5h. Add cuprous chloride hydrochloric acid solution and stir at room temperature for 3h. Then raise the temperature to 60℃ and keep for 0.5h, cool to room temperature and leave to stratify, discard the acid water layer, wash with water to neutral, filter and get p-chlorotoluene.

일반 설명

The reaction of 4-chlorotouleneand phenylboronic acid with Pd(OAc)2/L?2HX as the catalyst is the model reaction for determining the efficiencies of bisimidazolylidene (L) ligand precursors.

위험도

Avoid inhalation; strong irritant.

Safety Profile

Moderately toxic by ingestion. Mdly toxic by inhalation. Flammable when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Cl-. See also TOLYL CHLORIDE and CHLORINATED HYDROCARBONS, AROMATIC.

Purification Methods

Dry it with BaO, fractionally distil it, then fractionally crystallise it by partial freezing. [Beilstein 5 IV 806.]

p-클로로톨루엔 준비 용품 및 원자재

원자재

톨루엔 염소(기체) Industrial hydrochloric acid 염화제이철무수물 염화구리(Ⅰ) 황산동(II) Monochlorotoluene p-톨루이딘 o-클로로톨루엔 산성아황산나트륨

준비 용품

1-[2-(4-CHLOROPHENYL)-1-(1-HYDROXY-1-PHENYLETHYL)ETHYL]-1,2,4-TRIAZOLE o-클로로벤조트리클로라이드 p-클로로벤조트리클로라이드 p-클로로벤즈알데히드 2,4-Dichlorobenzotrifluoride 2,4-디클로로톨루엔 p-클로로벤질 시아나이드 2-(4-Chlorophenyl)-3-methylbutyric acid 디클로로벤조트리플로라이드 시플루트린 FLUORODIFEN P-클로로 안식향산 2-메톡시-5-메틸아닐린 플루오르벤젠알데히드 5-chloro-2-methylbenzenediazonium brofenvalerate 4-chloro-1-(dichloromethyl)benzene P-클로로벤질클로라이드 포메사펜 4-Fluoro-3-phenoxybenzaldehyde p-클로로벤조트리플루오라이드

p-클로로톨루엔 공급 업체

글로벌( 381)공급 업체

공급자	전화	이메일	국가	제품 수	이점
Shanghai Xin Cheng Yue Chemical Co.,Ltd	+86-021-57806787 +86-17701820076	wuziwei@xinyuefirm.com	China	30	58
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	5993	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7845	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1807	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	+86 18953170293	sales@sdzschem.com	China	2931	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Jinan Finer Chemical Co., Ltd	+86-531-88989536 +86-15508631887	sales@finerchem.com	China	2967	58