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Ethyl chloroacetate

Ethyl chloroacetate
Ethyl chloroacetate structure
CAS No.
105-39-5
Chemical Name:
Ethyl chloroacetate
Synonyms
NSC 8833;ethylchloracetate;2-chlorobutanoate;Chloroaceticester;Ethyl chloroacetat;Ethyl chloracetate;ethylechloroacetate;Ethyt chloroacetate;ETHYL CHLOROACETATE;RARECHEM AL BI 0139
CBNumber:
CB9852655
Molecular Formula:
C4H7ClO2
Formula Weight:
122.55
MOL File:
105-39-5.mol

Ethyl chloroacetate Properties

Melting point:
-26 °C (lit.)
Boiling point:
143 °C (lit.)
Density 
1.145 g/mL at 25 °C (lit.)
vapor density 
4.23 (vs air)
vapor pressure 
10 mm Hg ( 38 °C)
refractive index 
n20/D 1.421(lit.)
Flash point:
150 °F
storage temp. 
Store below +30°C.
solubility 
12.3g/l
form 
Liquid
color 
Clear colorless
Odor
Extremely irritating; fruity; pungent
explosive limit
2.6%(V)
Water Solubility 
20 g/L (20 ºC)
Merck 
14,3783
BRN 
506455
Stability:
Stable. Incompatible with acids, bases, oxidizing agents, reducing agents. Flammable.
CAS DataBase Reference
105-39-5(CAS DataBase Reference)
EWG's Food Scores
1
FDA UNII
6H07TEH4TF
NIST Chemistry Reference
Ethyl chloroacetate(105-39-5)
EPA Substance Registry System
Ethyl chloroacetate (105-39-5)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS09,GHS02,GHS05,GHS06,GHS07,GHS08
Signal word  Danger
Hazard statements  H301+H331-H310-H315-H317-H371-H401-H226-H301+H311+H331-H318-H400-H301-H311-H331
Precautionary statements  P261-P273-P280-P301+P310-P305+P351+P338-P311-P210-P233-P240-P241+P242+P243-P260-P262-P264-P270-P271-P272-P301+P310+P330-P302+P352+P310+P361+P364-P304+P340+P311-P305+P351+P338+P310-P308+P311-P403+P233-P405-P301+P310a-P303+P361+P353-P501a
Hazard Codes  T,N
Risk Statements  23/24/25-50-10
Safety Statements  45-61-7/9-16
RIDADR  UN 1181 6.1/PG 2
WGK Germany  2
RTECS  AF9110000
Autoignition Temperature 452 °C
TSCA  Yes
HS Code  2915 40 00
HazardClass  6.1
PackingGroup  II
Toxicity LD50 orally in Rabbit: 180 mg/kg LD50 dermal Rat 161 mg/kg
NFPA 704
2
3 0

Ethyl chloroacetate price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich E16856 Ethyl chloroacetate 99% 105-39-5 1l $71.5 2021-03-22 Buy
Sigma-Aldrich E16856 Ethyl chloroacetate 99% 105-39-5 2.5l $134 2021-03-22 Buy
TCI Chemical C0092 Ethyl Chloroacetate >98.0%(GC) 105-39-5 25mL $19 2021-03-22 Buy
TCI Chemical C0092 Ethyl Chloroacetate >98.0%(GC) 105-39-5 500mL $33 2021-03-22 Buy
Alfa Aesar A15554 Ethyl chloroacetate, 99% 105-39-5 500g $35.8 2021-03-22 Buy

Ethyl chloroacetate Chemical Properties,Uses,Production

Chemical Properties

Ethyl chloroacetate is a colourless liquid with a pungent, fruity odor.Ethyl chloroacetate has a vapor pressure of 10mmHg at 38 °C (Lewis, 1997). It is insoluble in water, but miscible with alcohol, ether, and acetone (Lide, 1998); it is soluble in benzene (Lewis, 1997). Ethyl chloroacetate readily decomposes in hot water and alkalis (Lewis, 1997).

Uses

Reagent used in the preparation of 5 member heterocycles.

Synthesis Reference(s)

Tetrahedron, 23, p. 359, 1967 DOI: 10.1016/S0040-4020(01)83321-4

General Description

A clear colorless liquid with a pungent odor. Flash point 100°F. Denser than water and insoluble in water. Vapors heavier than air.

Air & Water Reactions

Highly flammable. Slow hydrolysis to acidic products will cause slow corrosion of common metals. No hazard involved. [USCG, 1999].

Reactivity Profile

Ethyl chloroacetate is a chlorinated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Hazard

Strong irritant to eyes.

Health Hazard

Inhalation causes irritation of mucous membrane, headache, and nausea. Contact with liquid causes extreme eye irritation and conjunctivitis; irritates skin if not removed at once. Ingestion causes irritation of mouth and stomach.

Fire Hazard

Special Hazards of Combustion Products: Irritating, toxic hydrogen chloride and phosgene may be generated in fires.

Chemical Reactivity

Reactivity with Water Very slow, not hazardous; Reactivity with Common Materials: Slow hydrolysis to acidic products; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.

Safety Profile

oison by skin contact and subcutaneous routes. A severe eye irritant. Questionable carcinogen with experimental neoplastigenic data.Flammable liquid; a dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidizing materials. Will react with water or steam to produce toxic and corrosive fumes. Vigorous reaction with sodium cyanide. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits highly toxic fumes of cl-.

Potential Exposure

Used to make rodenticides, dyes, and other chemicals. Also used as a military poison

Shipping

UN1181 Ethylchloroacetate, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid.

Purification Methods

Shake the ester with satutated aqueous Na2CO3 (three times), aqueous 50% CaCl2 (three times) and saturated aqueous NaCl (twice). Dry it with Na2SO4 or MgSO4 and distil it. [Beilstein 2 IV 481.] LACHRYMATORY.

Incompatibilities

May form explosive mixture with air. Incompatible with strong bases; strong acids; reducing agents. Moisture, water, and steam contact forms toxic and corrosive fumes. Violent reaction with oxidizers, alkaline earth metals (barium, calcium, magnesium, strontium, etc.), alkaline metals, sodium cyanide. Attacks metals in the presence of moisture.

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

Ethyl chloroacetate Preparation Products And Raw materials

Raw materials

Preparation Products


Ethyl chloroacetate Suppliers

Global( 312)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-66670886
info@dakenchem.com China 20890 58
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0371-55170693
0371-55170693 info@tianfuchem.com CHINA 22607 55
ATK CHEMICAL COMPANY LIMITED
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+86 21 5161 9052/ 5187 7796 ivan@atkchemical.com CHINA 26762 60
Hefei TNJ Chemical Industry Co.,Ltd.
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Hebei Guanlang Biotechnology Co., Ltd.
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Henan Xiangtong Chemical Co., Ltd.
86-371-61312303
86-371-86017988 cathy@hnxtchem.com CHINA 293 58

View Lastest Price from Ethyl chloroacetate manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-12-08 Ethyl chloroacetate
105-39-5
US $10.00 / KG/Tin 1KG 99% 5000tons per month Wuhan Mulei New Material Technology Co. Ltd
2021-08-25 Ethyl chloroacetate
105-39-5
US $1.00 / KG 1KG 99% 100MT Henan Xiangtong Chemical Co., Ltd.
2021-07-13 Ethyl chloroacetate
105-39-5
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd

Ethyl chloroacetate Spectrum


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