석회석

석회석
석회석 구조식 이미지
카스 번호:
1317-65-3
한글명:
석회석
동의어(한글):
석회석;탄산칼슘;탄산 칼슘
상품명:
CALCIUM CARBONATE
동의어(영문):
CALCITE;CHALK;ARAGONITE;GROUND LIMESTONE;PRECIPITATED CHALK;WHITING;Agstone;KALKSPAR;domolite;franklin
CBNumber:
CB2356871
분자식:
CCaO3
포뮬러 무게:
100.09
MOL 파일:
1317-65-3.mol
MSDS 파일:
SDS

석회석 속성

녹는점
825 °C
끓는 점
2850 °C
밀도
2.93 g/mL at 25 °C(lit.)
용해도
5 M HCl: 20°C에서 0.1°M, 투명, 무색
물리적 상태
랜덤 크리스털
색상
회색
Solubility Product Constant (Ksp)
pKsp: 8.47
CAS 데이터베이스
1317-65-3(CAS DataBase Reference)
EPA
Limestone (1317-65-3)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 Xi
위험 카페고리 넘버 37/38-41
안전지침서 26-36/37/39
WGK 독일 -
RTECS 번호 FF9335000
기존화학 물질 KE-21996
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H315 피부에 자극을 일으킴 피부부식성 또는 자극성물질 구분 2 경고 GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 GHS hazard pictograms P280, P305+P351+P338, P310
예방조치문구:
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P302+P352 피부에 묻으면 다량의 물로 씻으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
P310 즉시 의료기관(의사)의 진찰을 받으시오. 삼켰다면 즉시 의료기관(의사)의 도움을 받으시오.
P321 (…) 처치를 하시오.
P332+P313 피부 자극이 생기면 의학적인 조치· 조언을 구하시오.
P362 오염된 의복을 벗고 세척 후에 재사용하기
NFPA 704
0
1 0

석회석 C화학적 특성, 용도, 생산

개요

Calcite is one of the most common minerals on the face of the earth, comprising about 4% by weight of the earth’s crust and is formed in many different geological environments. Calcite can form rocks of considerable mass and constitutes a significant part of all three major rock classification types. It forms oolitic, fossiliferous and massive limestones in sedimentary environments and even serves as the internal cement for many sandstones and shales.Calcite is even a major component in the igneous rock called carbonatite and forms the major portion of many hydrothermal veins. Not necessarily a variety of calcite, cave formations are certainly a unique aspect of calcite’s story.

화학적 성질

Calcium carbonate is a white, odorless powder, or crystalline solid.

용도

Source of lime; neutralizing agent, filler, and extender in rubber, plastics, paints; opacifying agent in paper; fortification of bread; putty; tooth pow- ders; antacid; whitewash; Portland cement; sulfur dioxide removal from stack gases; metallurgical flux; analytical chemistry; carbon dioxide gener- ation (laboratory).

제조 방법

The calcite present is derived mostly from the remains of organisms such as clams, brachiopods, bryozoa, crinoids and corals. These animals live on the bottom of the sea and when they die their shells accumulate into piles of shelly debris. This debris can then form beds of limestone. Some limestones may have been derived from nonbiogenic calcite formation.

정의

Aragonite: An anhydrous mineral form of calcium carbonate, CaCO3, which occurs associated with limestone and in some metamorphic rocks. It is also the main ingredient of pearls. It is not as stable as calcite, into which it may change over time.
Calcite:A mineral form of calcium carbonate occurring in limestone, chalk, and marble.
Charlk: A natural form of calcium carbonate (CaCO3) formed originally by marine organisms. (Blackboard chalk is calcium sulfate, CaSO4.).

일반 설명

Odorless, white to tan powder.

반응 프로필

CALCIUM CARBONATE has generally low chemical reactivity. Is non-combustible. Decomposes at high temperature (825°C) to give gaseous carbon dioxide and calcium oxide (quicklime). Incompatible with acids, alum, ammonium salts, fluorine, magnesium. Reacts with acids and acidic salts to generate gaseous carbon dioxide with effervescence (bubbling). The reaction is rapid and exothermic with concentrated solutions of acids. The efferversence can create extensive foaming. Ignites on contact with fluorine.

위험도

A nuisance particulate dust.

건강위험

Calcium carbonate is considered to be a nuisance dust.
Although no adverse effects have been reported in the literature among workers exposed to calcium carbonate, high concentrations of the dust would be expected to act as a physical irritant to the eyes and skin.1 Fourteen British workers exposed to heavy calcium carbonate concentrations for 12–35 years showed no trace abnormalities due to dust or any clinical sign of pneumoconiosis or chronic bronchitis on X ray.2 Long exposure to high dust concentrations of pure calcium carbonate (quartz content less than 1.1%) did not result in lung fibrosis.

농업용

Limestone or dolomite, used in agriculture for liming the soil, is ground to a fineness to ensure that 50% of the particles pass through a 1.70mm Indian Standards (IS) sieve, and 50% is retained on a 150micron IS sieve.

Safety Profile

A nuisance dust. An eye and skin irritant. Igmtes on contact with F2. Incompatible with acids, ammonium salts, (Mg + H2). Calcium carbonate is a common air contaminant. See also CALCIUM COMPOUNDS.

잠재적 노출

Calcium carbonate is used as a source of lime; neutralizing agent; manufacturing or rubber, plastics, paint and coatings; sealants, paper, dentifrices, ceramics, putty, polishes and cleaners, insecticides, inks and cosmetics; whitewash; Portland cement; antacids; analytical chemistry, and others

비 호환성

Calcium carbonate decomposes in high temperature forming carbon dioxide and corrosive materials

폐기물 처리

Landfills. It is the responsibility of chemical waste generators to determine if a discarded chemical is classified as a hazardous waste. See 40 CFR Parts 261.3 for United States Environmental Protection Agency guidelines for the classification determination. In addition, in order to ensure complete and accurate classification, waste generators must consult state and local hazardous waste regulations.

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