4-Chlorobenzaldehyde

4-Chlorobenzaldehyde Properties

Melting point	46 °C
Boiling point	213-214℃
Density	1.196
vapor density	0.6 (vs air)
vapor pressure	8.75 atm ( 21 °C)
refractive index	1.5550 (estimate)
Flash point	52 °F
storage temp.	Store below +30°C.
solubility	935mg/l
form	Liquid
color	White to pale yellow
Water Solubility	935 mg/L (20 ºC)
Sensitive	Air Sensitive
BRN	385858
Dielectric constant	72（0.0℃）
Stability	Stable, but air and light-sensitive. Incompatible with strong bases, strong reducing agents, strong oxidizing agents.
InChIKey	AVPYQKSLYISFPO-UHFFFAOYSA-N
LogP	2.34 at 25℃ and pH7
CAS DataBase Reference	104-88-1(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	E67727UP9Z
NIST Chemistry Reference	Benzaldehyde, 4-chloro-(104-88-1)
EPA Substance Registry System	p-Chlorobenzaldehyde (104-88-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07,GHS09

Signal word

Warning

Hazard statements

H302-H315-H317-H319-H411

Precautionary statements

P261-P273-P280-P301+P312-P302+P352-P305+P351+P338

Hazard Codes

F,C,N,Xn,Xi

Risk Statements

22-36/37/38-51/53-36/38

Safety Statements

26-61-37/39-36

RIDADR

UN 1219 3/PG 2

WGK Germany

2

RTECS

CU5076000

F

8-9

Autoignition Temperature

302 °C

TSCA

Yes

HazardClass

9

PackingGroup

III

HS Code

29130000

Toxicity

LD50 orally in Rabbit: 840 mg/kg LD50 dermal Rat 5000 mg/kg

NFPA 704

	2
1		0

4-Chlorobenzaldehyde price More Price(43)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	8.02453	4-Chlorobenzaldehyde for synthesis	104-88-1	5G	$34.2	2024-03-01	Buy
Sigma-Aldrich	8.02453	4-Chlorobenzaldehyde for synthesis	104-88-1	250g	$68.7	2024-03-01	Buy
Sigma-Aldrich	8.02453	4-Chlorobenzaldehyde for synthesis	104-88-1	1kg	$121	2024-03-01	Buy
Sigma-Aldrich	112216	4-Chlorobenzaldehyde 97%	104-88-1	50g	$37.3	2024-03-01	Buy
Sigma-Aldrich	112216	4-Chlorobenzaldehyde 97%	104-88-1	250g	$71.2	2024-03-01	Buy

Product number	Packaging	Price	Buy
8.02453	5G	$34.2	Buy
8.02453	250g	$68.7	Buy
8.02453	1kg	$121	Buy
112216	50g	$37.3	Buy
112216	250g	$71.2	Buy

4-Chlorobenzaldehyde Chemical Properties,Uses,Production

Chemical Properties

4-chlorobenzaldehyde appears as colourless to light yellow crystalline powder. Insoluble in water, easily soluble in ethanol, ether, benzene, soluble in water, acetone. Can be volatilized with water vapor. It can produced by the oxidation of 4-chlorobenzyl alcohol. 4-chlorobenzaldehyde is the intermediate of fungicide tebuconazole and plant growth regulator uniconazole.

Uses

4-Chlorobenzaldehyde is used as an intermediate for the manufacture of dyestuffs, optical brighteners, pharmaceuticals, agricultural chemicals and metal finishing products.

Preparation

4-Chlorobenzaldehyde can be obtained by chlorinated hydrolysis of p-chlorotoluene: add p-chlorotoluene and phosphorus trichloride to the reaction pot, raise the temperature to 155°C under light and pass chlorine. Control the temperature at 160-170℃ and pass chlorine to the calculated amount to obtain the chlorination solution. Add it to concentrated sulfuric acid with stirring, and stir for 5h at room temperature. let it stand and stratify, take the lower layer into ice water to crystallize, and filter it when it is cold to below 5℃. The filter cake was washed with ice water to obtain the crude product, distilled under reduced pressure and collected 108-111℃ (3.33kPa) fraction to obtain p-chlorobenzaldehyde.

Synthesis Reference(s)

Synthetic Communications, 26, p. 1, 1996 DOI: 10.1080/00397919608003856
Tetrahedron Letters, 43, p. 1395, 2002 DOI: 10.1016/S0040-4039(02)00027-8

General Description

Colorless to yellow powder or white crystalline solid. Pungent odor.

Air & Water Reactions

4-Chlorobenzaldehyde is sensitive to exposure to air. Insoluble in water.

