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비펜스린

비펜스린
비펜스린 구조식 이미지
카스 번호:
82657-04-3
한글명:
비펜스린
동의어(한글):
비펜스린;사이클로프로페인카복실산,3-[(1Z)-2-클로로-3,3,3-트라이플루오로-1-프로펜-1-일]-2,2-다이메틸-,(2-메틸[1,1'-바이페닐]-3-일)메틸에스터,(1R,3R)-;비펜스린(BIFENTHRIN);비펜트린;[1a,3a(Z)]-(+-)-3-(2-클로로-3,3,3-트라이플루오로-1-프로펜일)-2,2-다이메틸사이클로프로페인카복실산, (2-메틸[1,1'-바이페닐]-3-일)메틸 에스터;사이클로프로페인카복실산, 3-(2-클로로-3,3,3-트라이플루오로-1-프로펜일)-2,2-다이메틸-, (2-메틸[1,1'-바이페닐]-3-일)메틸 에스터, [1a,3a(Z)]-;사이클로프로페인카복실산, 3-(2-클로로-3,3,3-트라이플루오로-1-프로펜일)-2,2-다이메틸-, (2-메틸[1,1'-바이페닐]-3-일)메틸 에스터, [1a,3a(Z)]-(±)-;사이클로프로페인카복실산, 3-[(1Z)-2-클로로-3,3,3-트라이플루오로-1-프로펜-1-일]-2,2-다이메틸-, (2-메틸[1,1'-바이페닐]-3-일)메틸 에스터, (1R,3R)-;사이클로프로페인카복실산, 3-[(1Z)-2-클로로-3,3,3-트라이플루오로-1-프로펜-1-일]-2,2-다이메틸-, (2-메틸[1,1'-바이페닐]-3-일)메틸 에스터, (1R,3R)-릴-;사이클로프로페인카복실산, 3-[(1Z)-2-클로로-3,3,3-트라이플루오로-1-프로펜일]-2,2-다이메틸-, (2-메틸[1,1'-바이페닐]-3-일)메틸 에스터, (1R,3R)-;사이클로프로페인카복실산, 3-[(1Z)-2-클로로-3,3,3-트라이플루오로-1-프로펜일]-2,2-다이메틸-, (2-메틸[1,1'-바이페닐]-3-일)메틸 에스터, (1R,3R)-릴-
상품명:
Bifenthrin
동의어(영문):
Talster;TALSTAR;brigade;capture;fmc54800;Brookade;fmc58000;fmc-54800;biphenate;BRIGADE(R)
CBNumber:
CB1714667
분자식:
C23H22ClF3O2
포뮬러 무게:
422.87
MOL 파일:
82657-04-3.mol

비펜스린 속성

녹는점
68-71°C
끓는 점
453.2±45.0 °C(Predicted)
밀도
d25 1.212 g/ml
증기압
2.4×10-5 Pa (25 °C)
인화점
165 °C
저장 조건
0-6°C
물리적 상태
neat
수용성
0.01 g/100 mL
Merck
13,1215
InChIKey
OMFRMAHOUUJSGP-JHEGMOCKSA-N
CAS 데이터베이스
82657-04-3(CAS DataBase Reference)
NIST
Bifenthrin(82657-04-3)
EPA
Bifenthrin (82657-04-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xn;N,N,Xn,F,T
위험 카페고리 넘버 20/21/22-50/53-36-11-36/37/38-48/22-43-40-23/25
안전지침서 13-60-61-36/37-16-36-26-45-38-24-23
유엔번호(UN No.) UN 2588
WGK 독일 3
RTECS 번호 GZ1227800
위험 등급 6.1(b)
포장분류 III
HS 번호 29162090
유해 물질 데이터 82657-04-3(Hazardous Substances Data)
독성 LD50 orally in rats: 54.5 mg/kg; LD50 dermally in rabbits: >2000 mg/kg (Doel)
기존화학 물질 KE-05935
그림문자(GHS):
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H300 삼키면 치명적임 급성 독성 물질 - 경구 구분 1,2 위험 P264, P270, P301+P310, P321, P330,P405, P501
H317 알레르기성 피부 반응을 일으킬 수 있음 피부 과민성 물질 구분 1 경고 P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 눈에 심한 자극을 일으킴 심한 눈 손상 또는 자극성 물질 구분 2A 경고 P264, P280, P305+P351+P338,P337+P313P
H331 흡입하면 유독함 급성 독성 물질 흡입 구분 3 위험 P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H351 암을 일으킬 것으로 의심됨 (노출되어도 암을 일으키지 않는다는 결정적인 증거가 있는 노출경로가 있다면 노출경로 기재) 발암성 물질 구분 2 경고 P201, P202, P281, P308+P313, P405,P501
H372 장기간 또는 반복 노출되면 장기(또는, 영향을 받은 알려진 모든 장기를 명시)에 손상을 일으킴 특정 표적장기 독성 - 반복 노출 구분 1 위험 P260, P264, P270, P314, P501
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 P273, P391, P501
H411 장기적 영향에 의해 수생생물에 유독함 수생 환경유해성 물질 - 만성 구분 2
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P273 환경으로 배출하지 마시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P311 의료기관(의사)의 진찰을 받으시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

비펜스린 MSDS


Bifenthrin

비펜스린 C화학적 특성, 용도, 생산

개요

Bifenthrin is a synthetic pyrethroid insecticide/miticide/acaricide. Bifenthrin is off-white to pale tan waxy solid granules with a faint, musty odour and a slightly sweet smell. Bifenthrin is soluble in methylene chloride, acetone, chloroform, ether, and toluene and slightly soluble in heptane and methanol. It is slightly combustible and support combustion at elevated temperatures. Thermal decomposition and burning may form toxic byproducts such as carbon monoxide, carbon dioxide, hydrogen chloride, and hydrogen fluoride. Bifenthrin treatment affects the nervous system and causes paralysis in insects.

