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삼산화황

삼산화황
삼산화황 구조식 이미지
카스 번호:
7446-11-9
한글명:
삼산화황
동의어(한글):
무수황산;삼산화유황;삼산화황;황트리산화물(베타);황트리산화물(베타)(SULFURTRIOXIDE(BETA))
상품명:
Sulfur trioxide
동의어(영문):
SO3;Sulfan;SULFAN(R);sulfuricoxide;Sulfuric oxide;SULFUR TRIOXIDE;Schwefeltrioxid;SULPHUR TRIOXIDE;Sulfur oxide (SO3);Oxosulfane dioxide
CBNumber:
CB5854196
분자식:
O3S
포뮬러 무게:
80.06
MOL 파일:
7446-11-9.mol

삼산화황 속성

녹는점
16.8 °C(lit.)
끓는 점
44.8 °C
밀도
1.97 g/mL at 25 °C(lit.)
증기 밀도
2.8 (vs air)
증기압
280 mm Hg ( 25 °C)
저장 조건
Indoors
물리적 상태
colorless liquid
수용성
reacts violently
Merck
13,9069
안정성
Stable. Incompatible with organic materials, finely powdered metals, bases, water, cyanides and a wide variety of other chemicals. Reacts violently with water, oxygen and other chemicals - read a full data sheet before use.
CAS 데이터베이스
7446-11-9(CAS DataBase Reference)
NIST
Sulfur trioxide(7446-11-9)
EPA
Sulfur trioxide(7446-11-9)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 O,T+,C
위험 카페고리 넘버 45-8-14-26-34-37-35
안전지침서 53-17-26-36/37/39-45-8-25-30
유엔번호(UN No.) UN 1829 8/PG 1
WGK 독일 1
RTECS 번호 WT4830000
위험 등급 8
포장분류 I
유해 물질 데이터 7446-11-9(Hazardous Substances Data)
그림문자(GHS):
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H314 피부에 심한 화상과 눈에 손상을 일으킴 피부부식성 또는 자극성물질 구분 1A, B, C 위험 P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H335 호흡 자극성을 일으킬 수 있음 특정 표적장기 독성 - 1회 노출;호흡기계 자극 구분 3 경고
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P310 즉시 의료기관(의사)의 진찰을 받으시오. 삼켰다면 즉시 의료기관(의사)의 도움을 받으시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.

삼산화황 MSDS


Sulfuric anhydride

삼산화황 C화학적 특성, 용도, 생산

화학적 성질

Sulfur trioxide, S03, also known as sulfuric anhydride, needles or polymer, exists in a number of modifications that differ in molecular species and crystalline form. It has a white,ice-like modification that melts at 16°C (61°F) and two other as bestos-like forms that melt at the higher temperatures of 33 and 62°C (90 and 144 °F). The colorless liquid or gas form has irritating, toxic fumes and boils at 45 °C (112 °F). Sulfur trioxide is a highly reactive substance, a strong oxidizing agent,and a fire hazard. It reacts with metallic oxides to form sulfates and with water to form sulfuric acid. Sulfur trioxide is used for sulfonation.

화학적 성질

Sulfur trioxide is a crystalline solid which has 3 forms: alpha-, beta-, and gamma-; and can also exist as a gas or liquid.

용도

Sulfonation of organic compounds, especially nonionic detergents, solar energy collectors. It is usually generated in the plant where it is to be used.

일반 설명

Sulfur trioxide, is a colorless to white crystalline solid which will fume in air. Often shipped with inhibitor to prevent polymerization. Sulfur trioxide reacts violently with water to form sulfuric acid with the release of heat. Sulfur trioxide is corrosive to metals and tissue. Sulfur trioxide causes eye and skin burns. Ingestion causes severe burns of mouth esophagus and stomach. The vapor is very toxic by inhalation. Sulfur trioxide is a fire risk when in contact with organic materials such as wood, cotton, fiberboard, etc.

