디이소부틸케톤
|
|
디이소부틸케톤 속성
- 녹는점
- -46 °C
- 끓는 점
- 165-170 °C(lit.)
- 밀도
- 0.808 g/mL at 25 °C(lit.)
- 증기 밀도
- 4.9 (vs air)
- 증기압
- 1.7 mm Hg ( 20 °C)
- 굴절률
- n
20/D 1.412(lit.)
- 인화점
- 120 °F
- 저장 조건
- Store below +30°C.
- 용해도
- 에탄올, 에테르, 사염화탄소, 에 용해됨클로로포름, 벤젠 및 대부분의 유기 액체와 혼합 가능합니다.
- 물리적 상태
- 액체
- Specific Gravity
- 0.810 (20/4℃)
- 색상
- 무색투명~미황색
- 냄새
- 경증; 특징적인 케톤.
- ?? ??
- 녹색
- 폭발한계
- 0.8-6.2%, 100°F
- 수용성
- 0.05g/100mL
- JECFA Number
- 302
- BRN
- 1743163
- Henry's Law Constant
- 6.36(x 10-4 atm?m3/mol) at 20 °C (approximate - calculated from water solubility and vapor pressure)
- 노출 한도
- TLV-TWA 150 mg/m3 (25 ppm); IDLH 1000 ppm.
- Dielectric constant
- 9.9100000000000001
- 안정성
- 안정적인. 가연성. 강한 산화제와 호환되지 않습니다.
- LogP
- 3.71 at 20℃
- CAS 데이터베이스
- 108-83-8(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xi | ||
---|---|---|---|
위험 카페고리 넘버 | 10-37 | ||
안전지침서 | 24 | ||
유엔번호(UN No.) | UN 1157 3/PG 3 | ||
OEB | A | ||
OEL | TWA: 25 ppm (150 mg/m3) | ||
WGK 독일 | 1 | ||
RTECS 번호 | MJ5775000 | ||
자연 발화 온도 | 745 °F | ||
TSCA | Yes | ||
위험 등급 | 3 | ||
포장분류 | III | ||
HS 번호 | 29141990 | ||
유해 물질 데이터 | 108-83-8(Hazardous Substances Data) | ||
독성 | LD50 orally in Rabbit: 5750 mg/kg LD50 dermal Rabbit 16000 mg/kg | ||
IDLA | 500 ppm | ||
기존화학 물질 | KE-10907 |
디이소부틸케톤 C화학적 특성, 용도, 생산
용도
도료 및 도료 용 용제, 제약, 농약, 니트로 셀룰로오스 화합물, 수지, 잉크 및 접착제; 의약품 제조에서 유기 화합물의 재결정 화 촉매.포장, 보관 및 운송
환기가 잘되는 곳에 보관하십시오. 용기를 단단히 밀폐하십시오.개요
2, 6-Dimethyl-4-heptanone, also known as diisobutyl ketone, belongs to the family of ketones, being a flavoring ingredient. It can also be used as the extraction solvent for the determination of ten trace metals (V, Cr, Fe, Co, Ni, Cu, Zn, Mo, Cd, Pb) in aqueous samples with plasma atomic emission spectrometry. Similar logic can also be applied to the measurement of phosphorus using 2, 6-dimethyl-4-heptanone as the extraction agent. It is also an important organic solvent widely used as industrial intermediates.화학적 성질
5-Methyl-3-heptanone is a colorless liquid with low solubility in water (0.3 wt %); water is poorly soluble in the ketone (0.9 wt %). 5-Methyl-3-heptanone is highly soluble in common organic solvents.물리적 성질
Clear, colorless liquid with a mild, sweet, ether-like odor. Odor threshold concentration is 0.11 ppm (quoted, Amoore and Hautala, 1983).출처
Reported found in baked potato and wheaten bread.용도
2,6-Dimethyl-4-heptanone is used as a coating solvent. It is an active component of mint oil. It acts as a dispersant for organosol type resins. It is involved in the antigerminative treatment of bulbs and tubers. Further, it is used as a solvent for nitrocellulose. In addition to this, it acts as an intermediate in the preparation of inhibitors, active pharmaceutical ingredients and dyes.생산 방법
Diisobutyl ketone is produced by hydrogenation of phorone or by metal-catalyzed decomposition of isovaleric acid.It is also a by-product in the manufacture of methyl isobutyl ketone.일반 설명
A clear colorless liquid. Flash point 140°F. Less dense than water and insoluble in water. Vapors heavier than air.공기와 물의 반응
Flammable. Insoluble in water.반응 프로필
2,6-Dimethyl-4-heptanone may attack some plastics. 2,6-Dimethyl-4-heptanone reacts with oxidizers.건강위험
Inhalation of vapor causes irritation of nose and throat. Ingestion causes irritation of mouth and stomach. Vaporirritates eyes. Contact with liquid irritates skin.화학 반응
Reactivity with Water No reaction; Reactivity with Common Materials: May attack some forms of plastics; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.Safety Profile
Moderately toxic by ingestion and inhalation. Mddly toxic by skin contact. Human systemic effects by inhalation: headache, nausea or vomiting, and unspecified eye effects. An eye and skin irritant. Narcotic in high concentrations. Flammable liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use Con, dry chemical, water spray, mist or fog. When heated to decomposition it emits acrid smoke and fumes. See also KETONES.환경귀착
Biological. Using the BOD technique to measure biodegradation, the mean 5-d BOD value (mM BOD/mM diisobutyl ketone) and ThOD were 4.86 and 37.4%, respectively (Vaishnav et al., 1987).Chemical/Physical. Diisobutyl ketone will not hydrolyze because it has no hydrolyzable functional group.
At an influent concentration of 300 mg/L, treatment with GAC resulted in nondetectable concentrations in the effluent. The adsorbability of the carbon used was 60 mg/g carbon (Guisti et al., 1974).
폐기물 처리
Incineration, molten metal salt destruction.참고 문헌
Bone, K. M., and W. D. Hibbert. "Solvent extraction with ammonium pyrrolidinedithiocarbamate and 2,6-dimethyl-4-heptanone for the determination of trace metals in effluents and natural waters." Analytica Chimica Acta 107.JUN(1979):219-229.Miyazaki, Akira, A. Kimura, and Y. Umezaki. "Determination of ng ml-1 levels of phosphorus in waters by diisobutyl ketone extraction and inductively coupled plasma atomic emission spectrometry." Analytica Chimica Acta 127.96(1981):93-101.
Zhang, Fagen, et al. "Comparative metabolism and pharmacokinetics of diisobutyl ketone and diisobutyl carbinol in male SD rats." Toxicology Letters 232.1(2015):175-181.
디이소부틸케톤 준비 용품 및 원자재
원자재
준비 용품
디이소부틸케톤 공급 업체
글로벌( 326)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
Alfa Chemistry | |
Info@alfa-chemistry.com | United States | 24072 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 |
sales@hbmojin.com | China | 12446 | 58 |
Hebei Chuanghai Biotechnology Co,.LTD | +86-13131129325 |
sales1@chuanghaibio.com | China | 5882 | 58 |
Henan Bao Enluo International TradeCo.,LTD | +86-17331933971 +86-17331933971 |
deasea125996@gmail.com | China | 2503 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21667 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29888 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 |
alice@crovellbio.com | China | 8820 | 58 |
Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 |
sales@amoychem.com | China | 6387 | 58 |
Xi'an Kono chem co., Ltd., | 029-86107037 13289246953 |
info@konochemical.com | China | 2995 | 58 |