Reactivity Profile

4-Chlorobenzaldehyde is sensitive to exposure to air. 4-Chlorobenzaldehyde is also sensitive to light. REACTIVITY: 4-Chlorobenzaldehyde is incompatible with strong bases, strong oxidizers and strong reducing agents.

Fire Hazard

4-Chlorobenzaldehyde is combustible.

Purification Methods

Crystallise it from EtOH/water (3:1), then sublime it twice at ~50o/2mm. [Beilstein 7 H 235, 7 IV 568.]

4-Chlorobenzaldehyde synthesis

Synthesis of 4-Chlorobenzaldehyde from 4-Chlorobenzyl(trimethylsilyl) ether

4-Chlorobenzaldehyde Preparation Products And Raw materials

Raw materials

BENZAL CHLORIDE 2,2'-Azobis(2-methylpropionitrile) Manganese dioxide Chlorine 4-Chlorobenzyl chloride

Metallic oxides 4-Chlorotoluene

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Preparation Products

HOMOPIPERONYLAMINE 4-Chlorocinnamic acid Acid Blue 83 2-Amino-2-phenylacetic acid Robenidine hydrochloride

Cyromazine α-phenyl-2-p-tolylethylamine 2,4-Dinitroaniline AMMONIUM O,O-DIISOPROPYLTHIOPHOSPHATE Ammonium L-tartrate

3-(4-CHLORO-PHENYL)-PROPIONALDEHYDE 4-Chlorobenzyl pinacolone 1-amino-9,10-dihydro-9,10-dioxo-2-anthracenecarboxylicaci 4-CHLORO-ALPHA-(METHYLAMINO)BENZENE ACETIC ACID Aceglutamide

Chlorfenapyr UNICONAZOLE (4-CHLORO-BENZYL)-METHYL-AMINE Uniconazole Uniconazole wettable powder

5-chloro-alpha,alpha-bis(3,5-dichloro-2-hydroxyphenyl)-2-toluenesulfonic 4-Chloro-3-nitrobenzaldehyde Dithizone Dodecylamine Tetrabutyl titanate

NEOCUPFERRON 2,5-Dihydro-2,5-dimethoxyfuran Felbamate 3-ETHYLSULFONYL-2-PYRIDINESULFONAMIDE 2-(4-CHLOROPHENYL)-3-METHYL-TETRAHYDRO-1,3-THIAZINE-4-ONE

Propionamide Anilinoacetic acid Chlormezanone Baclofen N-[(4-CHLOROPHENYL)METHYLENE]METHANAMINE

Synthetic greasing agent 1,3-diisopropyl-2-isothiocyanato-5-phenoxybenzene Oxcarbazepine Boron nitride 1H-Benzotriazol-1-yloxytris(dimethylamino)phosphonium Hexafluorophosphate

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4-Chlorobenzaldehyde Suppliers

Global( 700)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Anhui Royal Chemical Co., Ltd.	+86-25-86655873 +8613962173137	marketing@royal-chem.com	China	142	55
Hebei Yanxi Chemical Co., Ltd.	+8617531190177	peter@yan-xi.com	China	5993	58
Dorne Chemical Technology co. LTD	+86-13583358881 +86-18560316533	Ethan@dornechem.com	China	294	58
Henan Bao Enluo International TradeCo.，LTD	+86-17331933971 +86-17331933971	deasea125996@gmail.com	China	2503	58
Springchem New Material Technology Co.,Limited	+86-021-62885108 +8613917661608	info@spring-chem.com	China	2068	57
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418679 +86-18949832763	info@tnjchem.com	China	2989	55
Shanxi Naipu Import and Export Co.,Ltd	+86-13734021967 +8613734021967	kaia@neputrading.com	China	1011	58
Shanghai Zheyan Biotech Co., Ltd.	18017610038	zheyansh@163.com	CHINA	3620	58

Supplier	Advantage
Anhui Royal Chemical Co., Ltd.	55
Hebei Yanxi Chemical Co., Ltd.	58
Dorne Chemical Technology co. LTD	58
Henan Bao Enluo International TradeCo.，LTD	58
Springchem New Material Technology Co.,Limited	57
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
Hefei TNJ Chemical Industry Co.,Ltd.	55
Shanxi Naipu Import and Export Co.,Ltd	58
Shanghai Zheyan Biotech Co., Ltd.	58

