핵산산

핵산산
핵산산 구조식 이미지
카스 번호:
142-62-1
한글명:
핵산산
동의어(한글):
n-카프론산;카프로인산;핵산산;카프로산;카프론산;헥산오익산;부틸아세틱산;N-헥산오익산;펜티포름산;부틸아세트산;카프로익애씨드
상품명:
Hexanoic acid
동의어(영문):
CAPROIC ACID;C6;N-CAPROIC ACID;N-HEXANOIC ACID;1-Hexanoic acid;N-CAPROATE;Natural Caproic Acid;CAPROIC ACID, NATURAL;Hexanoic Acid 〔n-Caproic Acid〕;NA-1706
CBNumber:
CB3224164
분자식:
C6H12O2
포뮬러 무게:
116.16
MOL 파일:
142-62-1.mol
MSDS 파일:
SDS

핵산산 속성

녹는점
-4 °C (lit.)
끓는 점
202-203 °C (lit.)
밀도
0.927 g/mL at 25 °C (lit.)
증기 밀도
4 (vs air)
증기압
0.18 mm Hg ( 20 °C)
FEMA
2559 | HEXANOIC ACID
굴절률
n20/D 1.4161(lit.)
인화점
220 °F
저장 조건
Store below +30°C.
용해도
물: 약간 녹는다1.082g/100g(lit.)
물리적 상태
액체
산도 계수 (pKa)
4.85(at 25℃)
Specific Gravity
0.929 (20/4℃)
색상
무색투명~연황색
수소이온지수(pH)
3.95(1 mM solution);3.43(10 mM solution);2.93(100 mM solution);
냄새
프로필렌 글리콜 중 10.00%. 신 지방 땀 치즈
?? ??
지방이 많은
Odor Threshold
0.0006ppm
수용성
1.1g/100mL(20℃)
Merck
14,1759
JECFA Number
93
BRN
773837
Dielectric constant
2.6(71℃)
안정성
안정적인. 염기, 환원제 및 산화제와 호환되지 않습니다. 가연성.
InChIKey
FUZZWVXGSFPDMH-UHFFFAOYSA-N
LogP
1.92 at 25℃
CAS 데이터베이스
142-62-1(CAS DataBase Reference)
NIST
Hexanoic acid(142-62-1)
EPA
Hexanoic acid (142-62-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 C,Xi
위험 카페고리 넘버 34-21-20/21/22
안전지침서 26-36/37/39-45-25
유엔번호(UN No.) UN 2829 8/PG 3
WGK 독일 1
RTECS 번호 MO5250000
F 고인화성물질 13
자연 발화 온도 380 °C
위험 참고 사항 Irritant
TSCA Yes
위험 등급 8
포장분류 III
HS 번호 29159000
유해 물질 데이터 142-62-1(Hazardous Substances Data)
독성 LD50 orally in rats: 3.0 g/kg (Smyth, Carpenter)
기존화학 물질 KE-19797
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H302 삼키면 유해함 급성 독성 물질 - 경구 구분 4 경고 GHS hazard pictograms P264, P270, P301+P312, P330, P501
H311 피부와 접촉하면 유독함 급성 독성 물질 - 경피 구분 3 위험 GHS hazard pictograms P280, P302+P352, P312, P322, P361,P363, P405, P501
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
예방조치문구:
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P301+P312 삼켜서 불편함을 느끼면 의료기관(의사)의 진찰을 받으시오.
P303+P361+P353 피부(또는 머리카락)에 묻으면 오염된 모든 의복은 벗거나 제거하시오 피부를 물로 씻으시오/샤워하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
1
3 0

핵산산 C화학적 특성, 용도, 생산

개요

Hexanoic acid (also known as Caproci acid), is the carboxylic acid derived from hexane with the general formula C5H11COOH. It is a colorless oily liquid with an odor that is fatty, cheesy, waxy, and like that of goats or other barnyard animals. It is a fatty acid found naturally in various animal fats and oils, and is one of the chemicals that give the decomposing fleshy seed coat of the ginkgo its characteristic unpleasant odor. The primary use of hexanoic acid is in the manufacture of its esters for artificial flavors, and in the manufacture of hexyl derivatives, such as hexylphenols. Hexanoic acid belongs to medium chain triglycerides (MCT) that are widely used as a nutrition supplement that added to foods, drugs and cosmetics.

화학적 성질

Hexanoic acid is a colourless liquid that has a sickening, sweaty, rancid, sour, sharp, pungent, cheesy, fatty, unpleasant odor reminiscent of copra oil. It exhibits an acrid taste. Hexanoic acid may be prepared by fractionation of the volatile fatty acids of coconut oil.

물리적 성질

Hexanoic acid is oily, colorless or slightly yellow, and liquid at room temperature. Odor is that of Limburger cheese. Soluble in alcohol and ether; slightly soluble in water. It is derived from the crude fermentation of butyric acid; or by fractional distillation of natural fatty acids.

출처

Hexanoic acid is found in many foods, some of which are tapioca pearl, meat bouillon, pecan nut, and oval-leaf huckleberry. A secondary product of butyric fermentation; reported found in the essential oils of lavender, camphor, palmarosa, lemongrass and Juniperus phoenicea; in a few fruital aromas: apple, currant and strawberry; also identified among the constituents of petitgrain lime oil.

용도

Hexanoic acid is used to prepare esters by reacting with alcohols, which finds application in artificial flavors. It is also involved in the production of hexylphenols, hexanoates and caproates. Further, it is used as non-viral gene carrier as well as to protect tomato plants from Botrytis cinerea.

정의

ChEBI: Hexanoic acid is a C6, straight-chain saturated fatty acid. It has a role as a human metabolite and a plant metabolite. It is a straight-chain saturated fatty acid and a medium-chain fatty acid. It is a conjugate acid of a hexanoate.

제조 방법

hexanoic acid is produced by fractionation of the volatile fatty acids of coconut oil.

일반 설명

Hexanoic acid is an oily carboxylic acid found (as glycerides) in cow’s milk and some vegetable oils. It is a white crystalline solid or colorless to light yellow solution with an unpleasant odor. Insoluble to slightly soluble in water and less dense than water. Contact may severely irritate skin, eyes and mucous membranes. May be toxic by ingestion, inhalation and skin absorption. Used to make perfumes.

공기와 물의 반응

Slightly water soluble.

위험도

Strong irritant to tissue.

건강위험

Harmful if swallowed, inhaled, or absorbed through skin. Material is extremely destructive to tissue of mucous membranes and upper respiratory tract, eyes and skin. Inhalation may be fatal as a result of spasm, inflammation and edema of the larynx and bronchia, chemical pneumonitis and pulmonary edema. Symptoms of exposure may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea and vomiting.

화재위험

Special Hazards of Combustion Products: Irritating vapor may be generated.

Purification Methods

Dry the acid with MgSO4 and fractionally distil it from CaSO4. [Beilstein 2 IV 917.]

핵산산 준비 용품 및 원자재

원자재

준비 용품


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