공기와 물의 반응

Combines with water with explosive force, forming sulfuric acid due to its acidity Sulfur trioxide chars most organic substances. On exposure to air Sulfur trioxide absorbs moisture rapidly, emitting dense white fumes [Merck 11th ed. 1989].

반응 프로필

The reaction of Sulfur trioxide and oxygen difluoride is very vigorous and explosions occur if the reaction is carried out in the absence of a solvent [J. Chem. Eng. Data 13(4):529-531. 1968]. The reaction of Sulfur trioxide in excess with tetrafluoroethylene causes explosive decomposition to carbonyl fluoride and sulfur dioxide [Chem. Eng. News 49(22):3. 1971]. The reaction of anhydrous perchloric acid with Sulfur trioxide is violent and accompanied by the evolution of considerable heat (Pascal 16:300 1931-34). Liquid Sulfur trioxide reacts violently with nitryl chloride, even at 75° C. The reaction of Sulfur trioxide and lead oxide causes white luminescence [Mellor 7:654 1946-47]. The combination of iodine, pyridine, Sulfur trioxide, and formamide developed a gas over pressurization after several months. This is due to the slow formation of sulfuric acid, from external water or dehydration of the formamide to hydrogen cyanide.

위험도

Oxidizing agent, fire risk in contact with organic materials, an explosive increase in vapor pressure occurs when the α form melts. The anhydride combines with water, forming sulfuric acid and evolving heat. Highly toxic, strong irritant to tissue.

건강위험

Sulfur trioxide is highly toxic. It is an irritant and corrosive to mucous membranes. Poisonous if inhaled or swallowed. Contact causes severe burns to skin and eyes.

화재위험

Fire risk in contact with organic materials. An explosive increase in vapor pressure occurs when the alpha form melts. Combines with water with explosive violence, forming sulfuric acid. May ignite other combustible materials (wood, paper, oil, etc.). Flammable poisonous gases may accumulate in tanks and hopper cars. Runoff to sewer may create fire or explosion hazard. Forms sulfuric acid on contact with water. Avoid water and organic materials. On exposure to air, Sulfur trioxide absorbs moisture and emits dense white fumes.

Safety Profile

Poison by inhalation. Human systemic effects by inhalation: cough and other pulmonary and olfactory changes. A corrosive irritant to skin, eyes, and mucous membranes. Violent reaction with O2F2, PbO, NClO2, HClO4, P, tetrafluorethylene, acetonitrile, sulfuric acid, dimethyl sulfoxide, dioxan, water, diphenylmercury, formamide, iodine, pyridine, metal oxides. Reacts with steam to form corrosive, toxic fumes of sulfuric acid. When heated to decomposition it emits toxic fumes of SO,. See also SULFURIC ACID.

잠재적 노출

Sulfur trioxide is used as a sulfating and sulfonating agent for detergent, lubricating oil additives, and other organic compounds; in solar energy collectors. It is also used as an intermediate in sulfuric acid manufacture and in making explosives.

운송 방법

UN1829 Sulfur trioxide, stabilized, Hazard class: 8; Labels: 8-Corrosive material, 6.1-Poisonous Inhalation Hazard, Inhalation Hazard Zone B.

비 호환성

Combustible and Corrosive. A strong oxidizer. Reacts violently with water, steam or moisture, releasing corrosive hydrosulfuric acid. Violent reactions occur on contact with strong bases; strong acids, chemically active metals; reducing agents; finely divided metal; cyanides, nitrates, picrates, fulminates, chlorates, sulfides, carbides, phosphorus, dioxygen difluoride, barium oxide; lead oxide; diphenyl mercury; alcohols, nitryl chloride; acetonitrile, dioxane, tetrafluoroethylene.

폐기물 처리

Return refillable compressed gas cylinders to supplier. Nonrefillable cylinders should be disposed of in accordance with local, state and federal regulations. Allow remaining gas to vent slowly into atmosphere in an unconfined area or exhaust hood. Refillabletype cylinders should be returned to original supplier with any valve caps and outlet plugs secured and valve protection caps in place.

삼산화황 준비 용품 및 원자재

원자재

준비 용품


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