View Lastest Price from 4-Chlorobenzaldehyde manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-28	4-Chlorobenzaldehyde 104-88-1	US $1.00 / g	1g	99%	1000kg	Dorne Chemical Technology co. LTD
2024-04-28	4-Chlorobenzaldehyde 104-88-1	US $5.00 / KG	1KG	99%	500mt/year	Jinan Finer Chemical Co., Ltd
2024-03-16	4-Chlorobenzaldehyde 104-88-1	US $0.00 / KG	100g	98%+	100kg	WUHAN CIRCLE POWDER TECHNOLOGY CO.,LTD

4-Chlorobenzaldehyde
104-88-1
US $1.00 / g
99%
Dorne Chemical Technology co. LTD

4-Chlorobenzaldehyde
104-88-1
US $5.00 / KG
99%
Jinan Finer Chemical Co., Ltd

4-Chlorobenzaldehyde
104-88-1
US $0.00 / KG
98%+
WUHAN CIRCLE POWDER TECHNOLOGY CO.,LTD

4-Chlorobenzaldehyde Spectrum

4-Chlorobenzaldehyde(104-88-1)MS 4-Chlorobenzaldehyde(104-88-1)¹HNMR 4-Chlorobenzaldehyde(104-88-1)¹³CNMR 4-Chlorobenzaldehyde(104-88-1)IR1 4-Chlorobenzaldehyde(104-88-1)IR2 4-Chlorobenzaldehyde(104-88-1)IR3 4-Chlorobenzaldehyde(104-88-1)Raman

104-88-1(4-Chlorobenzaldehyde)Related Search:

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4'-CHLOROACETANILIDE 4-Chlorophenylacetic acid 1,2-Dichlorobenzene 1-Nonanal 4-Chlorophenoxyacetic acid

4-Chlorobenzyl alcohol Paraldehyde 4-Chlorobenzoic acid 4-Chlorobenzyl cyanide 4-Chlorobenzonitrile

4-Chloroanisole 4-Methylbenzyl chloride 4-Fluorobenzoic acid

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p-chlorobenzenecarboxaldehyde Benzaldehyde,4-chloro- benzaldehyde,-chloro- p-chloro-benzaldehyd p-Chlorobenzaldehyde 4-Chlorobenzaldehyde 4-CHLOROBENZALDEHYDE 98% (GC) 4-Chlorobenzaldehyde, 98.5+% 4-CHLOROBENZYLALDEHYDE 4-Chlorbenzaldehyde p-CHLOROBENZALDEHYDE pure 17) PARA CHLORO BENZALDEHYDE 4-Chlorobenzaldehyde ,98% 4-Chlorobenzenecarbaldehyde 4-chloro-Benzaldehyde,4-Chloro-benzaldehyde 4-Chlorobenzoic aldehyde 4-CHLOROBENZALDEHYDE AMMONIA SOLUTION, STRONG AMMONIA NO 1 AMMONIA NO 2 AMMONIA 1 ION CHROMATOGRAPHY STANDARD AMMONIA 1K ION CHROMATOGRAPHY STANDARD AMMONIA, FREE REAGENT AMMONIA MONITOR BUFFER AMMONIA MONITOR FIRST REAGENT AMMONIA MONITOR REAGENT AMMONIA MONITOR REAGENT 1 AMMONIA MONITOR REAGENT 2 AMMONIA MONITOR SECOND REAGENT AMMONIA MONITOR STANDARD AMMONIA 10 ION CHROMATOGRAPHY STANDARD AMMONIA 10K ION CHROMATOGRAPHY STANDARD AMMONIUM LIQUOR AMMONIUM ION CHROMATOGRAPHY STANDARD AMMONIUM STANDARD AKOS BBS-00003190 4-Chlorbenzaldehyd 4-chloro-benzaldehyd 4-chlorobenzenaldehyde Benzaldehyde, p-chloro- Benzaldehyde, p-chloro- (8CI) Of chlorobenzaldehyde 4-Chlorobenzaldehyde, 98.5+% 100GR 4-Chlorobenzaldehyde, 98.5+% 250GR 4-CHLOROBENZALDEHYDE FOR SYNTHESIS 4-Chlorobenzaldehyde, 97+% Chlorobenzene forMaldehyde hlorobenzaldehyde orobenzaL 4-Chlorobenzaldehyde > Lumefantrine p-Chloro Benzaldehyde 4-Chlorobenzaldehyde ISO 9001：2015 REACH p-chlorobenzale Hyde 4-Chlorobenzaldehyde 104-88-1 p-Chlorobenzenecarboxaldehyde 104-88-1 PCAD Chloromezanone Impurity P-CHLOROBENZALDEHYDE PCAD PARA-CHLOROBENZALDEHYDE