화학적 성질

Bifenthrin is a member of the pyrethroid chemical class. It is an insecticide and acaricide. Bifenthrin is off-white to pale tan waxy solid granules with a faint, musty odor and slightly sweet smell. Bifenthrin is soluble in methylene chloride, acetone, chloroform, ether, and toluene, and is slightly soluble in heptane and methanol. It is slightly combustible and support combustion at elevated temperatures. Thermal decomposition and burning may form toxic by-products, such as carbon monoxide, carbon dioxide, hydrogen chloride, and hydrogen fl uoride. Bifentrin treatment affects the nervous system and causes paralysis in insects.

화학적 성질

White Solid

화학적 성질

Off white to pale tan waxy substance. Faint, sweet odor.

용도

Third generation synthetic pyrethroid. Insecticide, acaricide.

용도

Bifenthrin controls foliar insect pests and some mites on a range of crops including cereals, citrus, cotton, fruit and vegetables.

용도

Insecticide, acaricide.

정의

ChEBI: A carboxylic ester obtained by formal condensation of cis-3-(2-chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopropanecarboxylic acid and [(2-methyl-1,1'-biphenyl)-3-yl]methanol.

건강위험

Bifenthrin is moderately toxic to species of mammals when ingested. Exposures to large doses of bifenthrin cause poisoning with symptoms that include, but are not limited to, incoordination, tremor, salivation, vomiting, diarrhea, and irritability to sound and touch. Exposures to bifenthrin through skin absorption and/or inhalation of dust cause adverse health effects. On contact with bifenthrin, occupational workers develop adverse health effects that include skin sensations, rashes, numbness, and a burning and tingling type of effect. As a pyrethroid poison, bifenthrin disturbs the electrical impulses in nerves, over-stimulating nerve cells, causing tremors and eventually causing paralysis. The skin-related health effects were found to be reversible and subside after a brief period of time and stoppage of further exposures to bifenthrin. Although bifenthrin causes no infl ammation or irritation on human skin, it can cause a tingling sensation that lasts about 12 h. Bifenthrin has caused no symptoms of irritation to rabbits’ eyes. The US EPA has classifi ed bifenthrin as toxicity class II, meaning moderately toxic

농업용

Insecticide, Acaricide: A broad-spectrum insecticide. Registered to control cone worms, seed bugs, seed worms and other insects and mites on rangeland, forests and right-of-ways. It is also used to control household and lawn pests. A U.S. EPA restricted Use Pesticide (RUP).

상품명

BIFLEX®; BISTAR®; BRIGADE®; CAPTURE® Bifenthrin; DISCIPLINE®; DOUBLE THREAT®; EMPOWER®; FMC® 54800; FMC® 58000; TALSTAR®; TALSTAR LAWN & TREE®; TORANT®; ZIPAK®

잠재적 노출

A broad spectrum pyrethroid secticide/ acaricide used to control cone worms, seed bugs, seed worms and other insects and mites in forests, on rangeland, and right-of-ways. It is also used to control household and lawn pests. A United States Environmental Protection Agency Restricted Use Pesticide (RUP).

신진 대사 경로

When mites are administered 14C-bifenthrin either by injection or by contact, bifenthrin is efficiently metabolized by the mites and the metabolites identified arise from the combination of ester cleavage, oxidation, and conjugation reactions and are the 4'-hydroxy derivative of the ester, the primary ester cleavage products, the acid, and its 4'-hydroxy derivative from the alcohol moiety, as well as several unidentified metabolites.

저장

Bifenthrin should be kept stored in a cool, dry, well-ventilated place away from heat, open flame or hot surfaces. It should only be stored in its original containers and should not be contaminated with other pesticides, fertilizers, water, food, or feed by storage or disposal

운송 방법

UN2588 Pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1—Poisonous materials, Technical Name Required. UN3349 Pyrethroid pesticide, solid toxic, Hazard Class: 6.1; Labels: 6.1—Poisonous material.

Degradation

Bifenthrin is stable for 21 days in the pH range 5-9 at 21°C but it is labile at higher pH. It has a DT50 of 225 days in natural daylight and can therefore be regarded as relatively photochemically stable (PSD).

Toxicity evaluation

The solubility of bifenthrin in water is relatively low at 0.1 mg l-1. Furthermore, the water octanol coefficient (Kow) is 1×106 and results in bifenthrin binding to organic substrates. The soil sorption coefficients range between 1.31×105 and 3.02×105, indicating relatively tight binding to soil particles. They also tend to bind to organic particulate materials in the water column. The Kow of bifenthrin may explain the bioconcentration factors (BCFs) observed in some animals, especially fish. For example, fathead minnows (Pimephales promelas) exposed to 0.0037 mg l1 bifenthrin had BCFs of 21 000 after 127 days and 28 000 after 254 days of exposure. Hydrolysis of bifenthrin in buffered water occurs between pH 5 and 9. Photolysis studies in water and soil found that the half-lives were 408 and 96.9 days, respectively. The aerobic soil half-life was 96.3 days and the anaerobic halflife, 425 days.

비 호환성

May react violently with strong oxidizers, bromine, 90% hydrogen peroxide, phosphorus trichloride, silver powders or dust. Incompatible with silver compounds, lime, and ordinary soaps. Mixture with some silver compounds forms explosive salts of silver oxalate.

폐기물 처리

Incineration would be an effective disposal procedure where permitted. If an efficient incinerator is not available, the product should be mixed with large amounts of combustible material and contact with the smoke should be avoided. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

비펜스린 준비 용품 및 원자재

원자재

준비 용품


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